Surface roughness signatures of summer arctic snow-covered sea ice in X-band dual-polarimetric SAR

ABSTRACT

Surface roughness of sea ice is primary information for understanding sea ice dynamics and air–ice–ocean interactions. Synthetic aperture radar (SAR) is a powerful tool for investigating sea ice surface roughness owing to the high sensitivity of its signal to surface structures. In this study, we explored the surface roughness signatures of the summer Arctic snow-covered first-year sea ice in X-band dual-polarimetric SAR in terms of the root mean square (RMS) height. Two ice campaigns were conducted for the first-year sea ice with dry snow cover in the marginal ice zone of the Chukchi Sea in August 2017 and August 2018, from which high-resolution (4 cm) digital surface models (DSMs) of the sea ice were derived with the help of a terrestrial laser scanner to obtain the in situ RMS height. X-band dual-polarimetric (HH and VV) SAR data (3 m spatial resolution) were obtained for the 2017 campaign, at a high incidence angle (49.5°) of TerraSAR-X, and for the 2018 campaign, at a mid-incidence angle (36.1°) of TanDEM-X 1–2 days after the acquisition of the DSMs. The sea ice drifted during the time between the SAR and DSM acquisitions. As it is difficult to directly co-register the DSM to SAR owing to the difference in spatial resolution, the two datasets were geometrically matched using unmanned aerial vehicle (4 cm resolution) and helicopter-borne (30 cm resolution) photographs acquired as part of the ice campaigns. A total of five dual-polarimetric SAR features―backscattering coefficients at HH and VV polarizations, co-polarization ratio, co-polarization phase difference, and co-polarization correlation coefficient ―were computed from the dual-polarimetric SAR data and compared to the RMS height of the sea ice, which showed macroscale surface roughness. All the SAR features obtained at the high incidence angle were statistically weakly correlated with the RMS height of the sea ice, possibly influenced by the low backscattering close to the noise level that is attributed to the high incidence angle. The SAR features at the mid-incidence angle showed a statistically significant correlation with the RMS height of the sea ice, with Spearman’s correlation coefficient being higher than 0.7, except for the co-polarization ratio. Among the intensity-based and polarimetry-based SAR features, HH-polarized backscattering and co-polarization phase difference were analyzed to be the most sensitive to the macroscale RMS height of the sea ice. Our results show that the X-band dual-polarimetric SAR at mid-incidence angle exhibits potential for estimation of the macroscale surface roughness of the first-year sea ice with dry snow cover in summer.     

TBT toxicity on the marine microalga Nannochloropsis oculata

Commercial antifouling formulations containing TBT are the major source of organotin contamination in coastal waters. In view of the persisting TBT residues (13 ng Sn l⁻¹) in the coastal waters of South Korea, an attempt has been made to evaluate the growth response and biochemical composition of laboratory-cultured Nannochloropsis oculata to TBT toxicity. It is evident that the persisting concentration level of TBT is high enough to cause adverse effect on the microalgal species. The EC₅₀ (24 h) was found to be at 0.89 nM level of TBT for this marine eustigmatophyte N. oculata. Photosynthetic pigment content was significantly affected. At elevated TBT concentrations of 1.0 nM, especially pronounced changes in biochemical composition was found. TBT tolerance of N. oculata and its growth as well as biochemical responses are discussed.     

A method of calculating the non‐linear seismic response of a building braced with viscoelastic dampers

Buildings are continually subject to dynamic loads, such as wind load, seismic ground motion, and even the load from internal utility machines. The recent trend of constructing more flexible high‐rise buildings underscores the importance of including viscoelastic dampers in building designs. Viscoelastic dampers are used to control the dynamic response of a building. If the seismic design is based only on the linear response spectrum, considerable error may occur when calculating the seismic response of a building; rubber viscoelastic dampers show non‐linear hysteretic damping that is quite different from viscous damping. This study generated a non‐linear response spectrum using a non‐linear oscillator model to simulate a building with viscoelastic dampers installed. The parameters used in the non‐linear damper model were obtained experimentally from dynamic loading tests. The results show that viscoelastic dampers effectively reduce the seismic displacement response of a structure, but transmit more seismic force to the structure, which essentially increases its seismic acceleration response. Copyright © 2003 John Wiley & Sons, Ltd.     

Adsorption of organic matter at mineral/water interfaces: I. ATR-FTIR spectroscopic and quantum chemical study of oxalate adsorbed at boehmite/water and corundum/water interfaces

The types and structures of adsorption complexes formed by oxalate at boehmite (γ-AlOOH)/water and corundum (α-Al₂O₃)/water interfaces were determined using in situ attenuated total reflectance fourier transform infrared (ATR-FTIR) spectroscopy and quantum chemical simulation methods. At pH 5.1, at least four different oxalate species were found at or near the boehmite/water interface for oxalate surface coverages (Γ_ox) ranging from 0.25 to 16.44 μmol/m². At relatively low coverages (Γ_ox < 2.47), strongly adsorbed inner-sphere oxalate species (IR peaks at 1286, 1418, 1700, and 1720 cm⁻¹) replace weakly adsorbed carbonate species, and a small proportion of oxalate anions are adsorbed in an outer-sphere mode (IR peaks at 1314 and 1591 cm⁻¹). IR peaks indicative of inner-sphere adsorbed oxalate are also observed for oxalate at the corundum/water interface at Γ_ox = 1.4 μmol/m². With increasing oxalate concentration (Γ_ox > 2.47 μmol/m²), the boehmite surface binding sites for inner-sphere adsorbed oxalate become saturated, and excess oxalate ions are present dominantly as aqueous species (IR peaks at 1309 and 1571 cm⁻¹). In addition to these adsorption processes, oxalate-promoted dissolution of boehmite following inner-sphere oxalate adsorption becomes increasingly pronounced with increasing Γ_ox and results in an aqueous Al(III)-oxalate species, as indicated by shifted IR peaks (1286 → 1297 cm⁻¹ and 1418 → 1408 cm⁻¹). At pH 2.5, no outer-sphere adsorbed oxalate or aqueous oxalate species were observed. The similarity of adsorbed oxalate spectral features at pH 2.5 and 5.1 implies that the adsorption mechanism of aqueous HOx⁻ species involves loss of protons from this species during the ligand-exchange reaction. As a consequence, adsorbed inner-sphere oxalate and aqueous Al(III)-oxalate complexes formed at pH 2.5 have coordination geometries very similar to those formed at pH 5.1.The coordination geometry of inner-sphere adsorbed oxalate species was also predicted using quantum chemical geometry optimization and IR vibrational frequency calculations. Geometry-optimized Al₈O₁₂ and Al₁₄O₂₂ clusters with the reactive surface Al site coordinated by three oxygens were used as model substrates for corundum and boehmite surfaces. Among the models considered, calculated IR frequencies based on a bidentate side-on structure with a 5-membered ring agree best with the observed frequencies for boehmite/oxalate/water samples at Γ_ox = 0.25 to 16.44 μmol/m² and pH 2.5 and 5.1, and for a corundum/oxalate/water sample at Γ_ox = 1.4 μmol/m² and pH 5.1. Based on these results, we suggest that oxalate bonding on boehmite and corundum surfaces results in 5-coordinated rather than 4- or 6-coordinated Al surface sites.     

Assessment of groundwater chemistry in a coastal region (Kunsan, Korea) having complex contaminant sources: a stoichiometric approach

Groundwater chemistry in a coastal region (Kunsan, Korea) having complex contaminant sources was investigated. Water analysis data for 197 groundwater samples collected from the uniformly distributed sixty-six wells were used. Chemical analysis results indicate that groundwaters show wide concentration ranges in major inorganic ions, reflecting complex hydrochemical processes. Due to the complexity of groundwater chemistry, the samples were classified into four groups based on Cl and NO₃ concentrations and the processes controlling water chemistry were evaluated based on the reaction stoichiometry. The results explained the importance of mineral weathering, anthropogenic activities (nitrification and oxidation of organic matters), and Cl-salt inputs (seawater, deicer, NaCl, etc.) on groundwater chemistry. It was revealed that mineral dissolution is the major process controlling the water chemistry of the low Cl and NO₃ group (Group 1). Groundwaters high in NO₃ (Groups 2 and 4) are acidic in nature, and their chemistry is largely influenced by nitrification, oxidation of organic matters and mineral dissolution. In the case of chloride rich waters (Group 3), groundwater chemistry is highly influenced by mineral weathering and seawater intrusion associated with cation-exchange reactions.     

Capturing the heterogeneity of urban growth in South Korea using a latent class regression model

This study aims to analyze the spatial patterns of urban growth in South Korea between 2000 and 2010. Fourteen suspected causative independent variables were selected and latent class regression (LCR) was used to analyze the relationship between dependent (urban growth) and independent (causative) variables. The goodness‐of‐fit was assessed by comparison to logistic regression (LR) analysis. The LR analysis produced consistent coefficients for each independent variable across the study area. In contrast, an LCR analysis, with a three‐class assumption, resulted in a different magnitude and directional effects of the coefficients for each class. The LCR analysis enabled the identification of both spatially homogeneous and heterogeneous areas. In addition, the LCR analysis performed better than the LR analysis with a lower Akaike information criterion and Bayesian information criterion value, and a higher receiver operating characteristic value. We conclude that LCR analysis should be used to establish causative “driving” factors for efficient urban growth planning and urban spatial policy.     

Impact of UV-A radiation on erythemal UV and UV-index estimation over Korea

Because total UV(TUV) in the UV-A region is 100 times higher than in the UV-B region,UV-A is a considerable component when calculating erythemal UV(EUV) and UV-index.The ratio of EUV to TUV in the UV-A value [EUV(A)/TUV(A)]is investigated to convert the EUV(A) from TUV(A) for broadband observation. The representative value of EUV(A)/TUV(A),from the simulation study,is 6.9 × 10-4,changing from 6.1 × 10-4to 7.0 × 10-4as aerosol optical depth,total ozone and solar zenith angle change. By adopting the observational data of EUV(B) and TUV(A) from UV-biometer measurements at Yonsei University [(37.57?N,126.95?E),84 m above sea level],the EUV irradiance increases to 15% of EUV(B) due to the consideration of EUV(A) from the data of TUV(A) observation. Compared to the total EUV observed from the Brewer spectrophotometer at the same site,the EUV(B) from the UV-biometer observes only 95% of total EUV,and its underestimation is caused by neglecting the effect of UV-A. However,the sum of EUV(B) and EUV(A) [EUV(A+B)] from two UV-biometers is 10% larger than the EUV from the Brewer spectrophotometer because of the spectral overlap effect in the range 320–340nm. The correction factor for the overlap effect adjusts 8% of total EUV.     

Geology, Mineralogy and Geochemistry of Carbonate Replacement-Type Lead-Zinc-Silver Deposits in Janggun Mine, Republic of Korea

INTRODUCTIONThe Janggun mine,Republic of Korea,is located in thesoutheast of the Seoul,about latitude36°5 1′N and longitude12 9°0 4′E. In this mine area is situated the Bonghwa m ineral-ized zone of the Taebaegsan mining district,Korea.The geo-logic setting of the region was described as the Samgeum riQuadrangle(Kim et al.,196 2 ) .The general and local geolo-gy near the mine area have been studied by L ee (196 7) ,Hwang and Reedman(1975 ) .This mine consists of four min-eral de…     

Fatigue strength assessment of MARK-III type LNG cargo containment system

The aim of this paper is to investigate the fatigue strength of the GTT Mark-III type LNG insulation system. The LNG insulation system consists of several composite layers with various connections; plywood, triplex, reinforced polyurethane foam and mastic. Consequently, the LNG insulation system may include mechanical failures such as cracks as well as delaminations within the layers due to sloshing impact loads and fatigue loadings. In addition, these failures may cause a significant decrease of structural integrity. In this study, a series of fatigue tests have been carried out for Mark-III type LNGC insulation systems at room temperature considering the effect of sloshing impact. The load levels have been determined based on the ultimate strength of reinforced polyurethane foam. The aim of the study is to investigate the typical failure characteristics of the MARK-III LNG insulation system and to obtain the S–N data under fatigue loading. A consolidated single S–N curve is obtained based on a systematic finite element procedure. Future use of the S–N data in fatigue analysis requires that the response analysis is carried out using a finite element model with the same mesh density and material properties. This study can be used as a fundamental study for the fatigue assessment of the LNGC insulation system as well as a design guideline.