Hydrochemistry of groundwaters in a spa area of Korea: an implication for water quality degradation by intensive pumping

A geochemical study was carried out in a small spa area (Onyang Spa, Korea) where intensive pumping of deep thermal groundwater (1 300 000 m³ year⁻¹) is taking place. This has caused the deep fractures to lose their artesian pressure and the upper shallow fractures have been encroached by shallow, cold waters. To quantify the influence of long‐term heavy pumping on the quality of the geothermal water, groundwater sampling and chemical analysis, water‐level measurement, and well loggings were performed for the selected deep thermal wells and shallow cold wells. Chemical analysis results indicate a big contrast in water chemistry and origins between the two water types. Shallow groundwater shows a wider concentration ranges in solutes that are closely related to human activity, illustrating the water's vulnerability to contamination near the land surface. Plots of water chemistry as a function of fluoride reveal that the quality of the thermal water was greatly influenced by the shallow, cold groundwater and that intensive pumping of the deep thermal groundwater has caused the introduction of shallow groundwater into the deeper fractures. Although the deep and the shallow fractures were piezometrically separated to some extent, a mixing model based on fluoride and nitrate indicated that the cold‐water fractions in the thermal wells are up to 50%. This suggests that the thermal water is faced with water quality degradation by the downward flow of the shallow, cold water. Restriction on the total of all the pumpage permits per unit area is suggested to restore the artesian pressure of the deep thermal aquifer and to prevent cold‐water intrusion in the study area. Copyright © 2004 John Wiley & Sons, Ltd.     

The differentiated impact of emissions trading system based on company size

Most countries implementing an emissions trading system (ETS), such as EU member states, California in the US, or South Korea, are generally targeting large sized companies, which consume energy above a specific threshold. However, previous studies using computable general equilibrium (CGE) models have analyzed climate policies without considering company size. This may have led to inaccurate results because the impacts of climate policy would differ depending on the coverage of regulated companies. Accordingly, this study examines the environmental and economic impacts of greenhouse gas emission reduction policies, assuming policy results vary by firm size, as covered by the Korean emission trading system. To this end, a CGE model with a separate social accounting matrix based on company size is used to compare three scenarios that reflect different types of carbon pricing methods. The results show that greenhouse gases will be reduced to a lower extent and utility will decrease more if mitigation policies are only imposed to large companies.

Key policy insights

• Carbon pricing policies should consider the different impacts on companies of different sizes and industry sectors.

• Without considering the different sizes of companies covered by an ETS, the expected carbon price and its economic impact will be underestimated.

• Small and medium-sized companies will face more negative impacts than large companies in some industry sectors under an ETS, even if the mitigation burden is only faced by large companies.

     

Under-ice measurements of suspended particulate matters using ADCP and LISST-Holo

Ocean Science Journal - Using a mooring package comprising an acoustic Doppler current profiler (ADCP) and holographic imaging system, a 1-day ice camp study was performed under the Arctic sea ice...     

The simulation of aerosol transport over East Asia region

This study was carried out to understand the contribution of PM10 from China emission to Seoul Metropolitan Area (SMA) during high concentration period in January, 2007. The hourly PM10 concentration in Seoul Metropolitan Area had reached up to over 150 μg/m³ on 17th and 23rd of January in 2007. The aerosol transports from China along the Northwestern wind becomes the background concentrations in Korea and the assessment of the amount of contribution from China is very important in managing the air quality improvement plan in SMA.The U.S. EPA's Models-3/CMAQ (Community Multiscale Air Quality) was used to simulate PM10 concentration. The CMAQ performance was evaluated by comparing with the measurements in SMA for the episode period. The predictions were relatively in a good agreement with the measurements.The results show that the PM10 transport from China to Korea is significant and its contribution reaches up to 80% in the episode period. In order to assess more extensively the aerosol transport in East Asia region, the study to run the model in full year with speciated PM component measurements in super site is underway.     

Mineralogical, fluid inclusion, and stable isotope constraints on mechanisms of ore deposition at the Samgwang mine (Republic of Korea)—a mesothermal, vein-hosted gold–silver deposit

The Samgwang mine is located in the Cheongyang gold district (Cheonan Metallogenic Province) of the Republic of Korea. It consists of eight massive, gold-bearing quartz veins that filled NE- and NW-striking fractures along fault zones in Precambrian granitic gneiss of the Gyeonggi massif. Their mineralogy and paragenesis allow two separate vein-forming episodes to be recognized, temporally separated by a major faulting event. The ore minerals occur in quartz and calcite of stage I, associated with fracturing and healing of veins. Hydrothermal wall-rock alteration minerals of stage I include Fe-rich chlorite (Fe/(Fe+Mg) ratios 0.74-0.81), muscovite, illite, K-feldspar, and minor arsenopyrite, pyrite, and carbonates. Sulfide minerals deposited along with electrum during this stage include arsenopyrite, pyrite, pyrrhotite, sphalerite, marcasite, chalcopyrite, galena, argentite, pyrargyrite, and argentian tetrahedrite. Only calcite was deposited during stage II. Fluid inclusions in quartz contain three main types of C–O–H fluids: CO₂-rich, CO₂–H₂O, and aqueous inclusions. Quartz veins related to early sulfides in stage I were deposited from H₂O–NaCl–CO₂ fluids (1,500–5,000 bar, average 3,200) with T _htotal values of 200°C to 383°C and salinities less than about 7 wt.% NaCl equiv. Late sulfide deposition was related to H₂O–NaCl fluids (140–1,300 bar, average 700) with T _htotal values of 110°C to 385°C and salinities less than about 11 wt.% NaCl equiv. These fluids either evolved through immiscibility of H₂O–NaCl–CO₂ fluids as a result of a decrease in fluid pressure, or through mixing with deeply circulated meteoric waters as a result of uplift or unloading during mineralization, or both. Measured and calculated sulfur isotope compositions (δ³⁴S_H2S = 1.5 to 4.8‰) of hydrothermal fluids from the stage I quartz veins indicate that ore sulfur was derived mainly from a magmatic source. The calculated and measured oxygen and hydrogen isotope compositions (δ¹⁸O_H2O = −5.9‰ to 10.9‰, δD = −102‰ to −87‰) of the ore-forming fluids indicate that the fluids were derived from magmatic sources and evolved by mixing with local meteoric water by limited water–rock exchange and by partly degassing in uplift zones during mineralization. While most features of the Samgwang mine are consistent with classification as an orogenic gold deposit, isotopic and fluid chemistry indicate that the veins were genetically related to intrusions emplaced during the Jurassic to Cretaceous Daebo orogeny.     

Instability of an underground ancient tomb due to excavation and its relationship to the temperature and ground water

In order to consider a counterplan to preserve an ancient royal tomb in Kongju, Korea, the deformation of the wall structure, the atmospheric temperature in the tomb, and the groundwater level have been monitored. The long-term measurement of biaxial tilting of the tomb walls revealed that the brick-built subsurface opening had been subjected to severe structural instability. The measured deformation of the tomb was consistent with the displacement of soil around the tomb calculated using a numerical analysis. The instability of the tomb structure is closely related to the rainy season as the deformations measured are several times that in the dry season. A sudden change of temperature inside the tomb exerted an influence on the deformation of the tomb structure as well. It is suggested that the excavation be restored for tourists, the quicklime layer for preventing groundwater infiltration is reinforced, and a constant temperature is kept inside the tomb. This revised version was published online in July 2006 with corrections to the Cover Date.     

Genetic environment of germanium-bearing gold-silver vein ores from the Wolyu mine,Republic of Korea

The Wolyu mine is one of the largest vein-type gold-silver-bearing epithermal systems in the Youngdong district and is the first gold-silver deposit in Korea found to contain significant germanium, in the form of argyrodite (Ag₈GeS₆). Mineralized veins (78.9 ± 1.2 Ma) crosscutting Late Cretaceous hostrock tuff and quartz porphyry (81.5 ± 1.8 Ma) consist of three stages of quartz and carbonates, the first of which contains pyrite, basemetal sulfides and Au-Ag-minerals. Stage I Au-Ag-Ge-mineralized veins show a systematic variation of mineral assemblage with time: (1) quartz + pyrite; (2) quartz + pyrite + sphalerite + electrum + argentite; (3) carbonate + quartz + sphalerite + electrum + argentite; (4) carbonate + native silver + argentite + Ag-sulfosalts + argyrodite + sphalerite. Calculated values of temperature and sulfur activity are: assemblage (1), 360-280°C and 10^–7-10^–10; (2), 280-210°C and 10^–10-10^–14; (3), 210-180°C and 10^–14-10^–16; (4), 180-155°C and 10^–17-10^–18. These data, the frequent association of gold with sulfides, and the abundance of pyrite in alteration zones indicate that decreasing sulfur activity and cooling were important in triggering gold deposition. Hydrogen and oxygen isotope compositions of ore fluids display a systematic variation with increasing time. Within the main Ag-Au-Ge mineralization, D and ¹⁸O values decrease with the transition from quartz to carbonate deposition (from -78 and –2.8% to –90 and –8.7%., respectively), indicating increasing involvement (mixing) of less evolved meteoric water which resulted in progressive cooling and dilution of ore fluids in the shallow ( 370–600 m) Wolyu epithermal system.     

A new proposition for redating the Mithraic tauroctony scene

Assuming that the figures of the central icon of the Mithraic cult – the scene of tauroctony (bull slaying) – represent equatorial constellations at the time when the spring equinox was placed somewhere between Taurus and Aries, it is difficult to explain why some equatorial constellations (Orion and Libra) were not included in the Mithraic icons A simulation of the sky at the times in which the spring equinox was in the constellation of Taurus, only a small area of spring equinox positions permits to exclude these two constellations, with all other representations of equatorial constellations (Taurus, Canis Minor, Hydra, Crater, Corvus, Scorpio) included. These positions of the spring equinox occurred at the beginning of the age of Taurus, and included Gemini as an equatorial constellation. Two of the main figures in the Mithraic icons are two identical figures, usually represented on the each side of the bull, wearing phrygian caps and holding torches. Their names, Cautes and Cautopates, and their looks may indicate that they represent the constellation of Gemini. In that case the main icon of Mithraic religion could represent an event that happened around 4000 BC, when the spring equinox entered the constellation of Taurus. Also, this position of equator contains Perseus as an equatorial constellation. Ulansey suggested that the god Mithras is identified with the constellation Perseus. In that case, all figures in the main scene would be equatorial constellations.