Soft-sediment deformation structures interpreted as seismites in the uppermost Aptian to lowermost Albian transgressive deposits of the Chihuahua basin (Mexico)

Several levels of soft-sediment deformation structures (s.-s.d.s.) cut by synsedimentary normal faults have been observed in the transition beds between the “Las Vigas” and “La Virgen” formations (Cretaceous) in the northeastern part of the Chihuahua basin in Mexico. These structures consisted of four kinds of motifs (floating breccias, flame-like structures, large pillow structures, and wavy structures). They are restricted to five “stratigraphic” levels (Σ1–Σ5) and surrounded by undeformed beds in fluvio-lacustrine and tidal deposits and can be traced over a distance of several hundred meters. This deformation is interpreted to have resulted from the combined effects of liquidization and shear stress in soft-sediments due to local earthquakes in the area which could have been generated during the rifting stage of the Chihuahua basin. New constraints placed on the age of the “Las Vigas” Formation (bracketed by Late Aptian charophytes at the bottom and colomiellids of late Aptian to earliest Albian age at the top) suggest that this synrift tectonism lasted at least until the end of the Aptian.     

Chemical evidence of water movements in the deepest part of Lake Leman (Lake Geneva)

Regular surveys of bottom water chemistry (SiO₂, O₂, Fe, Mn) have been carried from 1978 to 1986 in the deepest 30 m of Lake Léman (max. depth 309 m) including interface waters sampled with a Jenkins Mortimer corer. When compared to normal chemical gradients near bottom, i.e. O₂ decrease and SiO₂ increase, three types of anomalies (lens, interface, and behaviour) have been observed on O₂ and SiO₂, the most sensitive chemical species. These anomalies were found throughout the year, in several stations of the deepest part of the lake and even along the slope of the lake basin. Major anomalies (O₂ + 3 to 10 mg ·l^–1; SiO₂ -1 to 2 mg·l^–1) were generally found at the sediment water interface and may extend 10–20 m above the sediment and last 10 weeks. Others marked lens anomalies could be observed for 3 to 4 months. Several mechanisms are probably responsible for this injection of surface waters along the lake slope (accumulation of turbid water on lake banks after severe windstorms; river density currents due to temperature and/or turbidity difference with lake waters). These water-inputs do not represent important volumes ( 1% total lake volume) but, when occuring at the interface, they ensure a sufficient oxygen level to prevent diffusion of phosphate and ammonia from pore waters when winter lake overturns do not reach bottom layers (from 1972 to 1980). Complete overturns, as observed in 1980/81, are connected with major interface anomalies (bottom O₂ moves up from 2 to 10 mg·l^–1) occuring before surface mixing reaches the deepest layers.     

Composition and spatial organization of a cold seep community on the South Barbados accretionary prism: Tectonic, geochemical and sedimentary context

Deep faunal assemblages were observed on cold seeps, between 1000 and 2000m depth, along the southern termination of the Barbados accretionary prism, during the Caracolante II and Diapicar cruises. Faunal composition and microdistribution of a cold seep community were analyzed at one site using deep-sea photographs and seismic (3.5 Kz) profiles. The community is dominated by large mussels up to 20cm long (possibly related to the genus Bathymodiolus), tiny vesicomyid clams, and vestimentiferan clusters in which animals are up to 2m long. There is a high density of sponges (three species), bryozoans and gorgonians. Other taxa occasionally associated with this assemblage include galatheid crabs, anemones, holothurians and possibly pennatulaceans which are numerous at boundaries of the site. A typical deep-sea fauna of fish, asteroids and ophiuroids is also scattered about the vicinity. This seep community is distributed as a band of discontinuous colonies, 40–50m in width and more than 10km in length. Living colonies alternate with accumulations shells and bare areas. The substratum is hard mud covered by a ferrugineous crust and cemented by carbonates. The early diagenetic character of the bottom and the occurrence of biological assemblages indicate that seepages of sulphur and/or methane, which have been revealed along the decollement zone of the Barbados prism, must diffuse through the sea floor. These biological and geological features are located on the crests of NE-SW anticlinal ridges and mud volcanoes which have been built by diaprism.     

Periglacial geoarchaeology at the Dog Creek site,Northern Yukon

The Dog Creek archaeological site (NcVi‐3), located in the northern Yukon, provides evidence of complex site transformational processes related to microclimatic conditions occurring since the mid‐Holocene. Geoarchaeological research at Dog Creek sought to interpret site formation processes in order to understand the relationship between surficial artifacts, buried artifacts, and stratified sediments. It also attempted to reconstruct the periglacial processes that were active in transforming the site and their relationships to microclimatic conditions. Sedimentology and fabric analysis show that artifacts were buried by solifluction and disturbed by frost heave and cryoturbation. Radiocarbon dating and pollen analysis demonstrated that solifluction took place approximately 5200–2000 years ago when a spruce forest existed at the site. This evidence suggests an onset of cooling conditions that continues to the present. After the mid‐Holocene, the spruce treeline began to move south toward its present position. © 2001 John Wiley & Sons, Inc.     

Evaluation of Zerovalent Zinc for Treatment of 1,2,3‐Trichloropropane‐Contaminated Groundwater: Laboratory and Field Assessment

The efficacy and feasibility of using zerovalent zinc (ZVZ) to treat 1,2,3‐trichloropropane (TCP)‐contaminated groundwater was assessed in laboratory and field experiments. In the first portion of the study, the reactivity of commercially available granular ZVZ toward TCP was measured in bench‐scale batch‐reactor and column experiments. These results were used to design columns for on‐site pilot‐scale treatment of contaminated groundwater at a site in Southern California. Two of the ZVZ materials tested were found to produce relatively high rates of TCP degradation as well as predictable behavior when scaling from bench‐scale to field testing. In addition, there was little decrease in the rates of TCP degradation over the duration of field testing. Finally, no secondary impacts to water quality were identified. The results suggest that ZVZ may be an effective and feasible material for use in engineered treatment systems, perhaps including permeable reactive barriers.     

Improving estuarine net flux estimates for dissolved cadmium export at the annual timescale: Application to the Gironde Estuary

Dissolved Cd (Cd_D) concentrations along the salinity gradient were measured in surface water of the Gironde Estuary during 15 cruises (2001–2007), covering a wide range of contrasting situations in terms of hydrology, turbidity and season. During all situations dissolved Cd concentrations displayed maximum values in the mid-salinity range, reflecting Cd addition by chloride-induced desorption and complexation. The daily net Cd_D fluxes from the Gironde Estuary to the coastal ocean were estimated using Boyle's method. Extrapolating Cd_D concentrations in the high salinity range to the freshwater end member using a theoretical dilution line produced 15 theoretical Cd concentrations (Cd_D⁰), each representative of one distinct situation. The obtained Cd_D⁰ concentrations were relatively similar (201 ± 28 ng L⁻¹) when freshwater discharge Q was >500 m³ s⁻¹ (508 ≤ Q ≤ 2600 m³ s⁻¹), but were highly variable (340 ± 80 ng L⁻¹; 247–490 ng L⁻¹) for low discharge situations (169 ≤ Q ≤ 368 m³ s⁻¹). The respective daily Cd_D net fluxes were 5–39 kg day⁻¹, mainly depending on freshwater discharge. As this observation invalidates the existing method of estimating annual Cd_D net fluxes, we proposed an empirical model, using representative Cd_D⁰ values and daily freshwater discharges for the 2001–2007 period. Subsequent integration produced reliable Cd_D net flux estimates for the Gironde Estuary at the annual timescale that ranged between 3.8–5.0 t a⁻¹ in 2005 and 6.0–7.2 t a⁻¹ in 2004, depending on freshwater discharge. Comparing Cd_D net fluxes with the incoming Cd_D fluxes suggested that the annual net Cd_D addition in the Gironde Estuary ranged from 3.5 to 6.7 t a⁻¹, without any clear temporal trend during the past seven years. The annual Cd_D net fluxes did not show a clearly decreasing trend in spite of an overall decrease by a factor 6 in Cd gross fluxes during the past decade. Furthermore, in six years out of seven (except 2003), the annual Cd_D net fluxes even exceeded river borne total (dissolved + particulate) gross Cd fluxes into the estuary. These observations were attributed to progressive Cd desorption from both suspended particles and bottom sediment during various sedimentation–resuspension cycles induced by tidal currents and/or continuous dredging (navigation channel) and diverse intra-estuarine sources (wet deposition, urban sources, and agriculture). Provided that gross fluxes remain stable over time, dissolved Cd exportation from the Gironde Estuary to the coastal ocean may remain at the present level for the coming decade and the estuarine sedimentary Cd stock is forecast to decrease slowly.     

Dissolved uranium, vanadium and molybdenum behaviours during contrasting freshwater discharges in the Gironde Estuary (SW France)

Understanding trace metal behaviour in estuarine environments requires sampling strategies and analytical methods adapted to strong physical and geochemical gradients. In this study, we present a specific sampling strategy covering a wide range of hydrological conditions during nine cruises in 2003–2007 to characterise the behaviour of three dissolved metals (uranium, vanadium and molybdenum) in surface and bottom water along the salinity gradient of the highly turbid macrotidal Gironde Estuary using a solid–liquid extraction. Uranium behaved conservatively whatever the water discharges observed. The slight dissolved U depletion compared to the theoretical dilution line between the fluvial and marine end-members occasionally observed in the low salinity range (0–3) was attributed to the mixing of different water bodies of the Gironde tributaries. In contrast, dissolved V behaviour was largely influenced by the hydrological conditions, showing increasingly pronounced addition with decreasing freshwater discharges, (i.e. increasing residence times of water and particles in the estuary). This addition of dissolved V in the low- to mid-salinity range was attributed to desorption processes observed in the Maximum Turbidity Zone (MTZ). The distribution of dissolved Mo concentrations along the salinity gradient was highly variable. Apparent conservative, and non-conservative behaviours were observed and were related to the concomitance of desorption from SPM, inputs from sediments for additive distribution and biological uptake and removal into sediments for subtractive distribution. Based on the whole database (2003–2007), annual net fluxes to the coastal ocean were estimated for dissolved U (15.5–16.6 t yr⁻¹) and V (31.3–36.7 t yr⁻¹).     

Distribution and reactivity of oxyanions (Sb, As, V, Mo) in the surface freshwater reaches of the Gironde Estuary (France)

The present work reports on the temporal variations of Sb, As, V and Mo concentrations in the surface freshwater reaches of the Gironde Estuary (SW France). Dissolved (<0.2 and <0.02 μm) and particulate Sb, As, V and Mo concentrations were measured in samples collected with high temporal resolution (every 30 min) during two consecutive tides at a fixed station located upstream of the city of Bordeaux and the maximum turbidity zone (MTZ). In addition, measurements of suspended particulate matter concentration, physico-chemical parameters, Cl⁻ concentration, water depth, current velocity and particulate Th concentration were performed either at the same time resolution or continuously. The data obtained suggested that variations in particulate As, V and Mo concentrations were most probably related to tidal cycling near the sampling site of fine grained particles from the MTZ located downstream. Significant differences in the behavior of the dissolved target oxyanions, mostly present in the <0.02 μm fraction, occurred. The behavior of Sb was conservative. Variations of the dissolved As and V concentrations showed similar cycling trends, strongly related to tidal cycles. These As and V cycles were interpreted as a mixing between upstream freshwater and downstream water enriched in dissolved As and V by desorption from the MTZ particles. The observed trend in the variation of the dissolved Mo was more complex than that of As and Sb and attributed to the mixing of the water bodies mentioned above coupled to a point source input of dissolved Mo from an intra-estuarine source. The contribution of this suspected Mo source to the dissolved Mo concentrations measured at the sampling site was estimated from the ratio of dissolved Mo to dissolved As concentrations. The additional dissolved Mo signal, coupled to the monitored ebb and flood length and associated current velocities, suggested an anthropogenic input which may derive from industrial activity near the city of Bordeaux. Extrapolating these results to the annual scale suggested that this dissolved Mo may be equivalent to 45-90% of the annual dissolved Mo flux into the Garonne Branch, highlighting the importance to further investigate the origin and behavior of Mo in the fluvial estuary near Bordeaux.     

Thermoddem: A geochemical database focused on low temperature water/rock interactions and waste materials

The development of Thermoddem, a thermodynamic database devoted to geochemical modelling for environmental studies in general and, more specifically, to chemical systems involving waste materials, is discussed here. Concerns are also focused on taking into account some specific needs for modellers by proposing different output formats and some important information concerning the solid phases, the transformation path, paragenesis and insights into crystallographic details. This additional information aims to avoid considering phases that may not be “active” under current environmental conditions. The database is especially devoted to environmental applications, ranging from waste material management to pollutant behaviour, including the context of deep underground disposal. Selection rules and conventions are illustrated through the example of the Fe-water system, while a second example details the relationships between low and high ionic strength media, from the point of view of thermodynamic databases. Technical aspects concerning the development of a management information system for Thermoddem and its availability on the web (http://thermoddem.brgm.fr) are also provided.     

Study of solar system planetary lightning with LOFAR

Radio signatures of lightning discharges have been detected by the Voyager spacecraft near Saturn and Uranus up to 40 MHz. Corresponding flux densities at the distance of the Earth are up to 1000 Jansky (Jy) for Saturn (1 event per minute above 50 Jy, with 30–300 ms duration) and up to a few tens of Jansky for Uranus. Low Frequency ARray LOFAR will allow us to detect and monitor the lightning activity at these two planets. Imaging will allow us to locate lightning sources on Saturn's disk (even if with moderate accuracy), which could then be correlated to optical imaging of clouds. Such observations could provide new information on electrification processes, atmospheric dynamics, composition, and geographical and seasonal variations, compared to the Earth. In addition, lightning may play a role in the atmospheric chemistry, through the production of non-equilibrium trace organic constituents potentially important for biological processes. LOFAR observations can also help us to assess the existence of lightning at Neptune (marginally detected by Voyager), at Venus (where their existence is very controversial), and at Mars (possibly resulting from dust cloud charging). At Jupiter, low-altitude ionospheric layers of meteoritic origin and/or intrinsically long discharge duration seem to prevent the emission and escape of high-frequency radio waves associated with lightning. LOFAR thus presents good possibilities for the detection and study of solar system planetary lightning; we also discuss its relevance to bring new information on Terrestrial lightning-related upper atmosphere transient phenomena (sprites, TIPPs…). Instrumental constraints are outlined.