Deformation history of the Naraku Batholith,Mt Isa Inlier,Australia: Implications for pluton ages and geometries from structural study of the Dipvale Granodiorite and Levian Granite

Plutons of the Naraku Batholith were emplaced into Proterozoic metasediments of the northern portion of the Eastern Fold Belt of the Mt Isa Inlier during two intrusive episodes approximately 200 million years apart. Structural relationships and geochronological data suggest that the older plutons (ca 1750 Ma) are contemporaneous with granites of the Wonga Batholith to the west. The Dipvale Granodiorite and the Levian Granite represent these older intrusive phases of the Naraku Batholith, and both contain an intense tectonic foliation, S₁, which is interpreted to have formed during the north‐south shortening associated with D₁ of the Isan Orogeny. The geometry of S₁ form surfaces at the southern end of the Dipvale Granodiorite, and of the previously unrecognised sheeted contact, defines a macroscopic, steeply south‐southwest‐plunging antiform, which was produced by the regional D₂ of the Isan Orogeny. S₁ form surfaces in the Levian Granite define open F₂ folds with wavelengths of several hundred metres. The structural age of emplacement of the Dipvale Granodiorite and the Levian Granite is interpreted to be pre‐ or syn‐ the regional D₁. An intense foliation present in some of the younger (ca 1505 Ma) granites that comprise the bulk of the Naraku Batholith is interpreted to represent S₃ of the Isan Orogeny. Foliations commonly have similar styles and orientations in both the pre‐D₁ and younger plutons. This emphasises the simplicity with which regional fabrics can be, and probably have been, miscorrelated in the Eastern Fold Belt, and that the classification of granites in general on the basis of structural and geometric criteria alone is fraught with danger.     

The AD 1362 Öræfajökull eruption,S.E. Iceland: Physical volcanology and volatile release

The explosive rhyolitic eruption of Öræfajökull volcano, Iceland, in AD 1362 is described and interpreted based on the sequence of pyroclastic fall and flow deposits at 10 proximal locations around the south side of the volcano. Öræfajökull is an ice-clad stratovolcano in south central Iceland which has an ice-filled caldera (4–5 km diameter) of uncertain origin. The main phase of the eruption took place over a few days in June and proceeded in three main phases that produced widely dispersed fallout deposits and a pyroclastic flow deposit. An initial phase of phreatomagmatic eruptive activity produced a volumetrically minor, coarse ash fall deposit (unit A) with a bi-lobate dispersal. This was followed by a second phreatomagmatic, possibly phreatoplinian, phase that deposited more fine ash beds (unit B), dispersed to the SSE. Phases A and B were followed by an intense, climactic Plinian phase that lasted ∼ 8–12 h and produced unit C, a coarse-lapilli, pumice-clast-dominated fall deposit in the proximal region. At the end of Plinian activity, pyroclastic flows formed a poorly-sorted deposit, unit D, presently of very limited thickness and exposed distribution. Much of Eastern Iceland is covered with a very fine distal ash layer, dispersed to the NE. This was probably deposited from an umbrella cloud and is the distal representation of the Plinian fallout. A total bulk fall deposit volume of ∼ 2.3 km³ is calculated (∼ 1.2 km³ DRE). Pyroclastic flow deposit volumes have been crudely estimated to be < 0.1 km³. Maximum clast size data interpreted by 1-D models suggests an eruption column ∼ 30 km high and mass discharge rates of ∼ 10⁸ kg s^− 1. Ash fall may have taken place from heights around 15 km, above the local tropopause (∼ 10 km), with coarser clasts dispersed below that under a different wind regime. Analyses of glass inclusions and matrix glasses suggest that the syn-eruptive SO₂ release was only ∼ 1 Mt. This result is supported by published Greenland ice-core acidity peak data that also suggest very minor sulphate deposition and thus SO₂ release. The small sulphur release reflects the low sulphur solubility in the 1362 rhyolitic melt. The low tropopause over Iceland and the 30-km-high eruption column certainly led to stratospheric injection of gas and ash but little sulphate aerosol was generated. Moreover, pre-eruptive and degassed halogen concentrations (Cl, F) indicate that these volatiles were not efficiently released during the eruption. Besides the local pyroclastic flow (and related lahar) hazard, the impact of the Öræfajökull 1362 eruption was perhaps restricted to widespread ash fall across Eastern Iceland and parts of northern Europe.     

Deriving hillslope sediment budgets in wildfire-affected forests using fallout radionuclide tracers

Information on post-fire sediment and nutrient redistribution is required to underpin post-fire catchment management decisions. Fallout radionuclide budgets (²¹⁰Pb_xs, ¹³⁷Cs and ⁷Be) were derived to quantify soil redistribution and sediment yield in forested terrain following a moderately severe wildfire in a small (89 ha) water supply catchment in SE Australia. Application of these techniques in burnt terrain requires careful consideration of the partitioning of radionuclides between organic and mineral soil components. Beryllium-7 and ²¹⁰Pb_xs were shown to be closely associated with ash, litter and soil organic matter whereas ¹³⁷Cs was more closely associated with subsurface coarse mineral soil. Comparison of the three tracer budgets indicated that the dominant sediment source areas were ridgetops and steep valley sideslopes, from which burnt surface material was conveyed to the stream network via pre-existing gullies. Erosion was predominantly driven by sheetwash, enhanced by soil water repellency, and modified by bioturbation which both supplies subsurface sediment and provides sinks for erosive overland flow. Footslope and riparian zones were not important sediment source areas. The estimated event-based (wildfire and subsequent rainfall) sediment yield is 58 ± 25 t km^− 2, based on fallout ⁷Be measurements. The upper estimate of total particulate phosphorus yield (0.70 kg ha^− 1) is more than 10 times that at equivalent unburnt sites. This illustrates that, soon after fire, burnt eucalypt forest can produce nutrient loads similar to those of agricultural catchments. The tracer budgets indicate that wildfire is an important control on sediment and phosphorus inputs to the stream network over the decadal timeframe and the pulsed nature of this release is an important concern for water quality management.     

Fe sorption onto nontronite (NAu-2)

The sorption of ferrous iron to a clay mineral, nontronite (NAu-2, a ferruginous smectite), was investigated under strictly anoxic conditions as a function of pH (3-10), Fe²⁺ concentration (0.01-50 mM), equilibration time (1-35 days), and ionic strength (0.01-0.5 M NaClO₄). The surface properties of NAu-2 were independently characterized to determine its fixed charge and amphoteric site density in order to interpret the Fe²⁺ sorption data. Fe²⁺ sorption to NAu-2 was strongly dependent on pH and ionic strength, reflecting the coupled effects of Fe²⁺ sorption through ion exchange and surface complexation reactions. Fe²⁺ sorption to NAu-2 increased with increasing pH from pH 2.5 to 4.5, remained constant from pH 4.5 to 7.0, increased again with further increase of pH from pH 7.0 to 8.5, and reached a maximum above pH 8.5. The Fe²⁺ sorption below pH 7.0 increased with decreasing ionic strength. The differences of Fe²⁺ sorption at different ionic strengths, however, diminished with increasing equilibration time. The Fe²⁺ sorption from pH 4.5 to 7.0 increased with increasing equilibration time up to 35 days and showed stronger kinetic behavior in higher ionic strength solutions. The kinetic uptake of Fe²⁺ onto NAu-2 is consistent with a surface precipitation mechanism although our measurements were not able to identify secondary precipitates. An equilibrium model that integrates ion exchange, surface complexation and aqueous speciation reactions reasonably well describes the Fe²⁺ sorption data as a function of pH, ionic strength, and Fe²⁺ concentration measured at 24 h of equilibration. Model calculations show that the species Fe(OH)⁺ was required to describe Fe²⁺ sorption above pH 8.0 satisfactorily. Overall, this study demonstrated that Fe²⁺ sorption to NAu-2 is affected by complex equilibrium and kinetic processes, likely caused by surface precipitation reactions.     

Characterization of carbon monoxide,methane and nonmethane hydrocarbons in emerging cities of Saudi Arabia and Pakistan and in Singapore

We investigate the composition of 63 C₂-C₁₀ nonmethane hydrocarbons (NMHCs), methane (CH₄) and carbon monoxide (CO), in Jeddah, Mecca, and Madina (Saudi Arabia), in Lahore, (Pakistan), and in Singapore. We established a database with which to compare and contrast NMHCs in regions where ambient levels and emissions are poorly characterized, but where conditions are favorable to the formation of tropospheric ozone, and where measurements are essential for improving emission inventories and modeling. This dataset will also serve as a base for further analysis of air pollution in Western Saudi Arabia including, but not limited to, the estimation of urban emissions and long range pollution transport from these regions. The measured species showed enhanced levels in all Saudi Arabian cities compared to the local background but were generally much lower than in Lahore. In Madina, vehicle exhaust was the dominant NMHC source, as indicated by enhanced levels of combustion products and by the good correlation between NMHCs and CO, while in Jeddah and Mecca a combination of sources needs to be considered. Very high NMHC levels were measured in Lahore, and elevated levels of CH₄ in Lahore were attributed to natural gas. When we compared our results with 2010 emissions from the MACCity global inventory, we found discrepancies in the relative contribution of NMHCs between the measurements and the inventory. In all cities, alkenes (especially ethene and propene) dominated the hydroxyl radical (OH) reactivity (k _OH) because of their great abundance and their relatively fast reaction rates with OH.     

An Assessment of HOx Chemistry in the Tropical Pacific Boundary Layer: Comparison of Model Simulations with Observations Recorded during PEM Tropics A

Reported are the results from a comparison of OH,H₂O₂CH₃OOH, and O₃ observationswithmodel predictions based on current HO_x–CH₄reaction mechanisms. The field observations are thoserecorded during the NASA GTE field program, PEM-Tropics A. The major focus ofthis paper is on thosedata generated on the NASA P-3B aircraft during a mission flown in the marineboundary layer (MBL) nearChristmas Island, a site located in the central equatorial Pacific (i.e.,2° N, 157° W). Taking advantage of thestability of the southeastern trade-winds, an air parcel was sampled in aLagrangian mode over a significantfraction of a solar day. Analyses of these data revealed excellent agreementbetween model simulated andobserved OH. In addition, the model simulations reproduced the major featuresin the observed diurnalprofiles of H₂O₂ and CH₃OOH. In the case ofO₃, the model captured the key observational feature whichinvolved an early morning maximum. An examination of the MBL HO_xbudget indicated that the O(¹D) + H₂Oreaction is the major source of HO_x while the major sinks involveboth physical and chemical processes involving the peroxide species,H₂O₂ and CH₃OOH. Overall, the generally goodagreement between modeland observations suggests that our current understanding ofHO_x–CH₄ chemistry in the tropical MBL isquite good; however, there remains a need to critically examine this chemistrywhen both CH₂O and HO₂are added to the species measured.     

Flocculation and sedimentation in the ACE Basin, South Carolina

Extremely rapid deposition of fine-grained sediment has been observed near an artificially created channel between the Edisto and Ashepoo Rivers in South Carolina. Accumulation rates on the order of 0.05 m mo⁻¹ formed a region of fluid mud known as the Mud Reach that was present during a study carried out in May 1998. Subsequent surveys in March and May 1999 found no evidence of fluid mud in this area. Image analysis of photographs of the suspended sediment from 1998 showed that the water column was populated by flocs with a median diameter on the order of 0.3 mm which tended to remain in suspension over the tidal cycle, and flocs on the order of 0.8 mm which remained in the near bottom region except at maximum current speeds. In 1999, both the size and concentration of flocs at the surface remained the same, but the size and abundance of flocs near the bottom was reduced. Disaggregated inorganic grain size analysis of the suspension and samples from a core collected in the Mud Reach indicated that in 1998 the accumulation of material on the bottom was the result of floc settling and that in spite of highu _s values, little sorting of this material was occurring. Grain size analysis of samples deeper in the core showed that the rapidly floc-deposited mud was underlain by coarser, well-sorted sediment, confirming that the Mud Reach was a transient feature. The observed flocculation processes may play a significant role in the trapping of fine-grained sediment throughout this region.     

International boundaries and territorial stability in the Middle East: an assessment

International boundaries in the Middle East are less likely to represent a major source of international stress than is generally perceived. Formal treaties exist for 80% of the regions' land boundaries and current political processes seem to be working in favour of the status quo and territorial stability. Regarding maritime boundaries, over 60 such issues have yet to be delimited throughout the region. Of these, the major maritime boundary disputes are concentrated in the Persian Gulf, while the boundary between Greece and Turkey remains a focus of regional conflict in the Mediterranean Basin. Although the function of international boundaries are changing, the delimitation process can be expected to continue in the Middle East. Given political will to resolve problems of delimitation, the ultimate demarcation of boundaries should progress without serious conflict between states in the region.