Distribution of marine lipid classes in salty Rogoznica Lake (Croatia)

Lipid classes in a small, eutrophicated salty lake (Rogoznica Lake, middle Adriatic), which is often subject to appeareance of anoxic conditions, were analyzed at the end of winter (March) and in summer (July) 2008. The results are supported with DOC, POC, phytoplankton, temperature, salinity and oxygen data. During both March and July massive, diatom blooms were recorded with maximum values at 5 m depth. Total lipids were found at high concentrations that were similar for the samplings in two months. Total particulate lipids dominated the pool, and showed large variations from 46.37 to 369.88 μg/l, with the highest concentration observed in the bottom anoxic layer in March. The variations for dissolved lipids were smaller and ranged from 44.82 to 124.35 μg/l. Opposite to lipids, DOC values increased 1.5 times between the two samplings, from the value of average 0.95 mg C/l in March to the average value of 1.44 mg/l in July. Conformingly with diatom blooms, POC was found in July at high concentrations (0.28–1.50 mg C/l), contributing to total organic carbon up to 46%. The distribution of organic carbon and lipids showed the tendency of accumulation toward deeper layers. The characterization of individual lipid classes revealed the dominance of phospholipids, indicating that the lipids in the lake mainly originated from the photosynthetically active phytoplankton community, which is sustained by high production of oxygen (oxygen saturation up to 200%). Low contribution of neutral lipids in the particulate fraction points to high availability of nutrients for present phytoplankton community. Lipid breakdown indices were found at significantly higher concentrations in March compared to July. Sea surface microlayer, the hydrophobic boundary, appeared to be generally lipid depleted in comparison to the sub-surface water. Qualitative analysis of sulfolipids revealed the potential of the lake for the occurrence of chemical interaction of sulfur with present organic matter.     

Source potential and palynofacies of Late Jurassic “Lemeš facies”, Croatia

Laminated limestone and calcareous shale outcrop samples from the Late Jurassic “Leme?” facies (Croatia) were investigated to characterize their organic facies and palynofacies and their hydrocarbon generative potential. The results indicate that the organic rich sediments of “Leme?” facies were deposited within a relatively shallow marine environment at low redox potential, characterized as an oxygen depleted depositional setting with stratified bottom waters of the carbonate platform (Adriatic Carbonate Platform). The organic rich samples contain a high portion of lipid rich amorphous kerogen of algal/phytoplankton origin, enriched by bacterial biomass. Most of the analyzed samples have total organic carbon contents (TOC) greater than 3%, Rock-Eval S2 >20 mg HC/g rock, yielding Hydrogen Index (HI) values ranging from 509–602 mg HC/g TOC. According to these results, the analyzed samples have very good to excellent oil generative potential. Relatively high sulfur content suggests that the kerogen is best described as Type II-S. Biomarker maturity parameters, as well as the fluorescence of the isolated kerogen, show that the organic matter is at early to peak oil thermal maturity. The observed level of thermal maturity indicates that these samples were once buried to depths of ～5.5–5.8 km before being uplifted in the late Tertiary. The surface outcrops of the “Leme?” facies suggest that these strata have significant source potential and are the likely source of oil in the Croatian External Dinarides.     

State of geoscientific research within the lorandite experiment (LOREX)

The LORandite EXperiment (acronym LOREX) is the only geochemical solar neutrino experiment still actively persued. The Tl-mineral lorandite, TlAsS₂, occurs in the ore deposit Allchar, Macedonia, close to the border of Greece. The polychronous and polygenetic Sb-As-Tl-Au Allchar deposit was formed by complex physico-chemical processes occurring in a heterogeneous geological environment and by interaction of polyphase hydrothermal fluids with the surrounding magmatic, sedimentary and metamorphic rocks. The genesis of ore mineralization is related to the products of polyphase magmatic activity of Pliocene age (~6.5 to ~1.8?Ma) and its spatial location was controlled by magmatic, structural and lithological factors. The Allchar deposit comprises several orebodies of various shapes, textural-structural characteristics and element associations. Thallium mineralization, which is of significance for the LOREX project, has been proved in two locations: (i) ore body Crven Dol in the northern part and (ii) ore body Centralni Deo in the central part of the Allchar deposit. The age of Tl-mineralization is 4.22?Ma at the Crven Dol locality and 4.31?Ma at Rudina near to the Centralni Deo locality. The present depth of ore mineralization from the present soil surface is about 30?m to 140?m, whereas the paleodepth of its formation is considerably bigger. Using the method of quantitative geomorphological analysis, and AMS- and MS-measurements of cosmogenic radionuclides ²⁶Al, ²¹Ne, and ³He, the erosion rate has been established to be ~70?m/Ma in the broader area of the Crven Dol locality and ~130?m/Ma in the Centrani Deo of the Allchar deposit. On the basis of these erosion rates and ages of Tl-mineralization, we have calculated the paleo-depth of Lorandite to be ca 180?m?±?35?m to 420?m?±?80?m. Geochemical and mineralogical investigations on lorandite in particular its trace elements (Pb, U, and Th), the quantity of lorandite in the two ore bodies, the geological age and the paleo depth of Tl-mineralization have provided encouraging results and indicate the feasibility of the LOREX project.     

Remapping Fictional Worlds: A Comparative Reconstruction of Fictional Maps

ABSTRACT

This article presents a quantitative analysis of fictional maps and their relation to historic maps from different periods. Fictional maps are maps of imaginary territories. This type of map is now common in fiction, but they arose relatively late, in the second half of the nineteenth century, and are considered an independent branch of cartography today. They stand out through the way they are published because they are component parts of books and not independent cartographic works, and therefore their creators are not cartographers but rather the authors of these books. Fictional maps are mostly subordinate to the story, but they serve to give a sense of historical authenticity and draw the reader into the story. Without networks of coordinates and with labels such as ‘the end of the world’, they are spatially indeterminate, but they establish a connection between the fictional landscape and its identity. This study deals with 89 fictional maps from recent children’s and young adult literature. First we present a historical overview of these works and fictional maps, and then a cartographic analysis of fictional maps. We examined seventy-seven books with fictional maps and evaluated the maps according to five groups of standard cartographic elements: natural elements, built elements, toponyms, mathematical elements, and explanatory elements. We discuss the differences between cartographic representation of fictional maps and historic maps, and build a cartographic model based on the frequency of cartographic elements to put fictional maps into historic and geographical contexts.     

Changing local finances in the Czech Republic — half way over?

Far-reaching changes launched in 1989, aimed mainly at establishing a democratic society and market economy have clearly brought many positive results. However, there is also a negative side to these progressive changes both in economic and social spheres. There are many difficult tasks ahead such as the reestablishment of a democratic and economically effective local government which will be able to fulfil contemporary needs and requirements. The aim of this report is not to describe all the changes occurring in local government or to review different opinions about what should be done, but rather to concentrate on one of the most important issues facing this body of government, that of financial reform. Special attention will be given to the economic performance of municipalities with regard to their population size. It will be argued that data from local budgets can reveal important features about the performance of local and regional economies which cannot be obtained in any other way.     

Solution to the spectral filter problem of residual terrain modelling (RTM)

In physical geodesy, the residual terrain modelling (RTM) technique is frequently used for high-frequency gravity forward modelling. In the RTM technique, a detailed elevation model is high-pass-filtered in the topography domain, which is not equivalent to filtering in the gravity domain. This in-equivalence, denoted as spectral filter problem of the RTM technique, gives rise to two imperfections (errors). The first imperfection is unwanted low-frequency (LF) gravity signals, and the second imperfection is missing high-frequency (HF) signals in the forward-modelled RTM gravity signal. This paper presents new solutions to the RTM spectral filter problem. Our solutions are based on explicit modelling of the two imperfections via corrections. The HF correction is computed using spectral domain gravity forward modelling that delivers the HF gravity signal generated by the long-wavelength RTM reference topography. The LF correction is obtained from pre-computed global RTM gravity grids that are low-pass-filtered using surface or solid spherical harmonics. A numerical case study reveals maximum absolute signal strengths of \(\sim 44\) mGal (0.5 mGal RMS) for the HF correction and \(\sim 33\) mGal (0.6 mGal RMS) for the LF correction w.r.t. a degree-2160 reference topography within the data coverage of the SRTM topography model (\(56^{\circ }\hbox {S} \le \phi \le 60^{\circ }\hbox {N}\)). Application of the LF and HF corrections to pre-computed global gravity models (here the GGMplus gravity maps) demonstrates the efficiency of the new corrections over topographically rugged terrain. Over Switzerland, consideration of the HF and LF corrections reduced the RMS of the residuals between GGMplus and ground-truth gravity from 4.41 to 3.27 mGal, which translates into \(\sim 26\)% improvement. Over a second test area (Canada), our corrections reduced the RMS of the residuals between GGMplus and ground-truth gravity from 5.65 to 5.30 mGal (\(\sim 6\)% improvement). Particularly over Switzerland, geophysical signals (associated, e.g. with valley fillings) were found to stand out more clearly in the RTM-reduced gravity measurements when the HF and LF correction are taken into account. In summary, the new RTM filter corrections can be easily computed and applied to improve the spectral filter characteristics of the popular RTM approach. Benefits are expected, e.g. in the context of the development of future ultra-high-resolution global gravity models, smoothing of observed gravity data in mountainous terrain and geophysical interpretations of RTM-reduced gravity measurements.