二叠系火山碎屑岩气藏天然气地球化学特征及气源分析——以四川盆地成都—简阳地区永探1井为例

2018年12月底,在四川盆地二叠系火山岩发育地区部署的风险探井永探1井测试获得22.5万m³/d的高产工业气流,实现了二叠系火山碎屑岩的重大勘探突破,展现了火山碎屑岩气藏的巨大勘探潜力。本文根据该钻井成果资料,应用分析化验数据,采用不同地区气-气对比方法,开展了成都—简阳地区天然气地球化学特征分析、源-储接触关系解剖及气源综合对比。在此基础上,对二叠系火山碎屑岩气藏天然气成因进行了鉴别,对天然气来源进行了判识。结果表明：永探1井火山岩气藏天然气均为典型的干气,干燥系数达0.997,CH₄质量分数高,平均为99.03%,C₂H₆质量分数低,平均为0.35%,C₃H₈几乎没有,不含H₂S;天然气甲烷、乙烷碳同位素值均较轻,甲烷碳同位素平均值为-32.17‰,乙烷碳同位素平均值为-34.27‰,且岩心及镜下可见大量残余沥青,天然气成因鉴别分析表明永探1井火山岩气藏天然气为原油二次裂解气;通过源-储接触关系解剖以及天然气甲烷、乙烷碳同位素对比分析,表明永探1井火山碎屑岩气藏天然气主要来源于德阳—安岳台内裂陷内发育的巨厚下寒武统筇竹寺组优质烃源岩,部分来源于中二叠统。     

坦桑尼亚林迪地区纳钦圭阿石墨矿床地质特征及找矿模型

坦桑尼亚林迪地区是世界上重要的石墨成矿带,纳钦圭阿石墨矿是成矿带新发现的典型矿床之一。矿区分南北2个矿段,共圈定工业矿体17条,推断石墨矿物资源量>100万t,固定碳平均品位为4.05%。矿体赋存于石墨片岩-片麻岩中,呈层状、透镜状产出,走向北东—北北东,产状与围岩一致,矿体与围岩呈渐变过渡关系。矿石类型为石墨片岩-片麻岩型,矿石矿物为鳞片状石墨,脉石矿物主要为石英、长石、云母及少量金属矿物。矿石中片度≥147 μm（+100目）的石墨占94.43%,工业类型为大鳞片晶质石墨矿石。以视极化率6%为异常下限,共圈定4处激电异常,高极化率异常与低电阻率异常对应良好,探矿工程确定为矿体出露位置。该石墨矿的找矿模型：新元古代莫桑比克活动带中一套中高级副变质岩系为区域找矿标志,石墨片岩、石墨片麻岩露头为矿区找矿的直接标志,延伸方向与地层走向一致的条带状低阻、高极化异常带为地球物理找矿标志。该石墨矿的地质特征及找矿模型可作为在坦桑尼亚寻找同类矿床的参考。     

Geochronological and geochemical evidence for a Late Ordovician to Silurian arc-back-arc system in the northern Great Xing'an Range,NE China

The early Paleozoic tectonic evolution of the Xing'an-Mongolian Orogenic Belt is dominated by two oceanic basins on the northwestern and southeastern sides of the Xing'an Block,i.e.,the Xinlin-Xiguitu Ocean and the Nenjiang Ocean.However,the early development of the Nenjiang Ocean remains unclear.Here,we present zircon U-Pb geochronology and whole-rock elemental and Sr-Nd isotopic data on the gabbros in the Xinglong area together with andesitic tuffs and basalts in the Duobaoshan area.LA-ICP-MS zircon U-Pb dating of gabbros and andesitic tuffs yielded crystallization ages of 443-436 Ma and 452-451 Ma,respectively.The Early Silurian Xinglong gabbros show calc-alkaline and E-MORB affinities but they are enriched in LILEs,and depleted in HFSEs,with relatively low U/Th ratios of 0.18-0.36 andεNd(t)values of-1.6 to+0.5.These geochemical features suggest that the gabbros might originate from a mantle wedge modified by pelagic sediment-derived melts,consistent with a back-arc basin setting.By contrast,the andesitic tuffs are characterized by high MgO(>5 wt.%),Cr(138-200 ppm),and Ni(65-110 ppm)contents,and can be termed as high-Mg andesites.Their low Sr/Y ratios of 15.98-17.15 and U/Th values of 0.24-0.25 and moderate(La/Sm)_n values of 3.07-3.26 are similar to those from the Setouchi Volcanic Belt(SW Japan),and are thought to be derived from partial melting of subducted sediments,and subsequent melt-mantle interaction.The Duobaoshan basalts have high Nb(8.44-10.30 ppm)and TiO2 contents(1.17-1.60 wt.%),typical of Nb-enriched basalts.They are slightly younger than regional adakitic rocks and have positiveεNd(t)values of+5.2 to+5.7 and are interpreted to be generated by partial melting of a depleted mantle source metasomatized by earlier adakitic melts.Synthesized with coeval arc-related igneous rocks from the southeastern Xing'an Block,we propose that the Duobaoshan high-Mg andesitic tuffs and Nbenriched basalts are parts of the Late Ordovician and Silurian Sonid Zuoqi-Duobaoshan arc belt,and they were formed by the northwestern subduction of the Nenjiang Ocean.Such a subduction beneath the integrated Xing'an-Erguna Block also gave rise to the East Ujimqin-Xinglong igneous belt in a continental back-arc basin setting.Our new data support an early Paleozoic arc-back-arc model in the northern Great Xing'an Range.     

Compression behavior of MICP-treated sand with various gradations

Acta Geotechnica - One-dimensional compression tests on quartz sands treated by microbially induced carbonate precipitation (MICP) were carried out to evaluate the effects of gradation and calcium...     

Investigation of the penetration characteristics of snake skin-inspired pile using DEM

Acta Geotechnica - Snake can perfectly utilize its scales to move. Inspired by the snake scales, this study investigated the characteristics of the snake skin-inspired pile penetration process. Six...     

A generalized model for effective thermal conductivity of soils considering porosity and mineral composition

Acta Geotechnica - Soils have a variety of mineral compositions. Although a number of thermal conductivity models have been developed for soils, few quantitatively investigated the effect of...     

Carboniferous ridge subduction in the Xingmeng Orogenic Belt: Constraints from geochronological,geochemical, and Sr-Nd-Hf isotopic analysis of strongly peraluminous granites and gabbro-diorites in the Xilinhot micro-continent

The Xingmeng Orogenic Belt evolved through a long-lived orogeny involving multiple episodes of subduction and accretion. However, there is a debate on its tectonic evolution during the Late Paleozoic. Here, we report geochemical, geochronological, and isotopic data from strongly peraluminous granites and gabbro-diorites from the Sunidzuoqi–Xilinhot region. Zircon U–Pb ages suggest that the intrusive rocks were emplaced during the Early Carboniferous (333–322 Ma). The granites exhibit geochemical characteristics similar to S-type granites, with high SiO₂ (72.34–76.53 wt.%), Al₂O₃ (12.45–14.65 wt.%), and A/CNK (1.07–1.16), but depleted Sr, Nb, and Ta contents. They exhibit positive ε_Nd(t) and ε_Hf(t) values (?0.3 to 2.8 and 2.7–5.7, respectively) and young Nd and Hf model ages (T_DM2(Nd)=853–1110 Ma and T_DM2(Hf)=975–1184 Ma), suggesting that they may be the partial melting products of heterogeneous sources with variable proportions of pelite, psammite, and metabasaltic rocks. The meta-gabbro-diorites from the Maihantaolegai pluton have low SiO₂ (47.06–53.49 wt.%) and K₂O (0.04–0.99 wt.%) contents, and demonstrate slight light rare earth element (REE) depletion in the chondrite-normalized REE diagrams. They have high zircon ε_Hf(t) values (14.41–17.34) and young Hf model ages (T_DM2(Hf)= 230–418 Ma), indicating a more depleted mantle source. The variations of the Sm/Yb and La/Sm ratios can thus be used to assess the melting degree of the mantle source from 5% to 20%, suggesting a quite shallow mantle melting zone. We propose that the petrogenesis and distribution of the strongly peraluminous granites and gabbro-diorites, as well as the tectonic architecture of the region, can be explained by a ridge subduction model. Based on these results, and previous studies, we suggest a southward ridge subduction model for the Sunidzuoqi–Xilinhot region.     

Pore structure and heterogeneity of shale gas reservoirs and its effect on gas storage capacity in the Qiongzhusi Formation

Fine characterization of pore systems and heterogeneity of shale reservoirs are significant contents of shale gas reservoir physical property research.The research on micro-control factors of low productivity in the Qiongzhusi Formation(Fm.)is still controversial.The lower Cambrian Qiongzhusi Fm.in the Qujing,Yunnan was taken as the object to investigate the influence of mineral compositions on the phys-ical properties of the reservoir and the heterogeneity of shale,using the algorithm to improve the char-acterization ability of Atomic Force Microscopy(AFM).The results showed that:(1)The pores are mainly wedge-shaped pores and V-shaped pores.The pore diameter of the main pore segment ranges from 5 to 10 nm.Mesopores are mainly developed in the Qiongzhusi Fm.shale in Well QD1,with the average pore diameter of 6.08 nm.(2)Microscopic pore structure and shale surface properties show strong hetero-geneity,which complicates the micro-migration of shale gas and increases the difficulty of identifying high-quality reservoirs.(3)The increase of clay mineral content intensifies the compaction and then destroys the pores.Conversely,brittle minerals can protect pores.The support and protection of brittle minerals to pores space depend on their content,mechanical properties and diagenesis.(4)Compression damage to pores,large microscopic roughness and surface fluctuations and strong pore structure heterogeneity are the reasons for the poor gas storage capacity of the Qiongzhusi Fm.,which will lead to poor productivity in the Qiongzhusi Fm.     

青海黄南地区近54年蒸发量变化特征及其影响因子

利用青海省黄南地区近54a(1960—2013年)蒸发量、气温、降水量、日照时数、水汽压等资料,应用地理信息系统、数理统计、线性回归和Mann-Kendall检验等方法分析了黄南地区蒸发量的空间及时间变化趋势,并对黄南地区蒸发量变化特征及其影响因子进行了诊断研究。结果表明:黄南地区年平均蒸发量呈明显的下降趋势,20世纪60—70年代为蒸发量偏多阶段,80年代及后为偏少阶段;黄南地区蒸发量最大的季节是春季和夏季,各季蒸发量均呈减少趋势;黄南地区年蒸发量在1973年发生了由多到少的突变,春、夏、秋、冬季分别发在1973、1975、1976和1974年;分析影响蒸发量的相关因子,蒸发量与日照时数呈显著的正相关关系,与水汽压和降水量呈显著的负相关关系,日照时数的减小是蒸发量减少的主要影响因子。     

一次攀西地区飑线天气过程形成机制分析

利用地面气象常规观测资料、区域自动站观测资料、雷达及卫星资料和NCEP 1°×1°的逐6h再分析资料,对2018年5月13日攀西地区南部的飑线天气过程的形成机制进行分析。结果表明:飑线发生在高空槽前,高空槽逐渐东移推动冷性气流沿背风坡东移,然后与前方低层暖空气汇合抬升形成对流;露点锋触发了飑线天气过程的形成;产生飑线天气区域的大气具有上干下湿、不稳定能量高、垂直风切变强、高层风速大和形成之前存在逆温层的特点;高空急流和动量下传对飑线的发生和加强具有促进作用;地形对飑线的形成和天气现象的分布有影响。