Discussion on influence of cavern’s span on surrounding rock classification

The influence of cavern’s span on surrounding rock classification is getting more and more recognition along with large span underground working’s increasingly coming forth. The authors analyse the timbering expense of cavern in jointed rock mass, the radius of plastic loosened zone and the size effect of macroscopical mechanical parameters of rock mass. Based on the complexion of depressing of surrounding rock’s stability due to increment of cavern’s span, the authors pinpoint attaching importance to the influence of cavern’s span on surrounding rock classification; and suggest reckoning the factor of cavern’s span in surrounding rock classification scientifically by studying the size effect of rock mass’s physico-mechanical parameters.     

Pristine and reacted surfaces of pyrrhotite and arsenopyrite as studied by X-ray absorption near-edge structure spectroscopy

Fe L-, S L-, and O K-edge X-ray absorption spectra of natural monoclinic and hexagonal pyrrhotites, Fe_1-xS, and arsenopyrite, FeAsS, have been measured and compared with the spectra of minerals oxidized in air and treated in aqueous acidic solutions, as well as with the previous XPS studies. The Fe L-edge X-ray absorption near-edge structure (XANES) of vacuum-cleaved pyrrhotites showed the presence of, aside from high-spin Fe²⁺, small quantity of Fe³⁺, which was higher for a monoclinic mineral. The spectra of the essentially metal-depleted surfaces produced by the non-oxidative and oxidative acidic leaching of pyrrhotites exhibit substantially enhanced contributions of Fe³⁺ and a form of high-spin Fe²⁺ with the energy of the 3d orbitals increased by 0.3–0.8 eV; low-spin Fe²⁺ was not confidently distinguished, owing probably to its rapid oxidation. The changes in the S L-edge spectra reflect the emergence of Fe³⁺ and reduced density of S s–Fe 4s antibonding states. The Fe L-edge XANES of arsenopyrite shows almost unsplit e_g band of singlet Fe²⁺ along with minor contributions attributable to high-spin Fe²⁺ and Fe³⁺. Iron retains the low-spin state in the sulphur-excessive layer formed by the oxidative leaching in 0.4 M ferric chloride and ferric sulphate acidic solutions. The S L-edge XANES of arsenopyrite leached in the ferric chloride, but not ferric sulphate, solution has considerably decreased pre-edge maxima, indicating the lesser admixture of S s states to Fe 3d orbitals in the reacted surface layer. The ferric nitrate treatment produces Fe³⁺ species and sulphur in oxidation state between +2 and +4.     

地质岩芯科技资源科普化工作探索与实践——以自然资源实物地质资料中心为例

岩芯科技资源科普化是打通地质科研—科普链条的重要途径,本文通过梳理我国岩芯科技资源现状,分析了岩芯科技资源科普化的现实意义,重点阐述了岩芯科技资源在向地质科普转化5个方面的探索与实践,提出了今后岩芯科技资源科普化工作应建立良好政策机制制度、转变科研人员观念、科技知识向科普转化水平、新技术新手段的应用以及做好科普活动的实施总结等5项工作建议。     

太湖表层沉积物多环芳烃的空间分布、来源及其风险

随着太湖流域社会与经济的发展,多环芳烃(PAHs)在各种环境介质中逐渐累积,污染日益严重,可能对太湖生态环境及周边人体健康构成威胁。为探究太湖沉积物PAHs的来源及生态风险,于2021年12月在太湖采集30个表层沉积物样品,利用气相色谱-质谱联用仪(GC-MS)检测样品中16种PAHs含量;利用受体模型和苯并[a]芘(BaP)毒性当量法进行来源解析及生态风险评估,并将各来源贡献与毒性当量浓度相结合,量化源风险。结果表明,太湖表层沉积物中16种PAHs总含量介于124~592 ng/g之间,平均值为294 ng/g,中值为279 ng/g;高环多环芳烃(HMW PAHs)为主要组分,占∑PAHs的67%。高含量区域位于竺山湾、梅梁湾、贡湖湾和西太湖,与国内外其他湖泊沉积物相比,太湖沉积物PAHs含量处于较低水平。源解析的结果表明,太湖表层沉积物中PAHs交通排放源贡献率为29.1%、煤炭燃烧源贡献率为26.7%、生物质燃烧源贡献率为28.7%、石油源贡献率为15.6%。生态风险评价结果表明,交通排放源、生物质燃烧源、煤炭燃烧源和石油源的BaP毒性当量含量(TEQ_BaP)均值分别为19.34、17.81、16.33和9.1 ng/g,均小于70 ng/g,几乎处于无风险水平。西太湖、贡湖湾和梅梁湾的部分区域ΣTEQ_BaP大于70 ng/g属于潜在风险区,具有一定潜在毒性。在后续的污染治理中应重点关注太湖西北部地区污染物的排放。本研究可为沉积物中PAHs污染的研究提供数据支撑,为地方政府精准、高效地管控PAHs污染提供理论依据。     

海南新村港潮汐汊道波流联合作用下的动力特征及其沉积动力学意义

基于ADCIRC与STWAVE模型,对海南新村港潮汐汊道的波浪-潮流联合作用进行了数值模拟,结果表明,S、SE向的平均浪与风暴浪在汊道近岸以产生西向沿岸流为主,SSW向平均浪与风暴浪作用时,在落潮主水道西侧形成东向沿岸流与西向沿岸流的交汇带。风暴浪作用下波生流与潮流的相互作用使瞬时流场与余流场均发生相应的变化。在平均浪作用时,汊道附近流速变化很小,而在风暴浪作用时流速增大,汊道内的涨、落潮流速不对称更为显著。在落潮主水道两侧由于波流联合作用产生涡漩,使动力减弱,从而造成泥沙落淤,而西向沿岸流的存在,使落潮主水道南侧边缘沙坝持续西移,泥沙沿落潮三角洲末端与冲流坝转运,导致新村港汊道口门西侧发育了规模较大的堆积地貌。     

用于房地一体调查轻便型点云影像集成移动测量方法与试验

房地一体调查是农村土地制度改革的重要举措,为加快推进房地一体调查工作,高质量完成调查任务,本文开展了轻便型移动测量系统在农村不动产测量中的应用研究。综合应用卫星定位、惯性导航、360全景、三维激光的VSurs-Q轻便型移动测量系统采集的影像、点云等多源数据,采用Vsurs Process和Vsur Map点云处理及制图软件形成地形地籍图,以及辅助地籍调查技术流程、关键技术指标及质量评价体系。珠海市高栏港经济区房地一体调查试验区成果表明：统计界址点中误差为0.062 m,满足界址点二级精度要求;统计界址点间距误差最大0.045 m,在边长限差容许范围内。1 km²范围外业采集2—3 d,房屋分布较密集和复杂区域4—5 d,较大限度地节省了调查时间。     

西藏东巧蛇绿岩中辉长岩锆石SHRIMP定年及其地质意义

东巧蛇绿岩位于分割羌塘地块和拉萨地块的班公湖—怒江缝合带中段,是该带最著名的产铬铁矿床的蛇绿岩残片之一。该蛇绿岩遭受构造肢解,恢复后的蛇绿岩剖面各岩石单元齐全。本文应用SHRIMPⅡ锆石UPb法,对东巧蛇绿岩中堆晶辉长岩进行了测年,获得辉长岩年龄为187.8±3.7 Ma。该年龄代表了东巧洋盆的形成时代,为确定研究区特提斯洋盆的古构造格局及其发育演化过程等提供了重要的年代学制约。     

Civil 3D在土石方量计算中的应用研究

介绍了计算土石方工程量的几种方法与原理,重点阐述了Civil 3D软件快速灵活计算工程量的步骤,分别以场地工程和道路工程为例,利用Civil 3D绘制道路纵、横断面图并计算土石方工程量,研究结果表明,Civil 3D能够快速计算工程量,较其他软件具有明显的优势。