Metal-silicate partitioning and constraints on core composition and oxygen fugacity during Earth accretion

We present the results of new partitioning experiments between metal and silicate melts for a series of elements normally regarded as refractory lithophile and moderately siderophile and volatile. These include Si, Ti, Ni, Cr, Mn, Ga, Nb, Ta, Cu and Zn. Our new data obtained at 3.6 and 7.7 GPa and between 2123 and 2473 K are combined with literature data to parameterize the individual effects of oxygen fugacity, temperature, pressure and composition on partitioning. We find that Ni, Cu and Zn become less siderophile with increasing temperature. In contrast, Mn, Cr, Si, Ta, Nb, Ga and Ti become more siderophile with increasing temperature, with the highly charged cations (Nb, Ta, Si and Ti) being the most sensitive to variations of temperature. We also find that Ni, Cr, Nb, Ta and Ga become less siderophile with increasing pressure, while Mn becomes more siderophile with increasing pressure. Pressure effects on the partitioning of Si, Ti, Cu and Zn appear to be negligible, as are the effects of silicate melt composition on the partitioning of divalent cations. From the derived parameterization, we predict that the silicate Earth abundances of the elements mentioned above are best explained if core formation in a magma ocean took place under increasing conditions of oxygen fugacity, starting from moderately reduced conditions and finishing at the current mantle-core equilibrium value.     

Calc-alkaline and shoshonitic lavas from five Andean volcanoes (between latitudes 21° 45′ and 24°30′S) and the distribution of the Plio-Quaternary volcanism of the south-central and southern Andes

The Plio-Quaternary volcanic rocks of the south-central Andes (southward from latitude 18°S) contain two associations: calc-alkaline and shoshonitic which coincide with seismic belts as geographically distinct zones aligned parallel to the oceanic trench. There is a continuous gradation from calc-alkaline to shoshonitic associations. The shoshonitic association appears to the north of latitude 26°S; southwards, the calc-alkaline association directly abuts against the continental (Argentinian) alkaline association.Thirty-one lavas from the Plio-Quaternary calc-alkaline Socompa, Lascar, Sairecabur and Tocorpuri and shoshonitic Sierra de Lipez volcanoes were studied. The lavas are porphyric with abundant glass. The distribution and the nature of the phenocrysts vary according to the chemistry of the calc-alkaline lavas. Petrographic evidence for crystal fractionation has been observed. Occasional phenocrysts of alkali feldspars occur in the shoshonitic lavas. The K₂O and SiO₂ contents increase from calc-alkaline to shoshonitic lavas with distance away from the oceanic trench. In lavas from Socompa, Lascar, Sairecabur and Tocorpuri calc-alkaline volcanoes, K₂O, Li and Rb increase and K/Rb and Sr decrease with increasing SiO₂; Ba increases with decreasing Sr, probably as a result of plagioclase fractionation. In lavas from Sierra de Lípez shoshonitic volcano, SiO₂ is high, K₂O is high and rather constant and Li, Rb, Ba and Sr increase with increasing SiO₂. Bolivian shoshonitic lavas appear to be genetically related to the calc-alkaline suite.The calc-alkaline lavas may be derived by crystal fractionation from a parental magma of andesitic nature that originated in or above the subjacent Benioff zone.     

A metric type III burst asymmetry relative to simple bipolar active regions

Metric type III solar radio burst positions are compared spatially and temporally to underlying active region geometry. The positions of these radio bursts have an asymmetric location distribution relative to simple bipolar regions. The type III bursts show a tendency to occur nearer the leading active region - an association shown before from type III burst and magnetic field polarity measurements. The type III bursts also generally occur to the left of the outward to inward directed magnetic field. The asymmetry relative to the outward directed magnetic field has a sense that is consistent with a mechanism of type III burst production that involves a pre-existing coronal current system situated between expanding closed and open magnetic field lines.     

Adsorption of xenon ions onto defects in organic surfaces: Implications for the origin and the nature of organics in primitive meteorites

Noble gases trapped in primitive meteorites are quantitatively hosted by a poorly defined organic phase, labeled phase Q. Xenon is enriched in heavy isotopes by +1.30 ± 0.06% per atomic mass unit (amu, 1σ) in phase Q relative to solar. To understand the origin of this fractionation, we have performed adsorption experiments of xenon atoms and ions, ionized in a radiofrequency plasma. Within the reaction vessel, anthracite was heated and the resulting smoke deposited onto the walls of the vessel, resulting in carbon-rich films. Xenon was trapped in the carbon films either as ions in the ionization zone of the vessel, or as neutral atoms outside this zone. Xenon trapped as ionic Xe is tightly bound and is enriched by +1.36 ± 0.05%/amu (1σ) in heavy isotopes, reproducing the isotopic fractionation of xenon trapped in phase Q relative to solar. Neutral xenon is more loosely trapped, is in much lower concentration, and is not isotopically fractionated. Ionized conditions allow the constant xenon isotopic composition observed in meteorite during stepwise heating release to be reproduced. Furthermore, the trapping efficiency of Xe⁺ estimated from these experiments is consistent with the high xenon concentration measured in phase Q of primitives meteorites.Xenon was not trapped in the film by implantation because the energies of the incident Xe atoms and ions were far too low (<1 eV). From the difference of behavior between ionic and neutral forms, we propose that xenon ions were trapped via chemical bonding at the surface of the newly created C-rich film. The observed mass-dependent fractionation of xenon is unlikely to have occurred in the gas phase. It is more probably related to variations in chemical bonding strengths of Xe isotopes as chemical bonds involving heavy Xe isotopes are more stable than those involving light ones. For young stars, including the young Sun, photons emitted in the far UV energy range able to ionize noble gases (<100 nm) were orders of magnitude more abundant than for the Present-day Sun, allowing efficient ionization of gaseous species. A way to achieve Q-noble gas fractionation and trapping was UV irradiation by nearby young stars from O/B association of the surface of growing organic grains in the outer part of the solar system or by the young Sun at the edge of the disk.     

Zarka shakedown modelling of expansive soils subjected to wetting and drying cycles

Unsaturated expansive soils subjected to wetting and drying cycles result in huge differential settlements of structures built on these materials. The existed models for these materials present large number of parameters that lead to time-consuming procedure to characterise their mechanical behaviour during wetting–drying cycles. In this context, Zarka shakedown theory previously applied to the mechanical loading of granular materials has been used for expansive soils subjected to suction cycles. The parameters of this shakedown-based model were calibrated for two different expansive soils. The comparisons between the experimental results and the calculations for the different tests, demonstrate the capacity of Zarka shakedown theory to simulate the mechanical behaviour of unsaturated expansive soils.     

Uncertainties of the relationship between the equatorial quasi-biennial oscillation, the Arctic stratosphere and solar forcing

Two different equatorial quasi-biennial oscillation (QBO) indices, two reanalyses and radiosonde observations are used to analyze the Arctic stratospheric temperature and height. This analysis was used to assess the uncertainties in the connection of solar forcing, QBO and the Arctic variability. The results show that (1) the frequency of the westerly/easterly phases of the QBO over the stratospheric equator has a significant multiple peak seasonal variation. The primary seasonal peaks occur in February, March and April for the westerly phase of the QBO and the easterly phase peaks in June, July and August. (2) The correlation of stratospheric Arctic temperature and height with the solar radio flux shows statistical significance in February or July/August even if there is no stratified phase of QBO (easterly and westerly phases) involved. However, when the correlation was computed according to the stratified phase of QBO, the solar signals in both temperature and height fields are remarkably amplified in February and November under the westerly phase, but the signal in the height field is most significant only in August under the easterly phase. (3) The impact of the QBO and solar forcing on the stratospheric temperature and heights in the Arctic varies depending on the season. The impacts are also sensitive to the specific height of the QBO-defined level that is used, the specific period of the analysis and the dataset used.     

Estimation of groundwater recharge in Wadi Al-Yammaniyah,Saudi Arabia

Groundwater recharge by natural replenishment for the unconsolidated alluvial aquifer in Wadi Al-Yammaniyah is estimated on a daily basis instead of the conventional monthly basis The study reveals that during the two-year period (1978 and 1979), the estimated recharge in the area is about 40% of the total average annual rainfall of 155 mm Subsurface underflow estimated at 36×10⁻⁶ m³/yr from the Wadi Al-Yammaniyah aquifer occurs in the vicinity of Wadi Ash-Shamiyah A comparison of the recharge and extracted volumes of water from the aquifer indicates that there is a net increase of 10 million m³ and 38 million m³ of water in the storage for 1978 and 1979, respectively     

Biomass carbon storage and its sequestration potential of afforestation under natural forest protection program in China

Based on the data from China′s Seventh Forest Inventory for the period of 2004–2008, area and stand volume of different types and age-classes of plantation were used to establish the relationship between biomass density and age of planted forests in different regions of the country. Combined with the plantation area in the first-stage of the Natural Forest Protection(NFP) program(1998–2010), this study calculated the biomass carbon storage of the afforestation in the first-stage of the program. On this basis, the carbon sequestration potential of these forests was estimated for the second stage of the program(2011–2020). Biomass carbon storage of plantation established in the first stage of the program was 33.67 Tg C, which was majority accounted by protection forests(30.26 Tg C). There was a significant difference among carbon storage in different regions, which depended on the relationship of biomass carbon density, forest age and plantation area. Under the natural growth, the carbon storage was forecasted to increase annually from 2011 to 2020, reaching 96.03 Tg C at the end of the second-stage of the program in 2020. The annual growth of the carbon storage was forecasted to be 6.24 Tg C/yr, which suggested that NFP program has a significant potential for enhancing carbon sequestration in plantation forests under its domain.     

The application of an innovative inverse model for understanding and predicting landslide movements (Salazie cirque landslides,Reunion Island)

The prediction of landslide movement acceleration is a complex problem, among others identified for deep-seated landslides, and represents a crucial step for risk assessment. Within the scope of this problem, the objective of this paper is to explore a modelling method that enables the study of landslide function and facilitates displacement predictions based on a limited data set. An inverse modelling approach is proposed for predicting the temporal evolution of landslide movement based on rainfall and displacement velocities. Initially, the hydrogeology of the studied landslides was conceptualised based on correlative analyses. Subsequently, we applied an inverse model with a Gaussian-exponential transfer function to reproduce the displacements. This method was tested on the Grand Ilet (GI) and Mare-à-Poule-d’Eau (HB) landslides on Reunion Island in the Indian Ocean. We show that the behaviour of landslides can be modelled by inverse models with a bimodal transfer function using a Gaussian-exponential impulse response. The cumulative displacements over 7 years of modelling (2 years of calibration period for GI, and 4 years for HB) were reproduced with an RMSE above 0.9. The characteristics of the bimodal transfer function are directly related to the hydrogeological functioning demonstrated by the correlative analyses: the rapid reaction of a landslide can be associated with the effect of a preferential flow path on groundwater level variations. Thus, this study shows that the inverse model using a Gaussian-exponential transfer function is a powerful tool for predicting deep-seated landslide movements and for studying how they function. Beyond modelling displacements, our approach effectively demonstrates its ability to contribute relevant data for conceptualising the sliding mechanisms and hydrogeology of landslides.