Impacts of Holocene climatic variations on alluvial fan activity below snowpatches in subarctic Québec

In the Lake Guillaume-Delisle area of subarctic Québec, storm-generated alluvial fans have been active sporadically throughout the Holocene. In this study, we propose that the persistence of late-lying snowpatches in fan catchments during Holocene cold episodes promoted alluvial fan activity by lowering the precipitation threshold required to trigger a torrential event. This hypothesis was tested by characterizing the depositional processes responsible for alluvial fan formation below snowpatches, and by reconstructing the Holocene alluvial fan activity. Stratigraphic and sedimentary analyses conducted on seven alluvial fans revealed that they were deposited by torrential activity leading to waterlaid, transient, or hyperconcentrated deposition. The chronology of the storm-generated alluvial fans — based on 22 radiocarbon dates — indicates that torrential activity was enhanced during the cooler Late Holocene (i.e., after ca. 3500 cal. yr BP). Snowier winters and cooler summers were beneficial to nival activity, allowing the persistence of larger snowpatches throughout the summer and fall seasons. Rainfall-induced thaw of such snowpatches during rainstorm events is inferred to have contributed to alluvial fan activity by increasing water availability. Three peaks of alluvial activity occurred during the Late Holocene (2950–2750, 1900–1400, and 800–300 cal. yr BP) and are indicative of increased storminess resulting in higher fan activity. Increased fan activity during cooler episodes was concurrent with increased runoff activity in the immediate pronival area. This stresses the importance of nivation below snowpatches and pinpoints the role of nivation in enhancing geomorphological activity during period of cooler and more humid climate in subarctic environments.     

Surface temperature differences between minerals in crystalline rocks: Implications for granular disaggregation of granites through thermal fatigue

Thermal expansion differences between minerals within rocks under insolation have previously been assumed to drive breakdown by means of granular disaggregation. However, there have been no definitive demonstrations of the efficacy of this weathering mechanism. Different surface temperatures between minerals should magnify thermal expansion differences, and thus subject adjacent minerals to repeated stresses that might cause breakdown through fatigue failure. This work confirms the existence of surface temperature differences between minerals in granitic rocks under simulated short-term temperature fluctuations so as to discriminate their potential for initiating granular disaggregation. The influence of colour, as a surrogate for albedo, and crystal size, as a function of thermal mass are specifically identified because of their ease of quantification. Four rock types with a range of these properties were examined, and subjected to repeated short-term temperature cycles by radiative heating and cooling under laboratory conditions. Results show that while albedo is the main control for overall and individual maximum temperatures, crystal size is the main factor controlling higher temperature differences between minerals. Thus, stones with large differences of mineral sizes can undergo magnified stresses due to thermal expansion differences.     

Melt loss and the preservation of granulite facies mineral assemblages

The loss of a metamorphic fluid via the partitioning of H₂O into silicate melt at higher metamorphic grade implies that, in the absence of open system behaviour of melt, the amount of H₂O contained within rocks remains constant at temperatures above the solidus. Thus, granulite facies rocks, composed of predominantly anhydrous minerals and a hydrous silicate melt should undergo considerable retrogression to hydrous upper amphibolite facies assemblages on cooling as the melt crystallizes and releases its H₂O. The common occurrence of weakly retrogressed granulite facies assemblages is consistent with substantial melt loss from the majority of granulite facies rocks. Phase diagram modelling of the effects of melt loss in hypothetical aluminous and subaluminous metapelitic compositions shows that the amount of melt that has to be removed from a rock to preserve a granulite facies assemblage varies markedly with rock composition, the number of partial melt loss events and the P–T conditions at which melt loss occurs. In an aluminous metapelite, the removal of nearly all of the melt at temperatures above the breakdown of biotite is required for the preservation of the peak mineral assemblage. In contrast, the proportion of melt loss required to preserve peak assemblages in a subaluminous metapelite is close to half that required for the aluminous metapelite. Thus, if a given proportion of melt is removed from a sequence of metapelitic granulites of varying composition, the degree of preservation of the peak metamorphic assemblage may vary widely.     

Up to what temperature is petroleum stable? New insights from a 5200 free radical reactions model

The discovery of crude oils and condensates at ever higher temperatures casts doubt on the validity of the usual geochemical modelling approach, that uses empirical reactions and rate constants. The solution used to account for such a high thermal stability is presently to adjust the rate parameters, but the physical meaning and scientific value of such a strategy can be questioned. We have developed a mechanistic model consisting of 5200 lumped free radical reactions to describe the thermal evolution of a mixture of 52 organic species meant to represent light petroleum. Rate constants used are those available in the literature or estimated using well established thermochemistry-reactivity correlations. Chemical structures included in the model are linear, branched and cyclic hydrocarbons, hydro- and alkyl-aromatics, PAHs, and three heteroatomic compounds. Reactions include cracking and alkylation chains and inhibiting and accelerating reactions from the various reactants. This model has been applied to several mixtures with various proportions of reaction inhibitors and accelerators, and to a composition representing a light mature oil. From the results obtained, we conclude that mature oils will be stable up to 240–260 °C, depending on their composition, and that the thermal cracking of oil to gas is not possible under reasonable basin conditions. The kinetics of petroleum cracking are thus much slower than generally recognized.     

Premier pôle paléomagnétique,d'âge Moscovien contraint par un test du pli,obtenu dans le bassin d'Illizi (Craton saharien,Algérie)First palaeomagnetic pole,of Moscovian age constrained by a fold test,in the Illizi Basin (Saharan Craton,Algeria)

Palaeomagnetic study, carried out in the Moscovian (～305 Ma) formation in the Edjeleh anticline, shows the existence of three magnetisation components. Two of them are probably Cenozoic and Permian remagnetisations. The third component determined by both well defined ChRMs and remagnetisation circles analysis passes the fold test. Because the folding started before or during the Stephano-Autunian, this third component is the primary magnetisation. Its palaeomagnetic pole (28.3°S, 58.9°E), close to other poles from the Saharan platform obtained from neighbouring periods but without palaeomagnetic tests, confirms the age of these last data. To cite this article: B. Bayou et al., C. R. Geoscience 334 (2002) 81–87.     

Sediment yield and storage variations in the Négron River catchment (south western Parisian Basin,France) during the Holocene period

In the Négron River catchment area (162 km²), surface‐sediment stores are composed of periglacial calcareous ‘grèze’ (5 × 10⁶ t) and loess (21 × 10⁶ t), and Holocene alluvium (12·6 × 10⁶ t), peat (0·6 × 10⁶ t) and colluvium (18·5 × 10⁶ t). Seventy‐five per cent of the Holocene sediments is stored along the thalwegs. Present net sediment yield, calculated from solid discharge at the Négron outlet, is low (0·6 t km^?2 a^?1) due to the dominance of carbonate rocks in the catchment. Mean sediment yield during the Holocene period is 7·0 t km^?2 a^?1 from alluvium stores and 7·6 t km^?2 a^?1 from colluvium stores. Thus, the gross sediment yield during the Holocene period is about 18·7 t km^?2 a^?1 and the sediment delivery ratio 3 per cent. The yield considerably varies from one sub‐basin to another (3·9 to 24·5 t km^?2 a^?1) according to lithology: about 25 per cent and 50 per cent of initial stores of periglacial grèze and loess respectively were reworked during the Holocene period. Sediment yield has increased by a factor of 6 in the last 1000 years, due to the development of agriculture. The very high rate of sediment storage on the slope during that period (88 per cent of the yield) can be accounted for by the formation of cultivation steps (‘rideaux’). It is predicted that the current destruction of these steps will result in a sediment wave reaching the valley floors in the coming decades. Subboreal and Subatlantic sediments and pollen assemblages in the Taligny marsh, where one‐third of the alluvium is stored, show the predominant influence of human activity during these periods in the Négron catchment. Copyright © 2002 John Wiley & Sons, Ltd.     

The interpretation of reaction textures in Fe‐rich metapelitic granulites of the Musgrave Block,central Australia: constraints from mineral equilibria calculations in the system K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3

Fe‐rich metapelitic granulites of the Musgrave Block, central Australia, contain several symplectic and coronal reaction textures that post‐date a peak S2 metamorphic assemblage involving garnet, sillimanite, spinel, ilmenite, K‐feldspar and quartz. The earliest reaction textures involve spinel‐ and quartz‐bearing symplectites that enclose garnet and to a lesser extent sillimanite. The symplectic spinel and quartz are in places separated by later garnet and/or sillimanite coronas. The metamorphic effects of a later, D3, event are restricted to zones of moderate to high strain where a metamorphic assemblage of garnet, sillimanite, K‐feldspar, magnetite, ilmenite, quartz and biotite is preserved. Quantitative mineral equilibria calculations in the system K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (KFMASHTO) using Thermocalc 3.0 and the accompanying internally consistent dataset provide important constraints on the influence of TiO₂ and Fe₂O₃ on biotite‐bearing and spinel‐bearing equilibria, respectively. Biotite‐bearing equilibria are shifted to higher temperatures and spinel‐bearing equilibria to higher pressures and lower temperatures in comparison to the equivalent equilibria in K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (KFMASH). The sequence of reaction textures involving spinel is consistent with a D2 P–T path that involved a small amount of decompression followed predominantly by cooling within a single mineral assemblage stability field. Thus, the reaction textures reflect changes in modal proportions within an equilibrium assemblage rather than the crossing of a univariant reaction. The D3 metamorphic assemblage is consistent with lower temperatures than those inferred for D2.     

La vallée d'Ys : un paléoréseau hydrographique immergé en baie de Douarnenez (Finistère,France)

Interpretation of the recent high-resolution survey, CANADOU 2000, in the Bay of Douarnenez (Finistère, France) allowed us to restore the morphology of the substratum and the sedimentary filling of the bay. The Brioverian and Palaeozoic substratum reveals a well-defined network of incised valleys as results of successive emergence stages of the Bay during the Quaternary. Valleys join in a westward-widened mean valley, called Ys Valley. The present-day sedimentary fill of the bay of Douarnenez appears mainly controlled by the Holocene rise and the consecutive highstand. It comprises fluvial and estuarine deposits filling up incised valleys and marine sedimentation extending out of the incised valleys. To cite this article: G. Jouet et al., C. R. Geoscience 335 (2003).To cite this article: G. Jouet et al., C. R. Geoscience 335 (2003).     

Wrench tectonics flip at oblique subduction. A model from New Zealand

In eastern North Island New Zealand, oblique subduction of the Pacific Plate beneath the Australian Plate is associated with strain partitioning. Dextral along-strike component of displacement occurred first at Early Miocene major faults within the eastern fore-arc domain. These faults were active from Early Miocene to Pliocene times. Since Pliocene times, most of the movement occurs at western faults such as the Wellington Fault. The latter joins the back-arc domain to the north. The jump of wrench faulting is related to the oblique opening of the back-arc domain. Both phenomena are impeded southwards by the Hikurangi oceanic plateau entering the subduction zone. To cite this article: J. Delteil et al., C. R. Geoscience 335 (2003).     

Classification of artificial (man-made) ground

The legacy inherited from anthropogenic processes needs to be addressed in order to provide reliable and up-to-date ground information relevant to development and regeneration in the urban environment. The legacy includes voids as well as anthropogenic deposits (artificial ground). Their characteristics derive from former quarrying and mining activities industrial processes creating derelict ground, variably consolidated made ground, and contaminated groundwater and soils. All need to be systematically assessed to inform the planning process and provide the basis for engineering solutions. Site-specific investigation needs to be conducted on the back of good quality geoscientific data. This comes from ‘field’ survey, remotely sensed data interpretation, historical maps, soil geochemical sampling, and geotechnical investigation. Three-dimensional and, in the future, four dimensional, characterization of superficial deposits is required to reach an understanding of the potential spatial lithological variability of artificial ground and the geometry of important surfaces, i.e. the boundary conditions. The classification scheme for artificial ground outlined in this paper and adopted by the British Geological Survey, will help in achieving this understanding.