Early evaluation of coastal nutrient over-enrichment: new procedures and indicators

Recent studies have provided compelling evidence for an accelerated anthropogenic impact on coastal systems, resulting in intense inputs of materials and nutrients from the continent. This has led scientists and policymakers to encourage the implementation of monitoring programmes, which have resulted in the multiplicity of datasets. However surprisingly, only a few attempts have been made to couple observations with statistical and mathematical tools to detect, as soon as the data become available perturbations in coastal systems. Here, we propose new mathematical procedures to evaluate the state of a system, based on the building of relative reference state and indicators of nutrient over-enrichment. The techniques were tested in some French coastal systems using data from the programme SOMLIT. Applied to this dataset, the multivariate procedures rapidly identified and evaluated anthropogenic nutrient anomalies from the continent on three sites (Wimereux, Roscoff and Villefranche-sur-Mer) from 1997 onwards.     

Preliminary results From a partial LRTAP model based on an existing meteorological forecast model

Abstract

An existing state‐of‐the‐art regional meteorological model is coupled through appropriate constituent mass conservation equations to model the long‐range transport of atmospheric pollutants (LRTAP) under restrictive constraints on atmospheric chemistry and deposition. Particular emphasis is given to the importance of a good representation of turbulence and other sub grid‐scale processes in the planetary boundary layer (PBL), both in the formulation and in the interpretation of the results. The regional meteorological model provides not only forecasts of wind velocity and temperature, but also vertical diffusion profiles consistent with the evolution of its PBL. The transport in the LRTAP model is handled by computationally stable algorithms such that the time step may be chosen on the basis of accuracy rather than stability, and the chemistry is described by a simple four‐species model of the oxidation of sulphur dioxide and nitrogen dioxide. Results are presented of a sample 48‐h summer simulation over central and eastern North America, using real meteorological data and time‐averaged emission inventory data; parameters of the integration include a one‐hour time step, a horizontal resolution of 100 km and 15 variably spaced vertical levels, 10 of which are contained in the lower one third of the atmosphere. It is argued that despite the simplicity of the chemistry, the results are qualitatively realistic and the high impact of the PBL processes on LRTAP is evident. For this particular simulation, it is interesting to note the existence of a region over Nova Scotia where the deposition of sulphates is significantly greater than that which could be expected from local sources. This is interpreted as being due to the confluence of two flows that pass over two different centres of high emission ofSC>2, andas being evidence of the model's ability to qualitatively model LRTAP.     

Thermal Conductivity of Argillaceous Rocks: Determination Methodology Using In Situ Heating Tests

This study focuses on the characterisation of thermal conductivity for three potential host rocks for radioactive waste disposal. First, the heat conduction process is reviewed on the basis of an analytical solution and key aspects related to anisotropic conduction are discussed. Then the existing information on the three rocks is summarised and a broad uncertainty range of thermal conductivity is estimated based on the mineralogical composition. Procedures to backanalyse the thermal conductivity on the basis of in situ heating tests are assessed and a methodology is put forward. Finally, this methodology is used to estimate the impact of experimental uncertainties and applied to the four in situ heating tests. In the three potential host rocks, a clear influence of the bedding planes was identified and anisotropic heat conduction was shown to be necessary to interpret the observed temperature field. Experimental uncertainties were also shown to induce a larger uncertainty on the anisotropy ratio than on the equivalent thermal conductivity defined as the geometric mean of the thermal conductivity in the three principal directions.     

The irradiation history of the Ghubara (L5) regolith breccia

Abstract— We measured cosmic‐ray products—noble gases, radionuclides, thermoluminescence, and nuclear tracks—and trace element contents and mineralogy of samples of three orthogonal and mutually intersecting cores (41–46 cm long) of a 101.6 kg Ghubara individual (1958,805) at The Natural History Museum, London. The xenoliths, like the host, have high concentrations of trapped solar gases and are heavily shocked. While contents of noble gases and degree of shock‐loading in this individual and three others differ somewhat, the data indicate that Ghubara is a two‐generation regolith breccia. Contents of cosmogenic ²⁶Al and ¹⁰Be and low track densities indicate that the Ghubara individuals were located more than 15 cm below the surface of an 85 cm meteoroid. Because of its large size, Ghubara's cosmic‐ray exposure age is poorly defined to be 15–20 Ma from cosmogenic nuclides. Ghubara's terrestrial age, based on ¹⁴C data, is 2–3 ka. Not only is Ghubara the first known case of a two‐generation regolith breccia on the macroscale, it also has a complicated thermal and irradiation history.     

Evaluating the genetic effects of the invasive Ocenebra inornata on the native oyster drill Ocenebra erinacea

Studies focusing on the effect of invasive species on the genetic diversity of native marine invertebrates remain scant. Here we report diversity among French populations of the intertidal gastropod Ocenebra erinacea (Linnaeus, 1758) sampled in the presence and absence of the invasive Ocenebra inornata (Recluz, 1851). Between 1999 and 2004, a total of 352 individuals of O. erinacea was collected from 15 sites (five of which had the invasive present) and was genotyped at the mitochondrial locus Cytochrome Oxidase 1 (cox1). No statistical difference was observed between polymorphism levels recorded within native populations exposed to the invasive, compared with populations sampled in the absence of O. inornata. No sign of native population decline was detected in response to the invader. While significant shifts in native O. erinacea population sizes have previously been reported in the literature, genetic effects may take longer to accumulate, or may be undetectable without a larger panel of genetic markers. By contrast, large genetic distances and significant population differentiation were recorded between Atlantic and Mediterranean O. erinacea samples, suggesting that these populations have distinct evolutionary histories. Comparison of genetic divergence within the closely related genus Nucella suggests that the Atlantic populations of O. erinacea and those from Thau Lagoon in the Mediterranean may belong to different species or subspecies.     

Pyroxene structures,cathodoluminescence and the thermal history of the enstatite chondrites

Abstract— In order to explore the thermal history of enstatite chondrites, we examined the cathodoluminescence (CL) and thermoluminescence (TL) properties of 15 EH chondrites and 21 EL chondrites, including all available petrographic types, both textural types 3–6 and mineralogical types α–δ. The CL properties of EL3α and EH3α chondrites are similar. Enstatite grains high in Mn and other transition metals display red CL, while enstatite with low concentrations of these elements show blue CL. A few enstatite grains with >5 wt% FeO display no CL. In contrast, the luminescent properties of the metamorphosed EH chondrites are very different from those of metamorphosed EL chondrites. While the enstatites in metamorphosed EH chondrites display predominantly blue CL, the enstatites in metamorphosed EL chondrites display a distinctive magenta CL with blue and red peaks of approximately equal intensity in their spectra. The TL sensitivities of the enstatite chondrites correlate with the intensity of the blue CL and, unlike other meteorite classes, are not simply related to metamorphism. The different luminescent properties of metamorphosed EH and EL chondrites cannot readily be attributed to compositional differences. But x-ray diffraction data suggests that the enstatite in EH5γ,δ chondrites is predominantly disordered orthopyroxene, while enstatite in EL6β chondrites is predominantly ordered orthopyroxene. The difference in thermal history of metamorphosed EL and EH chondrites is so marked that the use of single “petrographic” types is misleading, and separate textural and mineralogical types are preferable. Our data confirm earlier suggestions that metamorphosed EH chondrites underwent relatively rapid cooling, and the metamorphosed EL chondrites cooled more slowly and experienced prolonged heating in the orthopyroxene field.