Geology of the volcanic-hosted Brockman rare-metals deposit,Halls Creek Mobile Zone,northwest Australia. l. Volcanic environment,geochronology and petrography of the Brockman volcanics

Summary Rare-metals mineralization of the Brockman deposit (Halls Creek Mobile Zone, NW Australia) is hosted in a fluorite-bearing, rhyolitic volcaniclastic unit informally termed the Niobium Tuff. The Tuff, more correctly described as a tuffaceous volcaniclastic deposit, is the lowermost unit of a sequence of trachyte-to-rhyolite lavas, trachyandesite subvolcanic rocks, and volcaniclastic units of the Brockman volcanics located within the Halls Creek Group, a thick, early Proterozoic volcano-sedimentary sequence. High precision SHRIMP ion-microprobe zircon dating of the Niobium Tuff gives an eruption age of 1870 ± 4 Ma. Regional geochronological constraints indicate the Niobium Tuff was deposited about 15 Ma before major orogenic activity affected the area. Despite folding, faulting and low-grade metamorphism, the Brockman volcanics show excellent preservation of primary volcanological features, including pillow-lavas and pillow-breccias, that suggest a dominantly subaqueous, below-wave-base emplacement environment. The style of eruption products and magma volume constraints suggest the trachyte-dominated volcanics were erupted from a small shield volcanic complex probably in a rift-related basin in a shallow-marine setting. The tectonic setting was intraplate but differs from most Tertiary to recent trachyte volcanic complexes which are largely subaerial, are built on relatively thick continental crust, and show no post-eruptive orogenic history. Brockman-style rare-metal deposits are characterized by preservation of subaqueous volcanics beneath a thick sedimentary sequence, eruption of early incompatible-element enriched products followed by less differentiated magmas, and fine-grained mineralogy influenced by alteration processes. Prospects exist for discovery of analogous deposits, particularly in early Proterozoic mobile belts and Tertiary intraplate shield volcanic provinces.

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Geologie der an Vulkanite gebundenen Seltene-Metalle-Lagerstätte Brockman, Halls Creek Mobile Zone, Nordwest-Australien. I. Vulkanologie, Geochronologie und Petrographie der Brockman-Vulkanite

Zusammenfassung Selten-Metall-Vererzung der Brockman-Lagerstätten (Halls Creek Mobile Zone, NW Australien) sitzt in einer Fluorit-führenden, rhyolitischen vulkanoklastischen Einheit auf, die informell als der Niob-Tuff bezeichnet wird. Es handelt sich hier um ein vulkanoklastisches Tuff-Sediment; dieses ist die unterste Einheit einer Abfolge vor Trachyt bis Rhyolit-Laven, trachyandesitischen Subvulkaniten and vulkanoklastischen Einheiten der Brockman Vulkanite innerhalb der Halls Creek Gruppe, einer mächtigen frühproterozoischen vulkanosedimentdren Abfolge. Prüzisionsdatierungen des Niob Tuffs mit der SHRIMP Ionen-Mikrosonde ergeben ein Eruptionsalter von 1870 +-4 Millionen Jahren. Regionale geochronologische Zusammenhänge zeigen, daß der Niob Tuff etwa 15 Millionen Jahre vor einer größeren Orogenese, die das Gebiet betroffen hat, abgelagert wurde. Trotz Faltung, Bruchtektonik and niedriggradiger Metamorphose zeigen die Brockman-Vulkanite einen hervorragenden Erhaltungszustand primärer vulkanologischer Erscheinungen. Diese urnfassen auch Kissenlaven und KissenBreckzien, die eine vorwiegend subaquatische Ablagerung in ruhigem Wasser erkennen lassen. Die Art der Eruptionsprodukte and das Magmavolumen zeigen, daß die Trachytdominierten Vulkanite von einem kleinen Schildvulkan stammer, wahrscheinlich in einem Becken in einer Rift-Situation im seichten marinen Milieu. Die tektonische Situation war intraplate, aber unterscheidet sich von den meisten tertiären bis rezenten trachytischen Vulkan-Komplexen, die hauptsächlich subaerisch sind, auf einer relativ mächtigen kontinentalen Kruste aufsitzen, and keine post-eruptive orogene Entwicklung zeigen. Seltene-Metalle-Lagerstatten des Brockman-Typs rind durch die Erhaltung subaquatischer-Vulkanite unterhalb einer machtigen sedimentdren Abfolge gekennzeichnet; welters durch frühe Eruptionsprodukte, die an inkompatiblen Elementen angereichert sind, auf die dann weniger differenzierte Magmen folgten, und schließlich durch einen feinkörnigen Mineralbestand, der vor Umwandlungsprozessen betroffen war. Es besteht die Möglichkeit der Entdeckung analoger Lagerstätten, besonders in frühproterozoischen mobilen Gürteln und in tertidren intraplate Schildvulkan Provinzen.

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Mesoproterozoic Fraser Complex: Geochemical evidence for multiple subduction‐related sources of lower crustal rocks in the Albany‐Fraser Orogen,Western Australia

The 1300 Ma Fraser Complex in the Albany‐Fraser Orogen of Western Australia is a thrust stack of mainly gabbroic rocks metamorphosed to granulite facies. This package of fault‐bounded units was elevated from a deep crustal level onto the margin of the Yilgarn Craton during continental collision between the Mawson and Yilgarn Cratons. Incompatible trace‐element distributions demand at least three mantle sources. Primitive‐mantle‐normalised incompatible‐element distributions show strong negative Ta–Nb anomalies, typical of subduction‐derived magmas. Three lines of evidence indicate that the mafic magmas did not acquire these anomalies by assimilation of crustal rocks: (i) major‐element compositions do not allow appreciable contamination with felsic material; (ii) Ni contents of many mafic rocks are too high for a significant contribution from a felsic assimilant; and (iii) Sr and Nd isotopic data support a largely juvenile source for the magmas that produced the Fraser Complex. Hence, the Ta–Nb anomalies are interpreted to reflect subduction‐related magmatic sources. On multielement diagrams, depletions in Sr, Eu, P, and Ti can be explained by fractional crystallisation, whereas Th and Rb depletions in many of the Fraser Complex rocks probably reflect losses during granulite‐facies metamorphism. These results suggest that the lower crust in this region at 1300 Ma was dominantly of arc origin, and there is no evidence to support mantle plume components. The Fraser Complex is interpreted as remnants of oceanic arcs that were swept together and tectonically interleaved with the margin of the Mawson Craton just before, or during, collision with the Yilgarn Craton at 1300 Ma.     

Ecohydrographic constraints on biodiversity and distribution of phytoplankton and zooplankton in coral reefs of the Red Sea,Saudi Arabia

An integral concept of ecological research is the constraint of biodiversity along latitudinal and environmental gradients. The Red Sea features a natural example of a latitudinal gradient of salinity, temperature and nutrient richness. Coral reefs along the Red Sea coasts are supported with allochthonous resources such as oceanic and neritic phytoplankton and zooplankton; however, relatively little is known about how the ecohydrography correlates with plankton biodiversity and abundance. In this article we present the biodiversity of phytoplankton and zooplankton in Red Sea coral reefs. Oceanographic data (temperature, salinity), water samples for nutrient analysis, particulate organic matter, phytoplankton and zooplankton, the latter with special reference to Copepoda (Crustacea), were collected at nine coral reefs over ~1500 km distance along the Red Sea coast of Saudi Arabia. The trophic state of ambient waters [as indicated by chlorophyll a (Chl a)] changed from strong oligotrophy in the north to mesotrophy in the south and was associated with increasing biomasses of Bacillariophyceae, picoeukaryotes and Synechococcus as indicated by pigment fingerprinting (CHEMTAX) and flow cytometry. Net‐phytoplankton microscopy revealed a Trichodesmium erythraeum (Cyanobacteria) bloom north of the Farasan Islands. Several potentially harmful algae, including Dinophysis miles and Gonyaulax spinifera (Dinophyceae), were encountered in larger numbers in the vicinity of the aquaculture facilities at Al Lith. Changes in zooplankton abundance were mainly correlated to the phytoplankton biomass following the latitudinal gradient. The largest zooplankton abundance was observed at the Farasan Archipelago, despite high abundances of copepodites, veligers (Gastropoda larvae) and Chaetognatha at Al Lith. Although the community composition changed over latitude, biodiversity indices of phytoplankton and zooplankton did not exhibit a systematic pattern. As this study constitutes the first current account of the plankton biodiversity in Red Sea coral reefs at a large spatial scale, the results will be informative for ecosystem‐based management along the coastline of Saudi Arabia.     

Light curve analysis of the short period eclipsing binary RT and

We have analysed the 1978 UBV photoelectric observations of the short-period (RS CVn type) binary system RT And, using the rectifiable methods of Russell and Merrill (1952) and Kitamura (1965). The primary minimum is a transit. The solutions allow us to classify the system as a detached one, but a certain disagreement results with respect to solutions of previous epochs. A graphical test of the reliability of the solution is given.     

A Parameterization of Third-order Moments for the Dry Convective Boundary Layer

We describe one-dimensional (1D) simulations of the countergradient zone of mean potential temperature observed in the convective boundary layer (CBL). The method takes into account the third-order moments (TOMs) in a turbulent scheme of relatively low order, using the turbulent kinetic energy equation but without prognostic equations for other second-order moments. The countergradient term is formally linked to the third-order moments and , and a simple parameterization of these TOMs is proposed. It is validated for several cases of a dry CBL, using large-eddy simulations that have been realized from the MESO-NH model. The analysis of the simulations shows that TOMs are responsible for the inversion of the sign of in the higher part of the CBL, and budget analysis shows that the main terms responsible for turbulent fluxes and variances are now well reproduced.     

An objective classification system of air mass types for Szeged, Hungary, with special interest in air pollution levels

Summary This paper determines the characteristic air mass types over the Carpathian Basin for the winter (December, January, and February) and summer (June, July and August) months dependant on levels of the main air pollutants. Based on the ECMWF data set, daily sea-level pressure fields analysed at 00 UTC were prepared for each air mass type (cluster) in order to relate sea-level pressure patterns with the level of air pollutants in Szeged. The data comprise daily values of twelve meteorological and eight pollutant parameters for the period 1997–2001. Objective definition of the characteristic air mass types is achieved by using the methods of Factor Analysis and Cluster Analysis. According to the results, during the winter months five air mass types (clusters) were detected based on higher concentrations of primary pollutants that occur with high irradiance and low wind speed. This is the case when an anticyclone is found over the Carpathian Basin and over the region south of Hungary, influencing the weather of the country. Low levels of pollutants occur when zonal currents exert influence over Hungary. During the summer months anticyclones and anticyclone ridge situations are found over the Carpathian Basin. (During the prevalence of anticyclone ridge situations, the Carpathian Basin is found at the edge of a high pressure centre.) As a result of high irradiance and very low NO levels, secondary pollutants are highly enriched.     

Isotope geochemistry and Re–Os geochronology of the Yanjiagou Mo deposit in the central North China Craton

The Yanjiagou deposit, located in the central North China Craton (NCC), is a newly found porphyry‐type Mo deposit. The Mo mineralization here is spatially associated with the Mapeng batholith. In this study, we identify four stages of ore formation in this deposit: pyrite phyllic stage (I), quartz–pyrite stage (II), quartz–pyrite–molybdenite stage (III), which is the main mineralization stage, and quartz–carbonate stage (IV). We present sulphur and lead isotope data on pyrite, and rhenium and osmium isotopes of molybdenite from the porphyry deposit and evaluate the timing and origin of ore formation. The δ³⁴S values of the pyrite range from ‐1.1‰ to −0.6‰, with an average of −0.875‰, suggesting origin from a mixture of magmatic/mantle sources and the basement rocks. The Pb isotope compositions of the pyrite show a range of 16.369 to 17.079 for ²⁰⁶Pb/²⁰⁴Pb, 15.201 to 15.355 for ²⁰⁷Pb/²⁰⁴Pb, and 36.696 to 37.380 for ²⁰⁸Pb/²⁰⁴Pb, indicating that the ore‐forming materials were derived from a mixture of lower crust (or basement rocks) and mantle. Rhenium contents in molybdenite samples from the main ore stage are between 74.73 to 254.43 ppm, with an average of 147.9 ppm, indicating a mixed crustal‐mantle source for the metal. Eight molybdenite separates yield model ages ranging from 124.17 to 130.80 Ma and a mean model age of 128.46 Ma. An isochron age of 126.7 ± 1.1 Ma (MSWD = 2.1, initial ¹⁸⁷Os = 0.0032 ± 0.0012 ppb) is computed, which reveals a close link between the Mo mineralization and the magmatism that generated the Mapeng batholith. The age is close to the zircon U–Pb age of ca. 130 Ma from the batholith reported in a recent study. The age is also consistent with the timing of mineralization in the Fuping ore cluster in the central NCC, as well as the peak time of lithosphere thinning and destruction of the NCC. We evaluate the spatio‐temporal distribution of the Mo deposits in the NCC and identify three important molybdenum provinces along the northern and southern margins of the craton formed during three distinct episodes: Middle to Late Triassic (240–220 Ma), Early Jurassic (190–175 Ma), and Late Jurassic to Early Cretaceous (150–125 Ma). The third period is considered to mark the most important metallogenic event, coinciding with the peak of lithosphere thinning and craton destruction in the NCC. Copyright © 2014 John Wiley & Sons, Ltd.     

Unified modeling of flow liquefaction and cyclic mobility

Flow liquefaction and cyclic mobility are two different phenomena that are encountered during strong earthquakes. Flow liquefaction is associated with the contractive behavior of loose granular materials and cyclic mobility is associated with the dilative response of both loose and dense granular materials at low confining stresses. These two types of response pertain to the same material and therefore should be modeled in a consistent manner. Whether a soil in a given state exhibits contractive or dilative behavior is dependent on its dilatancy, d=d_v^p/d_q^p. A form of the dilatancy d=d(η,ψ,C) is proposed, where η=q/p is the stress ratio, and ψ and C denote the internal state variables and the intrinsic properties, respectively. It has been shown that such a state-dependent dilatancy is effective in describing both the contractive and dilative behavior. This allows the soil behavior associated with flow liquefaction and cyclic mobility during earthquakes to be modeled in a unified way.     

大气和植被生态及土壤系统水文过程相互作用的一些研究

利用我国测站的降水资料、卫星测得的OLR和高云量资料、SST和137°E次表层海温资料以及NCEP/NCAR再分析资料,分析了东亚夏季风的爆发和北进的年际变化特征及其与热带西太平洋热状态的关系.分析结果表明:当春季热带西太平洋处于暖状态,菲律宾周围对流活动强,在这种情况下,南海上空对流层下层有气旋性距平环流,西太平洋副热带高压偏东,从而使得南海夏季风爆发早;并且,当夏季热带西太平洋也处于暖状态,菲律宾周围对流活动也很强,在这种情况下,西太平洋副热带高压北进时,在6月中旬和7月初存在明显的突跳,从而使得东亚季风雨带在6月中旬明显由华南北跳到江淮流域,并于7月初由江淮流域北跳到黄河流域、华北和东北地区.这将引起江淮流域和长江中、下游夏季风降水偏少,并往往发生干旱,而黄河流域、华北和东北地区的夏季降水正常或偏多.相反,当春季热带西太平洋处于冷状态,菲律宾周围对流活动弱,在这种情况下,南海上空对流层下层有反气旋性距平环流,西太平洋副热带高压偏西,从而使得南海夏季风爆发晚;并且,当夏季热带西太平洋也处于冷状态,菲律宾周围对流活动也很弱,在这种情况下,西太平洋副热带高压北进时,在6月中旬或7月初向北突跳并不明显,而是以渐进式向北移动,从而使得东亚季风雨带一直维持在长江流域和淮河流域.这将引起此两流域夏季风降水偏多,并往往发生洪涝,而黄河流域、华北和东北地区的夏季降水偏少,发生干旱.作者还从非线性多平衡态动力理论说明了菲律宾周围对流活动强弱对西太平洋副热带高压北进时以突跳或渐进式向北移动起到重要作用.