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31.
32.
Si K- and L-edge ELNES spectroscopy and multiple-scattering (MS) calculations are used to examine mixed Si coordination compounds
varying in SiVI:SiIV ratio. As in previous studies, the edges are influenced mainly by silicon coordination (tetrahedral vs. octahedral), as supported
by the MS calculations. We demonstrate two methods semi-quantitatively to extract the value of SiVI/(SiVI+SiIV): (1) A linear relationship between the L2,3-L1 splitting and SiVI/(SiVI+SiIV) is observed, (2) a fitting method based on the coaddition of reference tetrahedral and octahedral Si spectra is applied
to both Si K- and L-edge ELNES spectra.
Received: February 10, 1997 / Revised, accepted: May 23, 1997 相似文献
33.
Rhian H Jones Laurie A Leshin Zachary D Sharp Alan J Schilk 《Geochimica et cosmochimica acta》2004,68(16):3423-3438
We report a study of the oxygen isotope ratios of chondrules and their constituent mineral grains from the Mokoia, oxidized CV3 chondrite. Bulk oxygen isotope ratios of 23 individual chondrules were determined by laser ablation fluorination, and oxygen isotope ratios of individual grains, mostly olivine, were obtained in situ on polished mounts using secondary ion mass spectrometry (SIMS). Our results can be compared with data obtained previously for the oxidized CV3 chondrite, Allende. Bulk oxygen isotope ratios of Mokoia chondrules form an array on an oxygen three-isotope plot that is subparallel to, and slightly displaced from, the CCAM (carbonaceous chondrite anhydrous minerals) line. The best-fit line for all CV3 chondrite chondrules has a slope of 0.99, and is displaced significantly (by δ17O ∼ −2.5‰) from the Young and Russell slope-one line for unaltered calcium-aluminum-rich inclusion (CAI) minerals. Oxygen isotope ratios of many bulk CAIs also lie on the CV-chondrule line, which is the most relevant oxygen isotope array for most CV chondrite components. Bulk oxygen isotope ratios of most chondrules in Mokoia have δ18O values around 0‰, and olivine grains in these chondrules have similar oxygen isotope ratios to their bulk values. In general, it appears that chondrule mesostases have higher δ18O values than olivines in the same chondrules. Our bulk chondrule data spread to lower δ18O values than any ferromagnesian chondrules that have been measured previously. Two chondrules with the lowest bulk δ18O values (−7.5‰ and −11.7‰) contain olivine grains that display an extremely wide range of oxygen isotope ratios, down to δ17O, δ18O around -50‰ in one chondrule. In these chondrules, there are no apparent relict grains, and essentially no relationships between olivine compositions, which are homogeneous, and oxygen isotopic compositions of individual grains. Heterogeneity of oxygen isotope ratios within these chondrules may be the result of incorporation of relict grains from objects such as amoeboid olivine aggregates, followed by solid-state chemical diffusion without concomitant oxygen equilibration. Alternatively, oxygen isotope exchange between an 16O-rich precursor and an 16O-poor gas may have taken place during chondrule formation, and these chondrules may represent partially equilibrated systems in which isotopic heterogeneities became frozen into the crystallizing olivine grains. If this is the case, we can infer that the earliest nebular solids from which chondrules formed had δ17O and δ18O values around -50‰, similar to those observed in refractory inclusions. 相似文献
34.
Sami Khomsi Mourad Bédir M. Ghazi Ben Jemia Hédi Zouari 《Comptes Rendus Geoscience》2004,336(15):1401-1408
Structural interpretations of newly acquired seismic lines in northeastern Tunisia allow us to highlight a new thrust front for the Atlasic range of Tunisia, in contrast to the previously Zaghouan fault thrust Dorsale zone. This new thrust front takes place on weakness tectonic zones, materialized by inherited faults anchored on the pre-Triassic basement. This front seems to be a paleogeographic trend controlling structural style and basin fill with a synsedimentary activity. The front is expressed by reverse faults, thrust faults, back thrusting, and decollement structures. To cite this article: S. Khomsi et al., C. R. Geoscience 336 (2004). 相似文献
35.
36.
Rouaida Trabelsi Moncef Zaïri Habib Smida Hamed Ben Dhia 《Comptes Rendus Geoscience》2005,337(5):515-524
The intensive agricultural and economic activities induce the increase of the risk of groundwater quality degradation through high groundwater pumping rates. The salinization and contamination are the main sources of this pollution, especially in coastal aquifers. The explanation of the origin of salinity for the shallow aquifer of Northern Sahel of Sfax was analysed by a chemical study of the groundwater main compounds. The partitioning of groundwaters into homogenous groups is undertaken by graphical techniques, including a Stiff pattern diagram, an expanded Durov diagram and several binary diagrams. The study indicates the presence of various salinization processes. In the recharge area, salinization is the result of dissolution/precipitation of the aquifer formation material (group I). The irrigation water return and the intensive pumping have been identified as major sources of salinization in the south by direct cation exchange and mixing reactions (groups II and III). The anomaly of high groundwater salinity observed near the Hazeg zone was explained by the presence of a seawater intrusion in this area. This hypothesis is related to the high chloride concentration, to the presence of inverse cation exchange reactions (group IV), and to the piezometric level inferior to sea level. To cite this article: R. Trabelsi et al., C. R. Geoscience 337 (2005). 相似文献
37.
Dorra Tanfous Amri Mourad Bédir Mohamed Soussi Hajer Azaiez Lahoussine Zitouni M. Hédi Inoubli Kamel Ben Boubaker 《Comptes Rendus Geoscience》2005,337(7):703-711
Seismic and sequence stratigraphy analyses, petroleum-well control and surface data studies of the Majoura–El Hfay region in the Central Atlas of Tunisia had led to identify and calibrate Jurassic seismic horizons. Seismic stratigraphic sections, seismic tectonics analyses, isochron and isopach mapping of Jurassic sequences show a differentiated structuring of platform and depocentre blocks limited by deep-seated NE–SW, north–south east–west and NW–SE faults intruded by Upper Triassic salt. The early salt migration seems to have started by the platform fracturing during the Lower Liassic rifting event. These movements are fossilized by thickness variations of Jurassic horizons, aggrading and retrograding onlap and toplap structures between subsiding rim-syncline gutters and high platform flanks intruded by salt pillows and domes. The salt migration is also attested by Middle and Upper Jurassic space depocentre migrations. Around the Majoura–El Hfay study blocks bounded by master faults, Triassic salt have pierced the Cretaceous and Tertiary sedimentary cover in a salt diapir extrusion and salt wall structures. To cite this article: D. Tanfous Amri et al., C. R. Geoscience 337 (2005). 相似文献
38.
Laurence Le Callonnec Alain Person Maurice Renard René Létolle Nathalie Nebout Leila Ben Khelifa Ivan Rubanov 《Comptes Rendus Geoscience》2005,337(12):1035-1044
The withdrawal of the Aral Sea tributaries (Amu and Syr Daria) for cultures has led to significant falls of its level and an important increase in its salinity. During the Holocene, a succession of low and high water inputs occurred. Silty deposits correspond to the high levels and carbonates to the low levels. This study makes a distinction between the Syr Daria and the Amu Daria water inputs during low-level periods by using mineralogical and chemical compositions of the carbonates deposits. Waters from the Syr Daria are more sulphatic and have a low iron content in comparison with that of the Amu Daria. The Syr Daria was the major tributary around 7500, 4956 and 970 yr?BP, whereas around 6200 and 3610 yr?BP, inflow also from the Amu Daria is observed. To cite this article: L. Le Callonnec et al., C. R. Geoscience 337 (2005). 相似文献
39.
40.
WANG Fang HE Yongtao FU Gang NIU Ben ZHANG Haorui LI Meng WANG Zhipeng WANG Xiangtao ZHANG Xianzhou 《资源与生态学报(英文版)》2020,11(3):290-297
Enclosure is one of the most widely used management tools for degraded alpine grassland on the northern Tibetan Plateau, but the responses of different types of grassland to enclosure may vary, and research on these responses can provide a scientific basis for improving ecological conservation. This study took one site for each of three grassland types (alpine meadow, alpine steppe and alpine desert) on the northern Tibetan Plateau as examples, and explored the effects of enclosure on plant and soil nutrients by comparing differences in plant community biomass, leaf-soil nutrient content and their stoichiometry between samples from inside and outside the fence. The results showed that enclosure can significantly increase all aboveground biomass in these three grassland types, but it only increased the 10-20 cm underground biomass in the alpine desert. Enclosure also significantly increased the leaf nutrient content of the dominant plants and contents of total nitrogen (N), total potassium (K), and organic carbon (C) in 10-20 cm soil in alpine desert, thus changing the stoichiometry between C, N and P (phosphorus). However, enclosure significantly increased only the N content of dominant plant leaves in alpine steppe, while other nutrients and stoichiometries of both plant leaves and soil did not show significant differences in alpine meadow and alpine steppe. These results suggested that enclosure has differential effects on these three types of alpine grasslands on the northern Tibetan Plateau, and the alpine desert showed the most active ecological conservation in the responses of its soil and plant nutrients. 相似文献