Earthquake behavior of structures with copper energy dissipators

The earthquake behavior of structures with supplemental copper dampers is evaluated in this study. The investigation is divided into two parts: (i) an experimental work with seven pairs of hourglass copper dampers of different aspect ratios and side profiles; and (ii) a parametric study of 6‐, 12‐, and 25‐story planar structures with elastic as well as inelastic behavior in the primary structure and copper dampers. The copper used in this study is electrolytic tough pitch (ETP) copper C11000; probably the most commonly used of all coppers; ductile, with a low‐yield, and highly resistant to corrosion. Experimental results demonstrate that all copper plates reached stable angular distortions of the order of γ=25%, which implies transverse distortions in the devices larger than 40mm. The behavior of the devices is highly dependent on the aspect ratio of the plate, h/t, and a recommendation is made to use plates in the range 11 h/t≤18. Plates beyond this range exhibit either large stress and strain concentrations in the neck of the device or a strong influence of axial deformations in their cyclic behavior. The inelastic earthquake response of structures with such devices shows that drift reduction factors of the order of 30 to 40% can be achieved with reasonably economic designs. It is also shown that the efficiency of these devices depends on the soil conditions and flexibility of the primary structure. Finally, it is concluded that supplemental copper dampers are a good alternative for drift reduction in a wide range of structural layouts, ranging from coupled shear‐wall systems to moment‐resisting frames, and for impulsive as well as non‐impulsive ground motions. Copyright © 2003 John Wiley & Sons, Ltd.     

Atmospheric Disturbances that Generate Intermittent Turbulence in Nocturnal Boundary Layers

Using the unprecedented observational facilities deployed duringthe 1999 Cooperative Atmosphere-Surface Exchange Study (CASES-99),we found three distinct turbulent events on the night of 18October 1999. These events resulted from a density current,solitary wave, and internal gravity wave, respectively. Our studyfocuses on the turbulence intermittency generated by the solitarywave and internal gravity wave, and intermittent turbulenceepisodes associated with pressure change and wind direction shiftsadjacent to the ground. Both the solitary and internal gravitywaves propagated horizontally and downward. During the passage ofboth the solitary and internal gravity waves, local thermal andshear instabilities were generated as cold air was pushed abovewarm air and wind gusts reached to the ground. These thermal andshear instabilities triggered turbulent mixing events. Inaddition, strong vertical acceleration associated with thesolitary wave led to large non-hydrostatic pressure perturbationsthat were positively correlated with temperature. The directionaldifference between the propagation of the internal gravity waveand the ambient flow led to lateral rolls. These episodic studiesdemonstrate that non-local disturbances are responsible for localthermal and shear instabilities, leading to intermittentturbulence in nocturnal boundary layers. The origin of thesenon-local disturbances needs to be understood to improve mesoscalenumerical model performance.     

A band selection technique for spectral classification

In hyperspectral remote sensing, sensors acquire reflectance values at many different wavelength bands, to cover a complete spectral interval. These measurements are strongly correlated, and no new information might be added when increasing the spectral resolution. Moreover, the higher number of spectral bands increases the complexity of a classification task. Therefore, feature reduction is a crucial step. An alternative would be to choose the required sensor bands settings a priori. In this letter, we introduce a statistical procedure to provide band settings for a specific classification task. The proposed procedure selects wavelength band settings which optimize the separation between the different spectral classes. The method is applicable as a band reduction technique, but it can as well serve the purpose of data interpretation or be an aid in sensor design. Results on a vegetation classification task show an improvement in classification performance over feature selection and other band selection techniques.     

Uptake and depuration of PAHs and chlorinated pesticides by semi-permeable membrane devices (SPMDs) and green-lipped mussels (Perna viridis)

Semi-batch seawater experiments were conducted to follow the uptake and release of selected PAHs (anthracene, fluorathene, pyrene and B[a]P) and organochlorine pesticides (α-HCH, aldrin, dieldrin, p,p′-DDT) in semi-permeable membrane devices (SPMDs) and green-lipped mussels (Perna viridis). Mathematical models were applied to describe the uptake and elimination curves of the contaminants for SPMDs, and kinetic parameters, such as uptake rate constants, and equilibrium triolein/water partitioning coefficients were calculated. SPMD data showed a good fit to estimate rate constant and partition coefficient equations, but only those contaminants which partitioned mainly in the dissolved phase (α-HCH and dieldrin) were well explained for mussels. Poor conformity of the other contaminants indicated mussels uptake by routes other than diffusion, such as ingestion of algae. An apparent equilibrium state was only noted for α-HCH in mussels. Aldrin was not detected in mussels in the first few days of exposure, indicating potential metabolism of this compound. B[a]P was not detected in the triolein of SPMDs, which suggests that the membrane may act as a reservoir. Loss of spiked B[a]P from the triolein was evident in a depuration experiment, which may indicate transfer to the membrane. Rate constants for mussels were higher than those for SPMDs, but the reverse was true for partition coefficients. Overall, mussels and SPMDs had similar uptake rates for all compounds in this study, excluding p,p′-DDT and dieldrin. Contaminant elimination took place more rapidly in mussels, implying that SPMDs are better candidates for detecting episodic discharge of organic contaminants.     

Exploring the role of topography in small channel erosion

Erosion caused by concentrated flows in agricultural areas is responsible for important soil losses, and rapid sediment transfer through the channel network. The main factors controlling concentrated flow erosion rates include the erodibility of soil materials, soil use and management, climate and watershed topography. In this paper, two topographic indices, closely related to mathematical expressions suggested by different authors, are used to characterize the influence of watershed topography on gully erosion. The AS1 index is defined as the product of the watershed area and the partial area‐weighted average slope. The AS2 index is similar to the AS1 but uses the swale slope as the weighting factor. Formally, AS2 is the product of the watershed area and the length‐weighted average swale slope. From studies made using different ephemeral gully erosion databases, it is shown that a high correlation consistently exists between the topographic indices and the volume of eroded soil. The resulting relationships are therefore useful to assess soil losses from gully erosion, to identify the most susceptible watersheds within large areas, and to compare the susceptibility to gully erosion among different catchments. This information is also important in studying the response of natural drainage network systems to different rainfall inputs. Copyright © 2005 John Wiley & Sons, Ltd.     

Trace elements in streambed sediments of small subtropical streams on O‘ahu, Hawai‘i: Results from the USGS NAWQA program

Data are presented for trace element concentrations determined in the <63 μm fraction of streambed sediment samples collected at 24 sites on the island of O‘ahu, Hawai‘i. Sampling sites were classified as urban, agricultural, mixed (urban/agricultural), or forested based on their dominant land use, although the mixed land use at selected sampling sites consisted of either urban and agricultural or forested and agricultural land uses. Forest dominated sites were used as reference sites for calculating enrichment factors.Trace element concentrations were compared to concentrations from studies conducted in the conterminous United States using identical methods and to aquatic-life guidelines provided by the Canadian Council of Ministers of the Environment. A variety of elements including Pb, Cr, Cu and Zn exceeded the aquatic-life guidelines in selected samples. All of the Cr and Zn values and 16 of 24 Cu values exceeded their respective guidelines. The potential toxicity of elements exceeding guidelines, however, should be considered in the context of strong enrichments of selected trace elements attributable to source rocks in Hawai‘i, as well as in the context of the abundance of fine-grained sediment in the streambed of O‘ahu streams.Statistical methods including cluster analysis, Kruskal–Wallis non-parametric test, correlation analysis, and principal component analysis (PCA) were used to evaluate differences and elucidate relationships between trace elements and sites. Overall, trace element distributions and abundances can be correlated to three principal sources of elements. These include basaltic rocks of the volcanic edifice (Fe, Al, Ni, Co, Cr, V and Cu), carbonate/seawater derived elements (Mg, Ca, Na and Sr), and elements enriched owing to anthropogenic activity (P, Sn, Cd, Sn, Ba and Pb). Anthropogenic enrichment gradients were observed for Ba, Cd, Pb, Sn and Zn in the four streams in which sediments were collected upstream and downstream.The findings of this study are generally similar to but differ slightly from previous work on sediments and suspended particulate matter in streams, from two urban watersheds of O‘ahu, Hawai‘i. Inter-element associations in the latter were often stronger and indicated a mixture of anthropogenic, agricultural and basaltic sources of trace elements. Some elements fell into different statistical categories in the two studies, owing in part to differences in study design and the hydrogeological constraints on the respective study areas.     

Petrogenesis of the Eocene and Mio–Pliocene alkaline basaltic magmatism in Meseta Chile Chico, southern Patagonia, Chile: Evidence for the participation of two slab windows

The Meseta Chile Chico (MCC, 46.4°S) is the westernmost exposure of Eocene (lower basaltic sequence, LBS; 55–40 Ma, K–Ar ages) and Mio–Pliocene (upper basaltic sequence, UBS; 16–4 Ma, K–Ar ages) flood basalt volcanism in Patagonia. The MCC is located south of the Lago General Carrera-Buenos Aires (LGCBA), southeast from the present day Chile Triple Junction (CTJ), east of the actual volcanic gap between Southern South Volcanic Zone and Austral Volcanic Zone (SSVZ and AVZ, respectively) and just above the inferred location of the South Chile Ridge segment subducted at 6 Ma (SCR-1). Erupted products consist of mainly ne-normative olivine basalt with minor hy-normative tholeiites basalt, trachybasalt and basanite. MCC lavas are alkaline (42.7–53.1 wt.% SiO₂, 3–8 wt.% Na₂O+K₂O) and relatively primitive (Ni: 133–360 ppm, Cr: 161–193 ppm, Co: 35–72 ppm, 4–16.5 MgO wt.%). They have a marked OIB-like signature, as shown by their isotopic compositions (⁸⁷Sr/⁸⁶Sr_o=0.70311–0.70414 and εNd=+4.7–+5.1) and their incompatible trace elements ratios (Ba/La=10–20, La/Nb=0.46–1.09, Ce/Pb=15.52–27.5, Sr/La<25), reflecting deep mantle origin. UBS-primitive lavas have characteristics similar to those of the Eocene LBS basalts, while UBS-intermediate lavas show geochemical imprints (La/Nb>1, Sr/La>25, low Ce/Pb, Nb/U) compatible with contamination by arc/slab-derived and/or crustal components. We propose that the genesis and extrusion of magmas is related to the opening of two slab windows due to the subduction of two active ridge segments beneath Patagonia during Eocene and Mio–Pliocene.     

Flood Forecasting and Warning at the River Basin and at the European Scale

Application of recent advances in numerical weather prediction (NWP) has the potential of allowing delivery of flood warning to extend well beyond the typical lead times of operational flood warning at the river basin scale. A prototype system, a European Flood Forecasting System (EFFS) developed to deliver such pre-warnings, aiming at providing a pre-warning at lead times of between 5 and 10 days is described. Considerable uncertainty in the weather forecast at these lead times, however, means that resulting forecasts must be treated probabilistically, and although probabilistic forecasts may be easy to disseminate, these are difficult to understand. This paper explores the structure of operational flood warning, and shows that integration in the flood warning process is required if the pre-warning is to fulfil its potential. A simple method of summarising the information in the pre-warning is presented, and the system in hindcast mode is shown to give clear indication of an upcoming major event in the Rhine basin up to 10 days before the actual event. Finally recommendations on the use of data assimilation to embed the EFFS system within an operational environment are given.     

Mechanisms of galena dissolution in oxygen-saturated solutions: Evaluation of pH effect on apparent activation energies and mineral-water interface

This work describes a laboratory investigation of processes ruling the dissolution of galena (PbS) under conditions that mimic oxidising Earth surface environments. Freshly cleaved (001) galena surface was partially dissolved in solutions at different pH (HCl, pH between 1.2 and 5.8) and temperature (298 K) levels for several weeks in a flow-through reactor. Analysis of the galena surface after exposure to oxygen-saturated solutions was performed by XPS. The estimated thickness of surface layer formed after interaction for four weeks with solution at pH 5.8 was ∼0.5 nm. After the same time of interaction with solution at pH 1, the surface layer was at least 9 nm thick. Stationary dissolution rates were measured at different pH (between 1 and 5.8) and temperatures (298, 323, 348 K). Reaction order with respect to hydrogen ion averages 0.6 and slightly decreases with temperature. Dissolution rates, plotted vs. the reciprocal values of temperature, follow Arrhenius behaviour. Activation energies show a sharply discontinuous variation with pH. They are 13.5 ± 2 kJmol⁻¹ at pH = 1.2 and 2.87, whereas at pH of 4.08, 4.7, and 5.8, they show, respectively, values of 48.8 ± 3.5, 45 ± 4, and 51 ± 4 kJmol⁻¹. The apparent activation energy was also investigated by starting the experiment from pH 5.8 and then decreasing to pH 1.2. In this case, the apparent activation energies were 44 ± 4 kJmol⁻¹ and 21 ± 4 kJmol⁻¹, respectively.Apparent activation energies indicate a diffusion-controlled kinetic regime for pH <3, and a mixture of surface and diffusion control for pH between ∼4 and 5.8. A strong effect of solution pH on the mineral-water interface is revealed also by the observed pH dependence of surface-layer thickness. On the basis of the high-resolution XPS signals, the dependence of activation energies on solution pH should reflect a change of structure, and also chemical composition, of the mineral-water interface.