Evolution of the groundwater system under the impacts of human activities in middle reaches of Heihe River Basin (Northwest China) from 1985 to 2013

Investigation of the evolution of the groundwater system and its mechanisms is critical to the sustainable management of water in river basins. Temporal and spatial distributions and characteristics of groundwater have undergone a tremendous change with the intensity of human activities in the middle reaches of the Heihe River Basin (HRB), the second largest arid inland river basin in northwestern China. Based on groundwater observation data, hydrogeological data, meteorological data and irrigation statistical data, combined with geostatistical analyses and groundwater storage estimation, the basin-scaled evolution of the groundwater levels and storage (from 1985 to 2013) were investigated. The results showed that the unbalanced allocation of water sources and expanded cropland by policy-based human activities resulted in the over-abstraction of groundwater, which induced a general decrease in the water table and groundwater storage. The groundwater level has generally fallen from 4.92 to 11.49 m from 1985 to 2013, especially in the upper and middle parts of the alluvial fan (zone I), and reached a maximum depth of 17.41 m. The total groundwater storage decreased by 177.52?×?10⁸ m³; zone I accounted for about 94.7 % of the total decrease. The groundwater balance was disrupted and the groundwater system was in a severe negative balance; it was noted that the groundwater/surface-water interaction was also deeply affected. It is essential to develop a rational plan for integration and management of surface water and groundwater resources in the HRB.     

YS-80-122海洋低温碱性蛋白酶的性质

碱性蛋白酶是一种最重要的工业用酶,广泛应用于洗涤、食品、皮革和丝绸行业.海洋低温碱性蛋白酶是一种应用我国海洋嗜极微生物黄海黄杆菌(YS-80-122)代谢产物并通过现代生物工程手段开发出的一类新型酶.通过6000转/分离心(4℃),收集(30%-65%)硫酸铵沉淀,透析后等电聚焦制备分离(12W),并经凝胶S-200过滤,获得纯品经SDS- PAGE 聚丙烯酰胺凝胶和C8 HPLC 图谱已达到电泳纯.其分子量为49,320Dal,等电点为8.5.建立酶活-温度-pH 方程与模型( r2＞0.9),可求出其最适温度为30℃,最适pH为9.5,低温(T≤30℃)和低 pH(pH≤8)对保持其稳定性有利.经试验该酶与大多数金属离子和增稠剂及表面活性剂适应性良好.Pb2 、 Ag 、Cu2 对其有抑制作用,EDTA对其有强烈抑制作用.该酶性质与以往发现碱性蛋白酶性质不同,属于一种新型海洋酶.     

海洋硫酸多糖916氧化降解条件的正交实验法优化

以分子量为考查指标,采用正交实验法研究了海洋硫酸多糖916的氧化降解最佳条件。考察了H2O2浓度、原料用量和反应时间对降解后分子量的影响。结果表明,最佳降解条件为体系中H2O2浓度为3%,原料用量为2%,反应时间为3h。该法简单易行,操作简便,所用试剂廉价易得,是一种简单有效的降解方法。     

栉孔扇贝(Chlamys farreri)中抗氧化肽的分离纯化及性质研究

以栉孔扇贝内脏团为原料,对其中抗氧化肽的制备、纯化及性质进行了研究。首先采用硫酸铵沉淀、DEAE-Sephadex A-50阴离子交换层析的方法,进行了扇贝提取蛋白的制备,其次采用海洋蛋白酶YS-80水解、SephadexG-25凝胶层析的方法,进行扇贝抗氧化肽的制备,获得多肽粗品(海洋肽,PCF),并进一步采用CM Sepharose阳离子交换层析和反相高效液相色谱的方法,对扇贝抗氧化肽进行了纯化,结果得到组分PCF-3A,反相高效液相显示为单一峰。采用茚三酮反应、Sephadex G-15凝胶层析和AccQ.Tag氨基酸分析柱,进行了PCF-3A的理化性质研究。结果表明,茚三酮反应呈阳性;分子量约为794D;由7种氨基酸组成,分别为天冬氨酸、甘氨酸、苏氨酸、丙氨酸、缬氨酸、赖氨酸和脯氨酸。采用邻苯三酚自氧化体系和Fenton反应体系对PCF-3A的抗氧化活性进行了研究,发现该肽可有效清除羟自由基和超氧阴离子,半抑制浓度(IC50)分别为0.39mg/ml和2.85mg/ml,具有明显的抗氧化、抗衰老作用。     

1556年陕西华县大地震形变遗迹及华山山前断裂古地震研究

华山山前断裂带晚第四纪以来具有明显的新活动,沿断裂带及其两侧分布有最新断层崖,基岩裂缝、黄土裂缝、山体崩(滑)塌体等众多的地震形变和破坏遗迹,华山山前断裂带应是1556年华县8级地震的发震断层。 从本文提供的一个古地震剖面分析,华山山前断裂带全新世以来可能发生过四次大地震,其重复间隔约2000—2500年     

Effects of Coal Gangue Content on Water Movement and Solute Transport in a China Loess Plateau Soil

The mining industry has grown strongly in China in recent decades, resulting in large amounts of coal gangues, which cause water and soil pollution, soil erosion, and various other environmental problems. They are often used in reclamation projects in attempts to restore land damaged by mining, hence they are frequently present (in widely varying proportions) in the topsoil in areas around mines. Their presence can strongly affect key soil variables, including its bulk density, structure, water retention, water movement, and solute transport rates. In the study presented here, the effects of gangue contents on infiltration, saturated hydraulic conductivity, and solute transport parameters of a Chinese Loess plateau soil were examined. The results show that infiltration rates and saturated hydraulic conductivity decreased with increasing gangue content. The Peck–Watson equation modeled these relationships well, but Bouwer–Rice equations provided poorer matches with the acquired data. Cumulative infiltration over time was described well by both the Philip equation and Kostiakov equation. Both the simplified convection–dispersion equation and a two‐region model described the solute transport processes well. In addition, the dispersion increased, while both the Peclet number and mobile water fraction decreased, with increases in gangue contents.     

丽江干河坝冰-岩碎屑流地貌、沉积特征与成因机制分析

2004年3月12日,云南省丽江市玉龙雪山南坡发生了较大规模的冰-岩碎屑流型高速远程滑坡。位于斜坡顶部（高程为4 337~5 350 m）的岩体和冰川块体沿着高陡岩壁向下滑动,在峡谷地形控制下于干河坝内形成体积约11.2×10⁶ m³的滑坡堆积体。本文通过遥感影像分析和现场调查,对干河坝冰-岩碎屑流的地貌与堆积特征进行了详细研究,初步阐释了干河坝冰-岩碎屑流发生的成因机制和运动过程。研究结果表明,节理裂隙发育、源区冻融作用加剧和历史地震效应是此次地震的诱发因素。地形的坡度变化特征、滑体表面“乘船石”结构及内部岩屑的定向排列表明滑坡的运动过程可分为碰撞破碎阶段和扩散堆积阶段。滑坡堆积区广泛分布的“冰川乳坑”和冰水沉积物暗示堆积体底部松散沉积物减阻或是干河坝冰-岩碎屑流具有远程效应的有利因素。深入理解干河坝冰-岩碎屑流的地貌特征及运动学过程,对揭示高速远程滑坡的超强运动机理具有重要的理论意义,同时对我国西部高寒山区大型滑坡灾害的预测预警亦具有现实意义。     

全新世亚洲季风百年-千年尺度变化的模拟研究进展

气候重建工作的深入开展极大地促进了全新世亚洲季风变化的研究,然而当前重建结果对亚洲季风的演变特征和机理存在很大争议,开展古气候模拟对理解全新世亚洲季风演变的时空特征和成因机制具有重要意义。为此,本文主要从气候模式模拟的角度回顾全新世亚洲季风百年-千年尺度变化的模拟研究工作,并将从外强迫和气候系统内部变率这两个角度对机制进行探讨。主要有以下进展:全新世瞬变模拟试验结果反映早全新世以来亚洲季风降水呈下降趋势,这主要受到地球轨道参数的影响,并通过改变海陆热力差异和半球间温度梯度来影响亚洲季风降水。在百年尺度弱季风事件上,模拟的8.2 ka BP时期的亚洲季风弱事件主要是由冰川融水触发,引起大西洋经向翻转环流AMOC减弱并通过大气遥相关导致季风降水减少;而4.2 ka BP时期模式模拟的亚洲弱季风事件主要是受内部变率所主导而并非外强迫因子影响。亚洲季风百年尺度变化的模拟研究主要集中在过去2 000年时段,中世纪气候异常期季风明显增强,而在小冰期逐渐减弱,太阳辐射和火山活动是影响其变化的主导因子,它们通过影响海陆热力差异、印—太海温变化来影响季风变化。     

基于HEC-RAS及GIS的川西叠溪古滑坡堰塞湖溃决洪水重建

青藏高原东南缘岷江上游地区地质环境条件十分复杂,滑坡堵江灾害及堰塞湖溃决事件频发,重建其灾害演化过程对于地区性防灾减灾和风险控制具有重要指导意义。以川西岷江上游叠溪古滑坡堰塞湖为研究对象,首先利用高精度DEM和ArcGIS软件重建了叠溪古堰塞湖的原始规模,其原始最大湖水面积为1.1×10⁷ m²,相应的湖容量为2.9×10⁹ m³;然后采用经验公式法和HEC-RAS一维水力学模型重建叠溪古堰塞湖溃决洪水的水力学特征。计算结果表明,HEC-RAS模拟的最大溃决洪水洪峰流量为73 060 m³/s,与经验公式法计算结果(74 500~76 800 m³/s,平均值76 000 m³/s)非常接近,误差小于5%。对应的最大洪水深度和流速分别为70.1 m和16.78 m/s,模拟河段的洪水淹没范围约为6.08 km²。综合误差分析推测的溃决洪峰流量误差范围为69 000~81 000 m³/s。叠溪古滑坡堰塞湖溃决洪水在世界范围内是十分罕见的,其最直接的影响是在下游数公里范围的河谷内形成大量带状或台阶状的溃坝堆积体和巨砾石堆积“阶地”,且这种影响仍延续至今,这与前人关于高能洪水水文特征和沉积特征的研究认识高度一致,证明本研究成果是非常可靠的。此外,本研究还表明,HEC-RAS一维水力模型可用于高山峡谷地区古滑坡堰塞湖溃决洪水重建研究,可为青藏高原东南缘岷江上游古环境重建和地貌演化提供参考。