A stochastic estimation of sediment production in an urban catchment using the USLE model

The goals of this study were to map the spatial distribution of sediment production and to estimate the probability of this production at the waterline based on a high potential of silting. The RUSLE-GIS model and Monte Carlo simulation were used. A sensitivity analysis of stochastic factors was performed by calculating the simple correlation coefficient. This procedure was applied to the Estrada Nova catchment, located in the city of Belém, northern Brazil, which has been subject to channel improvements and the construction of a detention basin. The results indicate that, following the urbanization and drainage improvements, there was a reduction in the annual sediment production probability, which is consistent with the dynamics in land use. The erodibility was the most sensitive factor in the sedimentation estimates. The methodology was considered an alternative to estimate sediment production in an urban catchment.     

Partition of arsenic in soils sediments and the origin of naturally elevated concentrations in groundwater of the southern pampa region (Argentina)

Excessive arsenic concentrations above the Argentinean and WHO guidelines for drinking water (10 μg L⁻¹) affects shallow aquifers of the southern Pampean Plain (Argentina) hosted in the Pampean and the Post Pampean formations (loess and reworked loess; Plio-Pleistocene–Holocene). Health problems related to high As concentrations in drinking waters are known as Endemic Regional Chronic Hydroarsenicism. Hydrochemistry of shallow groundwaters and soil geochemistry were investigated aiming to (1) understand the partition of As in the solid phase and its relationship with unacceptable As concentrations in waters, (2) identify the provision source of As to groundwaters. Only 5% of the samples had As concentrations <10 μg L⁻¹; in 27% As concentrations ranged from 10 to 50 μg L⁻¹ and in 58% it reached 60–500 μg L⁻¹. The coarse fraction (50–2,000 μm) hosts about 27% of the total As in the solid phase, being positively correlated to Ba (p < 0.01; r ² = 0.93). About 70% is included in the <2 μm fraction and had positive correlations of As–Fe (p < 0.05; r ² = 0.85) and As–Cr (p < 0.05; r ² = 0.68). Soils and sediment sand fractions of vadose zones are the primary sources of As in shallow groundwater while adsorption–desorption processes, codisolution–coprecipitation, and evaporation during the dry seasons raise As concentrations in waters exceeding the guideline value for drinking water.     

An overview of laboratory apparatuses to measure seismic attenuation in reservoir rocks

Intrinsic wave attenuation at seismic frequencies is strongly dependent on rock permeability, fluid properties, and saturation. However, in order to use attenuation as an attribute to extract information on rock/fluid properties from seismic data, experimental studies on attenuation are necessary for a better understanding of physical mechanisms that are dominant at those frequencies. An appropriate laboratory methodology to measure attenuation at seismic frequencies is the forced oscillation method, but technical challenges kept this technique from being widely used. There is a need for the standardization of devices employing this method, and a comparison of existing setups is a step towards it. Here we summarize the apparatuses based on the forced oscillation method that were built in the last 30 years and were used to measure frequency‐dependent attenuation in fluid‐saturated and/or dry reservoir rocks under small strains (10^?8–10^?5). We list and discuss important technical aspects to be taken into account when working with these devices or in the course of designing a new one. We also present a summary of the attenuation measurements in reservoir rock samples performed with these apparatuses so far.     

Hydrography and frontogenesis in a glacial fjord off the Strait of Magellan

Current velocity and hydrographic profiles obtained for the first time in a Chilean glacial fjord were combined with under-way surface temperature and salinity measurements to describe the formation of tidal intrusion fronts and plume-like fronts. These fronts formed within several hundred meters from each other in the vicinity of a shallow sill, maximum depth of approximately 3 m, in a glacial fjord off the Strait of Magellan in the Chilean Patagonia. Measurements were obtained in mid-December of 2003 and 2004, during late austral spring, under active glacier melting and calving. The glacial fjord is approximately 18 km long from the face of the glacier to the connection with the Strait of Magellan and typically less than 1 km wide throughout the system. Between the glacier face and the 3-m sill, depths are typically less than 100 m, and seaward of the sill, depths increase to more than 200 m. Velocity and salinity data obtained during flood periods revealed that water with oceanic salinity was aspirated to near-surface levels from depths of approximately 30 m as flood flows accelerated from approximately 10 cm s⁻¹, seaward of the sill, to approximately 60 cm s⁻¹ at the sill crest. The upwelled water was then slightly diluted by mixing at the sill crest before plunging down to the basin between the glacier and the sill. The plunging of salty water over the sill created dramatic tidal intrusion fronts only a few tens of meters from the sill crest and pumping of salt with every flood period. During ebb periods, the low salinity waters derived from the glacier and a small river near the glacier converged at the sill crest. After some mixing, the buoyant waters were released within a thin layer (∼3 m deep) lead by a plume-like front that remained coherent for a few hundred meters seaward of the sill. The main findings of this study were that tidal intrusion and plume fronts were observed within 2 km from each other, and that tidal pumping was the predominant mechanism for salt fluxes into the system.     

Salt crystallization in pores: quantification and estimation of damage

The objective of this study is to understand and predict the alteration of porous rock by crystallization of salts. Samples of different rocks have been tested according to the EN 12370 standard test. Two parameters are proposed to evaluate the alteration of a rock during these tests. The alteration index AI represents the cycle in which the first damages occur. The alteration velocity AV represents the alteration rate at the end of the experiment, when the decay has become regular. These parameters can be estimated with the help of a microstructural study of the rocks. The most relevant intrinsic parameters of the stones for this estimation are capillary coefficient, evaporation coefficient, tensile strength and P-waves velocity. An evaluation of the alteration pattern is also proposed depending on the eventual heterogeneities and anisotropies of the rocks. The influence of the dimension and shape of the samples is also discussed.     

Hydrogeological characterization of carbonated Jurassic aquifers in the Gijón-Villaviciosa basin (Asturias,N Spain) by means of geochemical and isotopic techniques

Chemical and isotopic analyses of groundwater from the carbonated Jurassic aquifers in the Gijón-Villaviciosa basin (Asturias, northern Spain) were carried out. Nine springs were sampled to determine major cations and anions, as well as the stable isotopes of the water molecule (δ²H and δ¹⁸O) and sulphate (δ³⁴S) values. Also, δ³⁴S values from gypsum coming both from Triassic rocks and bottom of Jurassic sequence were also determined. The results obtained were used to classify the waters with a genetic criteria in three groups: (1) waters with a high gypsum influence, with sulphate coming from Jurassic gypsum, (2) waters without gypsum influence, where sulphate source could be atmospheric deposition from industrial processes and marine aerosol, and (3) waters with some gypsum influence, in which sulphate origin could be a combination of different sources. In relation to recharge, δ²H and δ¹⁸O values were close to those of Global Meteoric Water Line and fit a local line that suggests a meteoric origin. The estimated elevations for spring recharge are in agreement with those obtained from hydrogeological maps.