Multiproxy late Holocene peat records from Ireland: towards a regional palaeoclimate curve

Two new peat‐based climate records from Ireland covering the late Holocene are presented. The sequences are dated by a strong chronological framework formed by AMS radiocarbon dates and SCPs. Three proxy indicators (testate amoebae, macrofossils and humification) have been determined allowing the limitations and strengths of each to be identified and utilised to provide a bog surface wetness (BSW) record for both sites. Age–depth models take into account the potential for accumulation rates to vary with bog vegetation. The records from each site have been used to derive a combined BSW record that displays changes to a wetter/cooler climate from ca. AD 30 (1920 BP), ca. AD 310 (1640 BP), ca. AD 805 (1145 BP), ca. AD 1040 (910 BP) and ca. AD 1300 (650 BP). Changes follow closely those identified in a northern Britain composite BSW record and largely correspond with lake‐level data in central France suggesting the main changes in water balance were coherent over a large region. Correspondence with increases in IRD and slower Iceland‐Scotland Overflow Water (ISOW) suggests that these changes were related to oceanic forcing influencing the track of dominant westerly air flow over Ireland. Copyright © 2007 John Wiley & Sons, Ltd.     

Detection and classification of surface roughness in an Arctic marginal sea ice zone

Sea ice dynamic and thermodynamic processes are important and highly variable elements of the marginal ice zone (MIZ). This study examines the detection and classification of statistically separable sea ice classes in the MIZ through a range of temporal and spatial scales. A helicopter‐based laser system was used to obtain large‐scale and a ship‐based laser profiler to identify small‐scale roughness types, respectively. The analysis of variance of surface height data from helicopter‐ and ship‐based laser systems, active microwave (AMW) C‐band backscattering data and passive microwave (PMW) (37 and 89 GHz) brightness temperature data reveal different classes that statistically differ from one another. We found significant statistical difference in variances in AMW data with six classes that differ in VV polarization, three classes in VH polarization, and five classes in HH polarization in the MIZ (e.g. snow‐covered first‐year ice, ice rubble, pancake ice, frost flowers, melt pond, flooded ice, and ice edge) of southeastern Beaufort Sea. The PMW emission was not as effective at discrimination, yielding only one statistically separable class. The results can potentially be extended to satellite‐based investigations of the MIZ at regional scales. Copyright © 2012 John Wiley & Sons, Ltd.     

Geodynamic context for the deposition of coarse‐grained deep‐water axial channel systems in the Patagonian Andes

We present field and seismic evidence for the existence of Coniacian–Campanian syntectonic angular unconformities within basal foreland basin sequences of the Austral or Magallanes Basin, with implications for the understanding of deformation and sedimentation in the southern Patagonian Andes. The studied sequences belong to the mainly turbiditic Upper Cretaceous Cerro Toro Formation that includes a world‐class example of conglomerate‐filled deep‐water channel bodies deposited in an axial foredeep depocentre. We present multiple evidence of syntectonic deposition showing that the present internal domain of the fold‐thrust belt was an active Coniacian–Campanian wedge‐top depozone where deposition of turbidites and conglomerate channels of Cerro Toro took place. Cretaceous synsedimentary deformation was dominated by positive inversion of Jurassic extensional structures that produced elongated axial submarine trenches separated by structural highs controlling the development and distribution of axial channels. The position of Coniacian‐Campanian unconformities indicates a ca. 50–80 km advance of the orogenic front throughout the internal domain, implying that Late Cretaceous deformation was more significant in terms of widening the orogenic wedge than all subsequent Andean deformation stages. This south Patagonian orogenic event can be related to compressional stresses generated by the combination of both the collision of the western margin of Rocas Verdes Basin during its closure, and Atlantic ridge push forces due to its accelerated opening, during a global‐scale plate reorganization event.     

A high-accuracy computed water line list

A computed list of  H₂¹⁶O  infrared transition frequencies and intensities is presented. The list, BT2, was produced using a discrete variable representation two-step approach for solving the rotation–vibration nuclear motions. It is the most complete water line list in existence, comprising over 500 million transitions (65 per cent more than any other list) and it is also the most accurate (over 90 per cent of all known experimental energy levels are within 0.3 cm⁻¹ of the BT2 values). Its accuracy has been confirmed by extensive testing against astronomical and laboratory data.
The line list has been used to identify individual water lines in a variety of objects including comets, sunspots, a brown dwarf and the nova-like object V838 Mon. Comparison of the observed intensities with those generated by BT2 enables water abundances and temperatures to be derived for these objects. The line list can also be used to provide an opacity for models of the atmospheres of M dwarf stars and assign previously unknown water lines in laboratory spectra.     

Hydrochemical dynamics of TOC and NO3 − contents as natural tracers of infiltration in karst aquifers

Analysis of Total Organic Carbon (TOC) and NO₃ ^? contents in the water at six springs in the province of Malaga (Southern Spain), sampled under different hydrologic conditions, revealed two different hydrochemical behaviour patterns for these natural tracers of infiltration. TOC content increased during every recharge period, following the rapid arrival of water infiltrating through the soil. On the other hand, NO₃ ^? content only rose during the first flood episodes (normally in autumn), and fell during the winter and spring ones. This difference is consequence of the distinctive biogeochemical kinetics of nitrogen with respect to organic carbon, both in the soil and within the aquifer. Unlike the mineralisation undergone by TOC from the surface to the spring, the NO₃ ^? ion remains in the aquifer almost unaffected, due to the oxidizing conditions prevailing within the karst medium, which do not allow its denitrification and favour its preservation within the saturated zone. In non-polluted aquifers, TOC and NO₃ ^? have a common origin in the soil and can be used to determine infiltration processes and the hydrogeological functioning of karst aquifers. Their different hydrochemical evolution provides information about mineralization and degradation processes of organic matter within karst aquifers, which can be used to validate the vulnerability to contamination in this type of medium.     

Using non-conservative tracers to characterise karstification processes in the Merinos-Colorado-Carrasco carbonate aquifer system (southern Spain)

The systematic sampling of the chemical composition of the groundwater from five karst springs (including an overflow spring) and one outflowing borehole have permitted to determine distinctive chemical changes in the waters that reflect the geochemical processes occurring in a carbonate aquifer system from southern Spain. The analysis of the dissolution parameters revealed that geochemical evolution of the karst waters basically depends on the availability of the minerals forming aquifer rocks and the residence time within the aquifers. In the three proposed scenarios in the aquifers, which include the preferential flow routines, the more important geochemical processes taking place during the groundwater flow from the recharge to the discharge zones are: CO₂ dissolution and exsolution (outgassing), calcite net dissolution, calcite and dolomite sequential dissolution, gypsum/anhydrite and halite dissolution, de-dolomitization and calcite precipitation. A detailed analysis of the hydrochemical data set, saturation indices of the minerals and partial pressure of CO₂ in the waters joined to the application of geochemical modelling methods allowed the elaboration of a hydrogeochemical model of the studied aquifers. The developed approach contributes to a better understanding of the karstification processes and the hydrogeological functioning of carbonate aquifers, the latter being a crucial aspect for the suitable management of the water resources.