Monazite U-Pb dating of staurolite grade metamorphism in pelitic schists

A study of the occurrence of and relations between rare-earth element (REE) minerals in pelitic schists indicates that monazite forms at or near the P and T of the staurolite isograd. Samples at staurolite grade from the Silurian Perry Mountain Formation in the Rumford quadrangle of Maine yield monazite in sufficient quantities to permit accurate dating of the metamorphic events forming the monazites. The bulk chemistry of the metapelites, as seen in the major element abundances and REE patterns, does not vary significantly across the study area. Thus the appearance and disappearance of REE phases is assumed to reflect changes in metamorphic grade. In a sample from the biotite zone, scanning electron microscope and microprobe studies show allanite and monazite intimately associated on a 10 m scale. The texture suggest that metastable detrital monazite breaks down, distributing its REE components to allanite. From samples below staurolite grade in which monazite is not present, our observations suggest that REEs are partitioned into allanite. At or near the staurolite isograd monazite forms as a metamorphic mineral, initiating its role as a geochronometer. Garnet-biotite geothermometry on samples at this grade from this and other studies places constraints on the minimum temperature necessary to form monazite: 525° C±25°C at 3.1±0.25 kbar. A total of 15 separates from nine schist samples ranging up to sillimanite grade have been dated. Each date is remarkably concordant, even though petrologic and textural studies by previous workers have shown that the rocks in the area have been affected by at least three metamorphic episodes. Calculations indicate insignificant Th disequilibrium in these monazites. The conditions associated with the metamorphic events suggest that monazite remains closed to lead loss provided that subsequent metamorphisms are at or below sillimanite grade. Two distinct metamorphic events are resolved, one at around 400 Ma and one at about 370 Ma. The latter was due to thermal effects of a nearby pluton that yields concordant monazite ages of 363 Ma. This work suggests that in addition to dating plutonism and high-grade metamorphism, monazite should be viewed as a reliable geochronometer for moderate metamorphism of pelitic schists.     

Monitoring and Modeling of Syringodium filiforme (Manatee Grass) in Southern Indian River Lagoon

Decreased salinity and submarine light associated with hurricanes of 2004?C2005 impacted seagrass habitats in the Florida coastal zone. A combination of salinities ??20 and light attenuation ??1.5?m^?1 resulting from the freshwater discharge in 2005 were among the drivers for a widespread decrease in the coverage and biomass of Syringodium filiforme (manatee grass) in 2006. These observations provided an opportunity to develop and apply a modeling framework to simulate responses of S. filiforme to variable water quality. The framework connects water column variables to field monitoring of seagrass abundance and salinity growth response experiments. The base model was calibrated with macrophyte abundance observed in southern Indian River Lagoon (IRL) from 2002 to 2007 and tested against shoot data from a different time (1997?C2002) and nearby location in the IRL. Model shoot biomass (gC?m^?2) was similar to field observations (r ²?=?0.70) while responding to monthly seasonal fluctuations in salinity and light throughout the 6-year simulations. Field and model results indicated that S. filiforme growth and survival were sensitive to, and increased with, rising salinity throughout 2007. This modeling study emphasizes that discharge, salinity, and submarine light are inter-dependent variables affecting South Florida seagrass habitats on seasonal to inter-annual time scales.     

Landscape response to tipping points in granite weathering: The case of stepped topography in the Southern Sierra Critical Zone Observatory

The dynamics of granitic landscapes are modulated by bimodal weathering, which produces patchy granular soils and expanses of bare rock ranging from meter-scale boulders to mountain-scale domes. We used terrain analysis and with cosmogenic nuclide measurements of erosion rates to quantitatively explore Wahrhaftig’s decades-old hypothesis for the development of “stepped topography” by differential weathering of bare and soil-mantled granite. According to Wahrhaftig’s hypothesis, bare granite weathers slower than soil-mantled granite; thus random erosional exposure of bare rock leads to an alternating sequence of steep, slowly weathering bedrock “steps” and gently sloped, but rapidly weathering, soil-mantled “treads.” Our investigation focused on the terrain surrounding the Southern Sierra Critical Zone Observatory (CZO), which is underlain by granitic bedrock and lies outside the limits of recent glaciation, in the heart of the stepped topography described by Wahrhaftig. Our digital terrain analysis confirms that steep steps often grade into gentle treads, consistent with Wahrhaftig’s hypothesis. However, we observe a mix-and-match of soil and bare rock on treads and steps, contrary to one of the hypothesis’ major underpinnings – that bare rock should be much more common on steps than on treads. Moreover, the data show that bare rock is not as common as expected at step tops; Wahrhaftig’s hypothesis dictates that step tops should act as slowly eroding base levels for the treads above them. The data indicate that, within each landscape class (i.e., the steps and treads), bare rock erodes more slowly than surrounding soil. This suggests that the coupling between soil production and denudation in granitic landscapes harbors a tipping point wherein erosion rates decrease when soils are stripped to bedrock. Although broadly consistent with the differential weathering invoked by Wahrhaftig, the data also show that steps are eroding faster than treads, undermining Wahrhaftig’s explanation for the origins of the steps. The revised interpretation proposed here is that the landscape evolves by back-wearing of steps in addition to differential erosion due to differences in weathering of bare and soil-mantled granite.     

Chemical characterization of fine particulate matter during peak PM10 episodes in Apulia (South Italy)

Some peak PM10 episodes, occurred during PM monitoring campaigns performed on October 2005 and February and June 2006 in Bari town, have been characterized. Moreover back trajectories of air masses and Principal Component Analyses were applied. Three of the peak PM10 episodes investigated were related to local emissions of primary pollutants during poor atmospheric dispersion conditions. The other two peak PM10 episodes considered are related with long range transport air masses toward Apulia region: in one case the chemical characterization and the back trajectories analysis indicate that high PM10 value detected is due to the Saharan dust advection in the Apulia region; in the other case air masses with different origin give rise to high PM10 value.Moreover PM10 daily mean concentrations, presented in this paper collected from January 2005 to August 2007 and obtained by automatic device in six stations of air quality monitoring networks in Bari territory, do not show a seasonal trend for PM10 concentrations, contrary to the PM10 trend shown in the towns of North Italy. This can be explained mostly considering that our region presents generally meteo-climatic conditions that favour pollutants dispersion.     

Phase equilibrium modelling of the amphibolite to granulite facies transition in metabasic rocks (Ivrea Zone,NW Italy)

The development of thermodynamic models for tonalitic melt and the updated clinopyroxene and amphibole models now allow the use of phase equilibrium modelling to estimate P–T conditions and melt production for anatectic mafic and intermediate rock types at high‐T conditions. The Permian mid‐lower crustal section of the Ivrea Zone preserves a metamorphic field gradient from mid amphibolite facies to granulite facies, and thus records the onset of partial melting in metabasic rocks. Interlayered metabasic and metapelitic rocks allows the direct comparison of P–T estimates and partial melting between both rock types with the same metamorphic evolution. Pseudosections for metabasic compositions calculated in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (NCKFMASHTO) system are presented and compared with those of metapelitic rocks calculated with consistent end‐member data and a–x models. The results presented in this study show that P–T conditions obtained by phase equilibria modelling of both metabasic and metapelitic rocks give consistent results within uncertainties, allowing integration of results obtained for both rock types. In combination, the calculations for both metabasic and metapelitic rocks allows an updated and more precisely constrained metamorphic field gradient for Val Strona di Omegna to be defined. The new field gradient has a slightly lower dP/dT which is in better agreement with the onset of crustal thinning of the Adriatic margin during the Permian inferred in recent studies.     

Towards urbanisation of the non-hydrostatic numerical weather prediction model Lokalmodell (LM)

Numerical weather prediction models are increasingly employed for providing meteorological data for urban air quality applications. Model resolution, physiographic parameters and surface-layer parameterisations need to be adapted to the requirements of the urban boundary layer. The Lokalmodell of the German Weather Service was triple-nested down to a horizontal grid resolution of 1.1 km, urbanised physiographic parameters were implemented, and an additional anthropogenic heat source was introduced. Results of a sensitivity study for a spring dust episode in Helsinki show a clear urbanisation effect of these measures on temperature, humidity and the partitioning of surface fluxes, leading to an increased Bowen ratio and heat storage and an urban heat island effect.     

The geology of kimberlite pipes of the Ekati property, Northwest Territories, Canada

This paper reviews key characteristics of kimberlites on the Ekati property, NWT, Canada. To date 150 kimberlites have been discovered on the property, five of which are mined for diamonds. The kimberlites intrude Archean basement of the central Slave craton. Numerous Proterozoic diabase dykes intrude the area. The Precambrian rocks are overlain by Quaternary glacial sediments. No Phanerozoic rocks are present. However, mudstone xenoliths and disaggregated sediment within the kimberlites indicate that late-Cretaceous and Tertiary cover (likely <200 m) was present at the time of emplacement. The Ekati kimberlites range in age from 45 to 75 Ma. They are mostly small pipe-like bodies (surface area mostly <3 ha but up to 20 ha) that typically extend to projected depths of 400–600 m below current surface. Pipe morphologies are strongly controlled by joints and faults. The kimberlites consist primarily of variably bedded volcaniclastic kimberlite (VK). This is dominated by juvenile constituents (olivine and lesser kimberlitic ash) and variable amounts of exotic sediment (primarily mud), with minor amounts of xenolithic wall-rock material (generally <5%). Kimberlite types include: mud-rich resedimented VK (mRVK); olivine-rich VK (oVK); sedimentary kimberlite; primary VK (PVK); tuffisitic kimberlite (TK) and magmatic kimberlite (MK). The presence and arrangement of these rock types varies widely. The majority of bodies are dominated by oVK and mRVK, but PVK is prominent in the lower portions of certain kimberlites. TK is rare. MK occurs primarily as precursor dykes but, in a few cases, forms pipe-filling intrusions. The internal geology of the kimberlites ranges from simple single-phase pipes (RVK or MK), to complex bodies with multiple, distinct units of VK. The latter include pipes infilled with steep, irregular VK blocks/wedges and at least one case in which the pipe is occupied by well-defined sub-horizontal VK phases, including a unique, 100-m-thick graded sequence. The whole-rock compositions of VK samples suggest significant loss of kimberlitic fines during eruption followed by variable dilution by surface sediment and concurrent incorporation of kimberlitic ash. Diamond distribution within the kimberlites reflects the amount and nature of mantle material sampled by individual kimberlite phases, but is modified considerably by eruption and depositional processes. The characteristics of the Ekati kimberlites are consistent with a two-stage emplacement process: (1) explosive eruption/s causing vent clearing followed by formation of a significant tephra rim/cone of highly fragmented, olivine-enriched juvenile material with varying amounts of kimberlitic ash and surface sediments (predominantly mud); and (2) infilling of the vent by direct deposition from the eruption column and/or resedimentation of crater rim materials. The presence of less fragmented, juvenile-rich PVK in the lower portions of certain pipes and the intrusion of large volumes of MK to shallow levels in some bodies suggest emplacement of relatively volatile-depleted, less explosive kimberlite in the later stages of pipe formation and/or filling. Explosive devolatilisation of CO₂-rich kimberlite magma is interpreted to have been the dominant eruption mechanism, but phreatomagmatism is thought to have played a role and, in certain cases, may have been dominant.     

Lead isotopic compositions of South Sandwich Island volcanic rocks and their bearing on magmagenesis in intra-oceanic island arcs

Pb isotope ratios have been measured in 12 volcanic rocks from the South Sandwich Islands. The ranges are ${}^{206}\text{Pb}{}^{204}\text{Pb}\text{= 18.51–18.66;}{}^{207}\text{Pb}{}^{204}\text{Pb}\text{= 15.55–15.64;}{}^{208}\text{Pb}{}^{204}\text{Pb}\text{= 38.42–38.64}$. In ${}^{207}\text{Pb}{}^{204}\text{Pb}\text{-}{}^{206}\text{Pb}{}^{204}\text{Pb}$ and ${}^{208}\text{Pb}{}^{204}\text{Pb}\text{-}{}^{206}\text{Pb}{}^{204}\text{Pb}$ correlation diagrams, the South Sandwich data plot distinctly above the fields for ocean ridge basalts, and yield trends showing apparent mixing with a sedimentary end member similar to South Atlantic pelagic sediments as reported by Chow and Patterson (1962) and this study. Armstrong and Cooper (1971) have likewise shown that volcanics from the Lesser Antilles show mixing trends with North Atlantic sediments in Pb isotope correlation diagrams. The North Atlantic sediments have distinctly higher ${}^{206}\text{Pb}{}^{204}\text{Pb}$ and ${}^{208}\text{Pb}{}^{204}\text{Pb}$ ratios compared to the South Atlantic sediments. The parallel relationships between sediments and volcanic island arc rocks of the North and South Atlantic provide strong evidence for a component of Pb from subducted sediments in the lavas of the west Atlantic basin. In contrast to these data, lavas from the Mariana Arc in the western Pacific show little or no component of Pb from pelagic sediments. The reason for the different behaviors in the two settings is speculative.