Raman microspectrometry, FT-IR and inclusion characteristics of gem garnets from Tanzania and Madagascar

Chemical composition, Raman microspectrometry, and Fourier transform infrared (FT-1R) and SEM-CL (Cathodluminescence) analyses are carried out for Tanzania and Madagascar garnets for locality identification. Inclusion study was sustained after electron probe microanalysis (EPMA). Needle-like illmenites, apatites and zircons were the most common solid inclusions in Tanzania garnets. Madagascar garnets revealed rutile needles and apatites were also observed, but differences in size, shape and distribution patterns were noticed compared to Tanzania garnets. Tanzania garnets exhibited all types of observable fluid inclusions such as ““ fingerprint““ pattern, called Type Ⅰ-A, liquid-only (L) single phase fluid inclusion, called Type Ⅰ-B and Type Ⅱ-A ( L S), Type Ⅱ-B ( L V) and Type Ⅲ-A (L Sylvite even if all examined garnets from three localities retained ““fingerprint““ features, so called, partially healed fractures, in common. Chemical composition, Raman microspectrometry and Fourier transform infrared (FT-IR) analysis taken turned out to be useful methods for the purpose of this study. Using consequences of SEM-CL and inclusion study, accordingly, the locality identification of gem-quality garnets is capable of being available in further application for other kinds of gemstones.     

<Emphasis Type="Italic">Cochlodinium polykrikoides</Emphasis> red tide detection in the South Sea of Korea using spectral classification of MODIS data

To distinguish true red tide water (particularly Cochlodinium polykrikoides blooms) from non-red tide water (false satellite high chlorophyll water) in the South Sea of Korea, we developed a systematic classification method using spectral information from MODIS level products and applied it to five different harmful algal bloom events. Red tide and nonred tide waters were classified based on four different criteria. The first step revealed that the radiance peaks of potential red tide water occurred at 555 and 678 nm. The second step separated optically different waters that were influenced by relatively low and high contributions of colored dissolved organic matter (CDOM) (including detritus) to chlorophyll. The third and fourth steps discriminated red tide water from non-red tide water based on the blue-to-green ratio in areas with lower and higher contributions of CDOM to chlorophyll, respectively. After applying the red tide classification (using the four criteria), the spectral response of the red tide water, which is influenced by pigment concentration, showed different slopes for the blue and green bands (lower slope at blue bands and higher slope at green bands). The opposite result was found for non-red tide water, due to decreasing phytoplankton absorption and increasing detritus/CDOM absorption at blue bands. The results were well matched with the discoloration of water (blue to dark red/brown) and delineated the areal coverage of C. polykrikoides blooms, revealing the nature of spatial and temporal variations in red tides. This simple spectral classification method led to increase user accuracy for C. polykrikoides and non-red tide blooms (>46% and >97%) and provided a more reliable and robust identification of red tides over a wide range of oceanic environments than was possible using chlorophyll a concentration, chlorophyll anomaly, fluorescence analysis, or proposed red tide detection algorithms.     

Analysis of changes in extreme temperatures using quantile regression

This study examines the changes in regional extreme temperature in South Korea using quantile regression, which is applied to analyze trends, not only in the mean but in all parts of the data distribution. The results show considerable diversity across space and quantile level in South Korea. In winter, the slopes in lower quantiles generally have a more distinct increase trend compared to the upper quantiles. The time series for daily minimum temperature during the winter season only shows a significant increasing trend in the lower quantile. In case of summer, most sites show an increase trend in both lower and upper quantiles for daily minimum temperature, while there are a number of sites with a decrease trend for daily maximum temperature. It was also found that the increase trend of extreme low temperature in large urban areas (0.80°C decade^?1) is much larger than in rural areas (0.54°C decade^?1) due to the effects of urbanization.     

湖北铜绿山矿床石英闪长岩的矿物学及Sr-Nd-Pb同位素特征

铜绿山是长江中下游鄂东南矿集区最重要的、大型夕卡岩型Cu-Fe(Au)矿床。本文对该矿区中与成矿密切的石英闪长岩进行了详细的矿物成分、地球化学及Sr-Nd-Pb同位素研究。结果表明:岩石中斜长石主要为更长石(An=21～31);角闪石贫Ti(0.2),高Mg/(Mg+Fe)(0.5),属于富镁角闪石;而黑云母为镁质黑云母。岩石的地球化学具有高硅(58.86%～67.71%),富碱(Na2O+K2O=5.67%～9.63%),富集轻稀土元素(LREE)和大离子亲石元素(LILE),并强亏损元素Nb、Ta、Ti等特征。岩石的(87Sr/86Sr)i为0.7055～0.7069,εNd(t)为-7.65～-3.44;(206Pb/204Pb)i=17.66～18.00,(207Pb/204Pb)i=15.49～15.56,(208Pb/204Pb)i=37.73～38.19。矿物成分、地球化学和同位素特征说明,铜绿山岩体与阳新岩体为同源岩浆的产物,源区为深度大于40km的富集地幔,经下地壳的混染及分离结晶作用形成。岩浆熔体形成的温度应大于889℃。角闪石和黑云母的温度计估算岩浆结晶温度分别为650～800℃和500～630℃,黑云母开始结晶温度略低于角闪石结晶结束温度,压力为1.49kbar,对应侵位深度约4.9km。岩浆具有利于Cu、Fe、Au等成矿元素进入熔体的条件,可能与板块俯冲作用相关。     

An enhanced engineering perspective of global climate systems and statistical formulation of terrestrial CO2 exchanges

This paper designs a comprehensive approach based on the engineering machine/system concept, to model, analyze, and assess the level of carbon dioxide (CO₂) exchange between the atmosphere and terrestrial ecosystems, which is an important factor in understanding changes in global climate. The focus of this article is on spatial patterns and on the correlation between levels of CO₂ fluxes and a variety of influencing factors in eco-environments. The engineering/machine concept used is a system protocol that includes the sequential activities of design, test, observe, and model. This concept is applied to explicitly include various influencing factors and interactions associated with CO₂ fluxes. To formulate effective models of a large and complex climate system, this article introduces a modeling technique that will be referred to as stochastic filtering analysis of variance (SF-ANOVA). The CO₂ flux data observed from some sites of AmeriFlux are used to illustrate and validate the analysis, prediction, and globalization capabilities of the proposed engineering approach and the SF-ANOVA technique. The SF-ANOVA modeling approach was compared to stepwise regression, ridge regression, and neural networks. The comparison indicated that the proposed approach is a valid and effective tool with similar accuracy and less complexity than the other procedures.     

Assessing the ecosystem health status of Korea Gwangyang and Jinhae bays based on a planktonic index of biotic integrity (P-IBI)

To assess the responses of planktonic organisms to pollutants in the coastal ecosystems of Gwangyang and Jinhae bays in Korea, we investigated seasonal changes in various biological factors during the period from 2010 to 2012. Based on the characteristics of nutrient uptake by planktonic organisms under the coastal pollution conditions, we focused on four major parameters: total phytoplankton, harmful algal bloom (HAB) species, heterotrophic bacteria (HB) and Escherichia coli to develop a planktonic index of biotic integrity (P-IBI). The threshold values for abundances of total phytoplankton, HAB species and HB were based on the zero Z-score following normal distribution of the data for each parameter during the three years. Based on this approach, the threshold values were: 1.2 × 10⁶ cells L^?1 for total phytoplankton; 3.3 × 10⁴ cells L^?1 for HAB species; and 1.7 × 10⁶ cells mL^?1for HB. Five grade levels for the P-IBI were established, based on the zero Z-scores. The threshold value for E. coli not to be normalized was based on the USEPA and the Korean Ministry of Oceans and Fisheries guidelines. Validity of the grades and threshold values for each parameter established using the field data were tested by algal bioassays in a mesocosm enclosure, which supported the threshold values obtained in the field. In Gwangyang Bay, the annual integrated score for the P-IBI in 2010 was better than in the other years of the study. In Jinhae Bay, the P-IBI for the inner area of Masan Bay was Grade IV–V, indicating unhealthy conditions relative to the central and western outer areas, where the P-IBI varied from Grade II to III. The P-IBI values for Gwangyang and Jinhae bays were mostly rated as “Good (Grade II) or Fair (Grade III)”, except for a few stations in the semi-enclosed areas of the inner part of Jinhae Bay. From an overall view based on the P-IBI developed in this study, the coastal ecosystem health status in Gwangyang Bay was in a better condition than Jinhae Bay. The P-IBI indicated also a change to an unhealthy status during the rainy periods of spring and summer, whereas during winter and autumn the index indicated healthy conditions.     

Reproductive ecology of the dominant dinoflagellate, <Emphasis Type="Italic">Ceratium fusus</Emphasis>, in coastal area of Sagami Bay,Japan

The seasonal abundance of the dominant dinoflagellate, Ceratium fusus, was investigated from January 2000 to December 2003 in a coastal region of Sagami Bay, Japan. The growth of this species was also examined under laboratory conditions. In Sagami Bay, C. fusus increased significantly from April to September, and decreased from November to February, though it was found at all times through out the observation period. C. fusus increased markedly in September 2001 and August 2003 after heavy rainfalls that produced pycnoclines. Rapid growth was observed over a salinity range of 24 to 30, with the highest specific rate of 0.59 d⁻¹ measured under the following conditions: salinity 27, temperature 24°C, photon irradiance 600 μmol m⁻²s⁻¹. The growth rate of C. fusus increased with increasing irradiance from 58 to 216 μmol m⁻²s⁻¹, plateauing between 216 and 796 μmol m⁻²s⁻¹ under all temperature and salinity treatments (except at a temperature of 12°C). Both field and laboratory experiments indicated that C. fusus has the ability to grow under wide ranges of water temperatures (14–28°C), salinities (20–34), and photon irradiance (50–800 μmol m⁻²s⁻¹); it is also able to grow at low nutrient concentrations. This physiological flexibility ensures that populations persist when bloom conditions come to an end.     

Statistical Analysis of the Relationships among Coronal Holes,Corotating Interaction Regions,and Geomagnetic Storms

We have examined the relationships among coronal holes (CHs), corotating interaction regions (CIRs), and geomagnetic storms in the period 1996?–?2003. We have identified 123 CIRs with forward and reverse shock or wave features in ACE and Wind data and have linked them to coronal holes shown in National Solar Observatory/Kitt Peak (NSO/KP) daily He i 10?830 Å maps considering the Sun?–?Earth transit time of the solar wind with the observed wind speed. A sample of 107 CH?–?CIR pairs is thus identified. We have examined the magnetic polarity, location, and area of the CHs as well as their association with geomagnetic storms (Dst≤?50 nT). For all pairs, the magnetic polarity of the CHs is found to be consistent with the sunward (or earthward) direction of the interplanetary magnetic fields (IMFs), which confirms the linkage between the CHs and the CIRs in the sample. Our statistical analysis shows that (1) the mean longitude of the center of CHs is about 8°E, (2) 74% of the CHs are located between 30°S and 30°N (i.e., mostly in the equatorial regions), (3) 46% of the CIRs are associated with geomagnetic storms, (4) the area of geoeffective coronal holes is found to be larger than 0.12% of the solar hemisphere area, and (5) the maximum convective electric field E _y in the solar wind is much more highly correlated with the Dst index than any other solar or interplanetary parameter. In addition, we found that there is also a semiannual variation of CIR-associated geomagnetic storms and discovered new tendencies as follows: For negative-polarity coronal holes, the percentage (59%; 16 out of 27 events) of CIRs associated with geomagnetic storms in the first half of the year is much larger than that (25%; 6 out of 24 events) in the second half of the year and the occurrence percentage (63%; 15 out of 24 events) of CIR-associated storms in the southern hemisphere is significantly larger than that (26%; 7 out of 27 events) in the northern hemisphere. Positive-polarity coronal holes exhibit an opposite tendency.     

Spatial and seasonal variations in the water quality of Jinhae Bay,Korea

The chemical and biological characteristics of surface waters in Jinhae Bay were investigated over four seasons to understand water quality in light of the growing industrialisation occurring within this area. Jinhae Bay includes four smaller bays: Masan; Hangam; Jindong; and Gohyun. The water quality in Jinhae Bay varied spatially and seasonally. The water quality of both Hangam Bay and Masan Bay was highly degraded, demonstrating high concentrations of ammonia, nitrate, chlorophyll a and particulate organic carbon. Contamination from sewage was the dominant cause of the water quality deterioration in these bays. Conversely, the water quality in Jindong Bay and Gohyun Bay was not as severely affected as that of the above two bays. Water quality in Jinhae Bay was particularly poor in summer when nutrient loading was highest due to the run-off associated with high precipitation. Principal component analysis indicated that nitrogen contamination was a major factor influencing the water quality of Jinhae Bay. The effective reduction in high-nitrogen discharges is essential to improve water quality in Jinghae Bay.     

Imaging the Yellow Sea Bottom Cold Water from multichannel seismic data

The Yellow Sea Bottom Cold Water (YSBCW) is a large cold water mass lying in the deep part of the Yellow Sea during the warm season. We acquired multichannel seismic (MCS) data using an air gun source to image the structure of the YSBCW. The MCS data recorded reflections from sea water. The recognition of these reflections was confirmed by finite-difference seismic modeling in the frequency-domain. The seismic section from MCS data enabled discrimination of water masses distinctly separated by reflecting horizons. The structure of the water masses is fairly consistent with temperature-depth variations obtained using expandable bathythermograph (XBT) casts. The YSBCW is imaged as the lowermost water mass, maximally 40 m thick, that extends as a lens-like form along the sea bottom under the warm mixed layer. The correlation of XBT measurements and the seismic section indicates a rapid decrease in temperature from around 11 to 8 °C in the uppermost part of the YSBCW. A transition zone between the mixed layer and the underlying YSBCW is also defined. This transition zone has fairly uniform thickness of 14–18 m and marks an interval of rapid temperature drop, indicating vigorous thermal mixing. Our study demonstrates that MCS profiling is a useful and reliable tool for imaging fine structures in the shallow Yellow Sea.