Provenance record of late Maastrichtian–late Palaeocene Andean Mountain building in the Amazonian retroarc foreland basin (Madre de Dios basin,Peru)

Biostratigraphic, sedimentological and provenance analyses suggest that a proto‐Andean Cordillera already existed in southern Peru by late Maastrichtian–late Palaeocene times. A 270‐m‐thick stratigraphic section shows changes in depositional environments from shallow marine (early Maastrichtian) to non‐marine (late Maastrichtian) then back to estuarine (late Palaeocene) conditions. An erosional surface separates lower Maastrichtian from upper Maastrichtian deposits. Above this surface, the late Maastrichtian unit exhibits moderately developed palaeosols and syn‐sedimentary normal faults. The sedimentary evolution is accompanied by a decrease in sedimentation rate and by changes in provenance. Shallow marine lower Maastrichtian deposits have a cratonic provenance as shown by their low εNd(0) values (?15 to ?16) and the presence of Precambrian inherited zircon grains. The upper Maastrichtian deposits have a mixed Andean and cratonic origin with εNd(0) values of ~12.6 and yield the first Cretaceous and Permo‐Triassic zircon grains. Estuarine to shallow marine upper Palaeocene deposits have an Andean dominant source as attested by higher εNd(0) values (?6 to ?10) and by the presence of Palaeozoic and Late Cretaceous zircon grains. The changes in depositional environments and sedimentation rates, as well as the shift in detrital provenance, are consistent with a late Maastrichtian–late Palaeocene period of Andean mountain building. In agreement with recently published studies, our data suggest that an Andean retroarc foreland basin was active by late Maastrichtian–late Palaeocene times.     

Coastal hazard mapping in the Cuddalore region, South India

It is estimated that nearly one-third of India’s population lives on the coast and is dependent on its resources. Shoreline erosion, storm surges and extreme events have resulted in severe loss of human life, damage to ecosystems and to property along the coast of India. Studies carried out in the Cuddalore region of South India reveal that this low-lying coastal zone, which suffered significant erosion during the last century, has been severely affected by the tsunami of 2004, storm floods and cyclones. In response to these impacts, a variety of coastal defense measures and adaptation strategies have been implemented in the region, although with only limited success. In order to inform future coastal planning in this region, the work reported here identifies a composite hazard line, seaward of which coastal flooding events will have a return interval of less than 1 in 100 years. The area landward of the coastal hazard line will be unaffected by 100 years of coastal erosion at present day rates. The study directly supports the Integrated Coastal Zone Management (ICZM) Plan of the Tamil Nadu State through the identification and assessment of coastal hazards and the overall vulnerability to coastal flooding and erosion. The key results from this pilot study will be used directly by the State of Tamil Nadu in the protection of the coastal livelihoods, better conservation measures and sustainable development along the coast. This study is a step toward mapping the hazard line for the entire coast of India that helps protect human lives and property.     

Aerosol particle behavior during Dust Storm and Diwali over an urban location in north western India

In this study, the aerosol behavior during two contradictory events, i.e., dust storm (DS) and Diwali (DW) has been studied over Jaipur. The aerosol particle number concentration shows distinct features between DS and DW events. The total ANC was found minimum during DS while maximum during DW. The 24 h mean of total ANC was 9.15 × 10⁴ (±7.71 × 10⁴) and 5.38 × 10⁵ (±3.73 × 10⁵ particles/l) during DS and DW, respectively. The total ANC increases from 7.78 × 10⁴ to 5.32 × 10⁵ and 3.52 × 10⁵ to 1.70 × 10⁶ particles/l in 24 h during DS and DW, respectively. In DS, the ANC in coarse mode (2 < particle diameter < 20 μm) is significantly high while in DW, the ANC in fine mode (0.3 < particle diameter < 2 μm) exhibits higher concentration. During dust episode, a significant change in ANC (3.0 × 10³ to 1.12 × 10⁵ particles/l) was observed for the particle of size range in 2.0–20 μm with a slight increase in particles number concentration (7.48 × 10⁴ to 4.20 × 10⁵ particles/l) in 0.3–2.0 μm range is also observed. During DS, the fine and coarse mode particles increased 4.61 and 36.44 times while during DW, it increased 3.83 and 0.95 times, respectively. The relatively high particle levels during DW are attributed for two reasons: local emissions due to burning of fire crackers and meteorological conditions, i.e., low wind speeds and low mixing-layer heights lead to relatively high particle concentrations.

     

Ionic sources and water quality assessment around a reservoir in Tehri, Uttarakhand, Garhwal Himalaya

The paper discusses the ionic sources and chemical quality of the waters (surface and groundwater) around the Tehri reservoir in Uttarakhand, Garhwal, Himalaya, for drinking and irrigation purposes. The main Bhagirathi river, tributary streams and springs and groundwater are the main sources of water for the reservoir and inhabitant living around it. Fifty-two water samples were collected from springs, handpumps (borewell) and streams and were analysed for major ions. The pH is varying from 6.8 to 8.6 and EC from 28 to 820 μS/cm. The chemical composition of water is dominated by Ca, Mg and HCO₃. The high ratio of Ca + Mg/Na + K and low ratio of Na + K/TZ indicate dominance of carbonate dissolution as the main solute acquisition process in this part of Lesser Himalaya. The trilinear and X–Y plots suggest less contribution from silicate weathering and anthropogenic activities. The excess of Na over Cl indicating much of the alkalis in the waters of Tehri area have source other than precipitation possibly from silicate weathering. Recharged by meteoric water, the quality of water in the study area is controlled essentially by chemical processes occurring between water and lithology and locally altered by human activities. Among the trace metals the concentration of Fe at few locations has marginally exceeded the WHO and BIS standards of drinking water. The analytical result computed from various water quality indices indicate fairly good quality of water for both drinking and irrigation purposes. The factor analysis performed on the major ion data indicate two factors are the most important affecting the water quality of the area.     

Photocatalytic degradation of azo dye Orange II in aqueous solutions using copper-impregnated titania

During dyeing process, industries consume large quantity of water and subsequently produce large volume of wastewater. This wastewater is rich in color and contains different dyes. Orange II is one of them. In this article, metal-impregnated TiO₂ P-25 catalyst was used to enhance the photocatalytic degradation of Orange II dye. Photodegradation percentage was followed spectrophotometrically by the measurements of absorbance at λ _max = 483 nm. The effect of copper-impregnated TiO₂ P-25 photocatalyst for the degradation of Orange II has been investigated in terms of percentage removal of color, chemical oxygen demand (COD) and total organic carbon (TOC). As such 98 % color removal efficiency, 97 % percentage removal of COD and 89 % percentage removal of TOC was achieved with TiO₂ P-25/Cu catalysts under typical conditions. Copper-impregnated TiO₂ P-25 photocatalyst showed comparatively higher activity than UV/H₂O₂ homogeneous photodegradation. The relative electrical energy consumption for photocatalytic degradation was considerably lower with TiO₂ P-25/Cu photocatalyst than that with homogeneous photodegradation. Transmission electron microscopic analysis was used for catalyst characterization.     

Gradual diversions of the Rio Pastaza in the Ecuadorian piedmont of the Andes from 1906 to 2008: role of tectonics, alluvial fan aggradation, and ENSO events

The successive courses of the Rio Pastaza in the upper Amazonian Puyo plateau (Ecuador) during the past century have been followed using historical maps, aerial photographs, satellite imagery, topographic and river long profiles, and field studies. The abrupt change in direction of the Rio Pastaza from transverse to longitudinal was a result of two avulsions occurred between 1906 and 1976 at the braided-meandering transition of the former alluvial plain. These avulsions are related to aggradation at the toe of a braided piedmont fan prograding on to a hinterland-dipping topographic slope formed by ongoing tectonic backtilting. The main avulsion proceeded by annexation of a south-dipping depression created in front of the cordillera by backtilting of the plateau. A partial and gradual avulsion having occurred upstream of the former site between 1976 and 2008 is marked by the progressive predominance of a newly formed inner branch. Tectonic backtilting enhanced aggradation upstream of the initial site while it offered the newly avulsed channel a still more favorable way along the cordillera by creating a westward lateral slope. The correlation between ENSO events and the occurrence of the 1976–2008 avulsions strongly suggests that the triggers of the avulsions were the floods caused by the high water and sediment discharges associated with ENSO (La Ni?a) events contrasting with the regular monthly discharge and the lack of actual ‘normal’ floods during the inter-ENSO periods.     

Les ensembles fluviatiles néogènes du bassin subandin d'Équateur et implications dynamiquesThe Neogene fluvial systems of the Ecuadorian foreland basin and dynamic inferences

A sedimentological study of the Neogene continental infill of the Subandean foreland basin of Ecuador led us to define an evolution of the fluvial system from an alluvial plain to an alluvial fan with an increasing slope in the same time as the drainage changed from mostly longitudinal to transverse. Combined with the data presently available on palaeotopography, exhumation, tectonic evolution and geomorphology, these results enable us to infer that, in contrast with the other Subandean foreland basins of Bolivia and Peru, the progradation of the Neogene alluvial fans proceeded by an overall expansion, associated with a relatively small tectonic shortening and not as a result of the development of successive thrust-related depocentres. This also indicates that the surrection of the Cordillera progressed in Ecuador throughout the Neogene. To cite this article: F. Christophoul et al., C. R. Geoscience 334 (2002) 1029–1037.     

Experimental study of the interspecific competition between two sibling marine herbivorous rotifers in relation to food availability and initial population density

Our laboratory study concerns the competitive interaction between two marine rotifer species Brachionus plicatilis and Brachionus rotundiformis at five algal (Nannochloropsis salina) concentrations (0.4×10⁶ to 32.4×10⁶ cells/ml) and at four initial inoculation densities (numerically, 100% B. plicatilis; 75% B. plicatilis and 25% B. rotundiformis, 50% each of the two species; 25% B. plicatilis and 75% B. rotundiformis and 100% B. rotundiformis. The initial biomass varied as 0.33 and 0.22 μg/ml for B. plicatilis and B. rotundiformis respectively. Experiments were performed at (25±1)℃. Population densities were enumerated and the medium was changed daily up to 8 d in the experiment. At the lowest food level tested, B. rotundiformis formed superior competitor than B. plicatilis, regardless of starting inoculation density. Generally when the food concentrations increased, B. plicatilis showed a greater increase in biomass than B. rotundiformis. B. rotundiformis formed the largest in population growth, regardless of increasing food concentrations. When grown alone, B. plicatilis reached peak abundances of (1.311 5±0.028) and (137.5±0.014) μg/ml at low and high food densities respectively. The corresponding values of B. rotundiformis were 0.724 5±0.016 and 18.15±0.021. The adverse effects of B. rotundiformis on the peak abundances of B. plicatilis were observed at the lowest food level and higher initial density. The rate of population growth in controls varied from (0.792±0.162) to (1.482±0.132) μm/d for B. plicatilis and (0.445±0.041) to (0.856±0.012) μm/d for B. rotundiformis, depending on food level. When both species were introduced together, low food levels favoured higher abundance of B. rotundiformis than B. plicatilis, suggesting that increased population density of the smaller B. rotundiformis was more successfull than larger B. plicatilis in brackish waters. Our work reveals that available food (type and quantity) along with starting inoculation density had significant effect on the interspecific competition between marine sibling rotifer species in zooplankton community structure.     

Estimation of Cd,Pb and flame retardants in electric mosquito bat using EDXRF,ICP-OES,AAS and GC–MS

In the present study, investigated the concentrations of hazardous substances such as Pb, Cd and polybrominated flame retardants present in an electric mosquito bats, which are used for trapping the mosquitoes in the domestic areas. China has captured a big share of mosquito bat market in India and penetrated deep into rural areas also. The presence of hazardous substances is fatal to environment and human beings. Hence, the concentrations of hazardous substances present in the bats need to be estimated accurately. The dismantled homogeneous samples were subjected to estimate the toxic metals like cadmium and lead by using energy-dispersive X-ray fluorescence spectroscopy, inductively coupled plasma optical emission spectroscopy and atomic absorption spectroscopy for comparison. The flame brominated retardants were tested using gas chromatography–mass spectrometer. The analytical data obtained from the power supply wires of the bat suggest that the concentration levels of cadmium found to be below the detection limits. Whereas the lead content has higher in the range of 3574–7575 ppm than the permissible limits set by the e-waste rule, i.e. 1000 ppm. Moreover, the high amount of lead (>80,000 ppm) was obtained in the printed circuit board apart from power supply wires of mosquito bat. The content of brominated flame retardants in mosquito bat was estimated to be within the limits of e-waste rule. Considering their significant high hazardous metals content, coupled with their large quantities of mosquito bats used in the country, there is a need to control the hazardous waste of mosquito bats.