In this study, the removal of zinc(II) ion from an aqueous solution by pistachio shells (PS) is investigated. The dynamic behavior of the adsorption is examined on the effects of pH, adsorbent dosage, and contact time. The adsorption rates are determined quantitatively and simulated by the Lagergren first order, pseudo‐second order, Elovich, and intra‐particle diffusion kinetic models. The adsorption kinetic models are also tested for validity. The thermodynamic parameters, which are also deduced from adsorption experiments, are very useful in elucidating the nature of adsorption. The experimental results reveal that the optimum pH value and the contact time for the adsorption of Zn2+ onto PS are found as 6 and 10 min, respectively. According to these parameters, adsorption process follows the pseudo‐second order kinetic model with high correlation coefficients (R2 = 0.999). The obtained results demonstrate that PS is a reasonably effective adsorbent for the removal of Zn2+ from aqueous leachate of hazardous waste. 相似文献
Land subsidence in the western San Joaquin Valley has been studied and monitored for almost six decades. Especially in the 1950s and 1960s, land subsidence had tremendous negative environmental and socioeconomic implications. The rate of land subsidence in the Los Banos–Kettleman City area, however, has decreased during the last three decades as a result of a decrease in groundwater withdrawal, following the importation of surface water to the Valley in late 1960s. The land subsidence in the Valley potentially could be a serious issue if the existing surface water supplies cannot meet increasing water demands during future critical drought periods. In this respect, this paper proposes a preliminary analysis to predict magnitudes of subsidence for the period 2000 to 2040, based on historical occurrences. In this study, extrapolation from earlier subsidence is based on: (1) knowledge of recent post-drought records at extensometers, (2) assumption of a single time porosity scenario, and (3) the premise that pumpage from the confined aquifer gradually will decrease as a result of progressive water quality degradation. Predicted magnitudes of land subsidence in the Los Banos–Kettleman City area are expected to be in the range 0.5 to 4.0 m for the next 4 to 5 decades under the scenario considered in this paper. [Key words: subsidence, groundwater extraction, aquitard, inelastic compaction, active porosity, Los Banos-Kettleman City, California.] 相似文献
In the context of climate change and over-exploitation of water resources, water shortage and water pollution in arid regions have become major constraints to local sustainable development. In this study, we established a Soil and Water Assessment Tool (SWAT) model for simulating non-point source (NPS) pollution in the irrigation area of the lower reaches of the Kaidu River Basin, based on spatial and attribute data (2010–2014). Four climate change scenarios (2040–2044) and two agricultural management scenarios were input into the SWAT model to quantify the effects of climate change and agricultural management on solvents and solutes of pollutants in the study area. The simulation results show that compared to the reference period (2010–2014), with a decline in streamflow from the Kaidu River, the average annual irrigation water consumption is expected to decrease by 3.84x108 m3 or 8.87% during the period of 2040–2044. Meanwhile, the average annual total nitrogen (TN) and total phosphorus (TP) in agricultural drainage canals will also increase by 10.50% and 30.06%, respectively. Through the implementation of agricultural management measures, the TN and TP in farmland drainage can be reduced by 14.49% and 16.03%, respectively, reaching 661.56 t and 12.99 t, accordingly, and the increasing water efficiency can save irrigation water consumption by 4.41 x108 m3 or 4.77%. The results indicate that although the water environment in the irrigation area in the lower reaches of the Kaidu River Basin is deteriorating, the situation can be improved by implementing appropriate agricultural production methods. The quantitative analysis results of NPS pollutants in the irrigation area under different scenarios provide a scientific basis for water environmental management in the Kaidu River Basin.
In the Song Tranh 2 (ST2) hydropower reservoir located in the Quang Nam province, Central Vietnam, earthquakes started occurring soon after impoundment of the reservoir in late 2010. Earthquakes continue to occur in the region, and two earthquakes of M 4.6 and 4.7 on October 22, 2012 and November 15, 2012, respectively, have been reported (Trieu et al. 2014; Giang et al. 2015) in the vicinity of the reservoir. In the present study, b-value has been estimated, and focal mechanism solutions have been computed for the first time using moment tensor inversion approach. Also, the influence of impoundment of reservoir on the occurrence of earthquakes has been computed for the ST2 region based on Coulomb stress. A quality data set of 595 earthquakes recorded for the period of October 2012 to April 2014 at ten stations of the seismic network operated by the Institute of Geophysics (IGP) has been used to calculate b-values for the northern and southern seismicity clusters of the region. In general, the b-values associated with reservoir-triggered seismicity (RTS) are found to be higher than the regional b-values in the frequency-magnitude relation of earthquakes. For the ST2 region, it is found that the b-values for the northern and southern clusters are 0.94 ± 0.04 and 0.90 ± 0.04, respectively. Focal mechanism solutions obtained for the two earthquakes close to the reservoir have a right-lateral strike-slip mechanism, with the preferred planes trending NW-SE. These results are concurrent with the orientation of the nearby local surface faults, which we confirm as the active faults in this region. Influence of the stresses due to reservoir water load on the local seismicity is computed based on the obtained focal mechanism by using the concept of fault stability. It is found that most of the earthquakes occur in the positive Coulomb stress region, which shows the influence of reservoir impoundment on earthquake occurrence in the vicinity. Our results suggest that the local earthquakes are triggered by the impoundment of the ST2 reservoir. 相似文献