Identification of a sulfide derivative with a bicyclic hydrocarbon skeleton related to squalene. Part II: synthesis of a S-spiro-like dithiolane triterpenoid

A sulfide with a bicyclic squalene hydrocarbon skeleton present in sediments from various depositional settings and of different geological age has been identified by synthesis of a reference compound. In contrast to previous expectations [cf. Schouten, S., Sinninghe Damsté, J.S., de Leeuw, J.W., 1995. A novel triterpenoid carbon skeleton in immature sulphur-rich sediments. Geochimica et Cosmochimica Acta 59, 953–958; Gug, S., Schaeffer, P., Adam, P., Klein, S., Motsch, E., Albrecht, P., 2009. Identification of a sulfide derivative with a bicyclic hydrocarbon skeleton related to squalene. Part I: Synthesis of a dithiane triterpenoid. Organic Geochemistry 40, 876–884.], this sulfide bears two “S-spiro type“ thiolane moities, but not the two thiochromane moieties originally envisaged. The synthesis resulted in the formation of a complex isomeric mixture of compounds, all co-eluting in gas chromatography (GC) in the form of one broad peak, as is the case with the geochemical compound. The spiro-type sulfide was formed by intramolecular sulfurization of a polyunsaturated bicyclic squalene derivative of unknown biological origin. The presence of this sulfide in a number of Triassic to Miocene marine sediments from various and contrasting depositional settings (upwelling environments, shallow continental platforms, lagoonal sub-basins, hypersaline environments), all characterized by strongly anoxic conditions, but with or without photic zone anoxia, indicates that the microorganisms biosynthesizing the precursor bicyclic squalene occupy diverse ecological niches.     

Trends in 1,4-Dioxane Analyses: Implications for Identification and Characterization of Contaminated Groundwater Sites

1,4-Dioxane is a contaminant of emerging concern, and there is significant uncertainty about how its environmental occurrence in groundwater is being assessed given the various analytical methods available. This study compiled public sampling records from 2000 to 2019 that included >106,000 analyses of 1,4-dioxane from 822 different U.S. sites. The 1,4-dioxane detection frequency in the entire dataset (including all methods) was 45%, and the median detected concentration was 10 μg/L, highlighting the dilute nature of 1,4-dioxane in environmental media and the importance of selecting methods with adequate sensitivity. The annual distribution of samples analyzed by each method type confirmed a shift towards methods designed for semi-volatile compounds (Method 8270 and Method 8270 SIM) that exhibited consistently lower reporting limits (median reporting limit for each year typically ≤1 μg/L). In contrast, the method designed for volatile compounds (Method 8260) exhibited less sensitivity for 1,4-dioxane (median reporting limit per year between 40 and 100 μg/L) and its use declined significantly over time with increasing use of the moderately sensitive Method 8260 SIM in later years. This shift contributed to an increase in the 1,4-dioxane detection frequency over time, with a strong correlation between the annual detection frequency and the median reporting limit. Sites where 1,4-dioxane was analyzed but not detected overwhelmingly used less-sensitive methods that may not have been adequate for the expected concentration levels. Given the sub-μg/L groundwater criteria issued for 1,4-dioxane by some regulatory agencies, more sensitive and accurate methods will be increasingly needed to assess compliance.     

冈底斯中段卡热辉长岩锆石U- Pb年代学、地球化学及构造意义

以冈底斯中段曲水县西南方向卡热乡一带出露的辉长岩为研究对象,进行了LA-ICP-MS锆石UPb测年以及全岩地球化学的系统测定,据此讨论岩石的成因及其构造意义。该辉长岩主要由单斜辉石和斜长石组成,辉长岩具有低硅、贫碱、富铝,中等富集轻稀土,富集大离子亲石元素,亏损高场强元素的地球化学特征,与岛弧和大陆边缘地区产出的高铝玄武岩化学组成十分相似,表明辉长岩原生岩浆为被俯冲改造的岩石圈幔源岩浆,在演化过程中受到了上地壳物质的混染。锆石LA-ICP-MS U-Pb年龄为49.01±0.51Ma(MSWD=0.41),指示岩体形成时代为始新世。卡热辉长岩具有显著亏损的锆石Hf同位素组成,εHf(t)值均为正值,分布在+10.88～+13.71之间,综合分析表明卡热辉长质侵入体可能为近期遭受俯冲板片析出流体交代作用的亏损地幔部分熔融的产物。结合区域构造演化史认为该岩体在冈底斯南缘的始新世期间存在着强烈的岩浆底侵和壳幔岩浆混合作用。     

计算机2000年问题对地震观测的影响及其预防方法

简要分析了计算机２０００ 年问题对地震观测的影响．这些影响主要表现在各种应用软件方面．提出了几种预防方法,除了更换必要的观测仪器之外,还要解决各类软件的２０００ 年问题     

含流体致密砂岩的纵波频散及衰减:基于双重双重孔隙结构模型描述的特征分析

致密砂岩普遍具有低孔、低渗及微裂缝发育的地质特征,并且呈现出很强的非均匀性.致密砂岩储层与常规砂岩储层比较,具有明显的岩石物理性质、渗流力学性质方面的差异.致密砂岩内部的非均匀性对弹性波频散、衰减有显著影响,其中包括孔隙结构的非均匀性,即岩石内部孔隙参数的不均一性,以及孔隙内部不相混溶流体的非均匀分布;此外,非均匀性的尺度也决定了波出现显著频散与衰减的频段.综合考虑致密砂岩孔隙结构非均匀性及流体斑块状饱和的非均匀性,本文采用双双重孔隙介质结构模拟了致密砂岩的弹性波响应,分析了同时具备两类非均质性岩石中的波传播特征.调查分析了两组分别来自中国鄂尔多斯盆地苏里格气田及四川盆地广安气田的不同类型致密砂岩储层的岩芯超声波实验数据,给出了岩石样本的弹性波速度频散与衰减曲线.结果显示理论模型预测结果与完全饱和、部分饱和岩石的实验数据吻合良好.对两个地区致密砂岩岩芯数据进行对比分析,苏里格致密砂岩样本总体上比广安致密砂岩渗透率高,在各孔隙度范围内,特征模拟显示苏里格样本的裂隙尺寸明显大于广安样本.广安致密砂岩在低孔隙度范围内发育了更多、更小的颗粒裂隙/接触.致密砂岩的速度频散与衰减结果受流体黏度、晶体破裂及流体斑块状饱和的共同影响.此外,孔隙度越大,部分饱和岩石中斑块状饱和机制对总衰减的贡献越低,与之相对,结构非均质性所占的比重则有所增强.     

层状半空间中周期分布凸起地形对平面SH波的散射

提出了一种新的以层状半空间中周期分布斜线荷载动力格林函数为基本解的间接边界元方法,研究了周期分布凸起地形对平面SH波的散射问题.方法将散射波场分解为凸起内部散射波场和凸起外部散射波场.凸起内部散射波场通过在凸起闭合边界上施加虚拟斜线荷载产生的动力响应来模拟,而凸起外部散射波场则通过在凸起与半空间交界面上施加虚拟周期分布斜线荷载产生的动力响应来模拟.周期分布斜线荷载动力格林函数的引入,使得本文方法仅需针对一个凸起进行边界单元的离散和求解,便可完成问题的求解,避免了通过截断无限边界求解而引入的误差,方法具有较高精度的同时显著降低了求解自由度.文中通过与已有结果的比较,验证了方法的正确性,并以均匀半空间和基岩上单一土层中周期分布凸起为例进行了数值计算分析.研究表明,凸起间距对凸起地形间的动力相互作用有着显著的影响,同时层状半空间中周期分布凸起地形对SH波的散射与均匀半空间情况也有着显著的差别.     

外源污染物对硬骨鱼甲状腺干扰作用机制的研究进展

甲状腺激素在鱼类生长发育、变态、生殖、渗透调节以及摄食和营养代谢中发挥着重要作用,外源化合物对硬骨鱼的甲状腺干扰作用会导致发育和孵化延迟、运动性降低。本文首先对鱼类甲状腺激素的中枢调控、合成、转运、代谢和发挥作用的相关过程进行简要介绍,随后从核受体介导途径、非受体介导途径两个方面综述了外源污染物对硬骨鱼甲状腺的干扰作用机制,最后从物种特异性、检测指标、膜受体介导途径三个方面提出了目前研究的不足之处以及解决方法,以期为今后探究外源污染物对鱼类甲状腺系统干扰作用机制的研究提供更多的参考。     

西昌市泸山地区典型火后泥石流特征与成因机制研究——以响水沟左岸3#支沟为例

2020年3月30日,四川省凉山州西昌市经久乡发生森林大火,山火燃烧后形成的山火灰和烧焦土体在强降雨作用下极易启动形成泥石流,给西昌市泸山、琼海景区生态环境及当地百姓生命财产安全带来潜在地质灾害风险。以西昌市安哈镇响水沟左岸3^#支沟为例,采用野外调查、无人机航拍、地球物理探测、现场及室内实验等手段,对2020年5月1日该沟发生的火后泥石流流体特征、动力学参数及成因机制等开展研究,系统分析了山火及降雨过程对该次火后泥石流形成的影响机制。该成果可为系统认识西昌泸山“3·30”山火地区火后泥石流的运动特征、物源规模、激发雨量及其发展趋势研判提供科学参考。     

横观各向同性场地中埋置衬砌隧道对qP波的散射

采用间接边界元法(IBEM)结合"分区契合"技术,研究qP波入射下横观各向同性(TI)场地中衬砌隧道的动力响应问题。方法充分利用半空间和全空间动力格林函数在分别构造含孔半无限空间域和闭合域内散射波场方面的优势,将含有衬砌隧道的层状弹性半空间分解为含孔半无限空间域和一个环形衬砌闭合域来分别进行波场构造,有效地降低了求解时间和存储量。文中验证方法的正确性,并以均匀TI半空间和基岩上单一TI土层为例,计算分析弹性半空间场地中隧道衬砌内表面动应力放大问题。结果表明qP波入射下,TI介质与各向同性介质场地中埋置衬砌隧道的动力响应差异显著,TI介质参数的变化导致场地动力特性的改变,进而改变场地与衬砌隧道的动力相互作用机制,显著影响着衬砌内表面动应力的大小及其空间分布。