The reliability of analytical data for tributyltin (TBT) in sea water and its implications on water quality criteria

To investigate the reliability of analytical data for tributyltin (TBT) in sea water, split water samples were distributed to ten laboratories in six countries. The sub-surface samples comprised: (i) an offshore (0·5 km) water sample, (ii) the same sample but spiked with an undisclosed quantity of TBT standard compound (175 ng TBT⁺ liter⁻¹), and (iii) a sample taken from a yacht marina. The seven acceptable data sets were in good agreement for the spiked sample (178 ± 26 ng TBT⁺ liter⁻¹) but showed a greater variation in concentrations reported for the yacht marina sample (366 ± 93 ng TBT⁺ liter⁻¹). Atomic absorption and gas chromatographic-flame photometric detection techniques produced results of similar accuracy and precision. Samples acidified with 1 ml of 10% (v/v) acetic acid appeared stable for more than 2 weeks when stored refrigerated and in darkness. Analyses of the offshore seawater sample revealed TBT contamination (9 ± 7 ng TBT⁺ liter⁻¹) indicating dispersion of the compound to the shelf waters off Monaco. The spread in values reported by the laboratories demonstrates inherent difficulties in obtaining good precision below approximately 20 ng TBT⁺ liter⁻¹. This observation is discussed with respect to the setting and enforcing of water quality standards.     

On the application of the units of measurement of the amount and composition of matter in oceanology

We consider the procedures of conversion of the conventional and out-of-system units of measurement of the amount and composition of matter used in oceanology to the International System of Units (SI). The coefficients of conversion are presented in the form of a table. We present the data on the units of measurement of mineralization (scales of salinity) of seawater for the oceanic range of its variability, freshened waters of internal seas, and brines. The contemporary concept of salinity as a dimensionless quantity is discussed.Translated from Morskoi Gidrofizicheskii Zhurnal, No. 4, pp. 61–72, July–August, 2004.     

Temperature of the ocean surface as an indicator of thermodynamic processes in the northwest Pacific

The numerical computations and analysis of the anomalies of temperature of the ocean surface in the northwest part of the Pacific Ocean were carried out on the basis of the archival data for 1960 and 1964–1985. A five-year period of general instability of the annual average temperature was revealed (1973–1977). In this period, the year 1974 was the coldest and the year 1977 was characterized as extremely warm. We performed the analysis of the interannual and annual variability of the anomalies of temperature of the ocean surface and revealed common features and distinctions of the seasonal evolution of these anomalies for years with substantially different temperature conditions. A quasistationary zone of maximally heated waters was discovered in the band located (independently of the year and season) between 36 and 46°N to the east of 140°E. This zone coincides in space with the zone of the subarctic front and the south part of the subarctic region. The influence of the meanders of the Kuroshio Current was demonstrated. It is shown that their activity increases after the events of El-Niño and, hence, the thermal energy of the water area considerably increases and remains elevated for a period of 1–2 yr after the indicated events.Translated from Morskoi Gidrofizicheskii Zhurnal, No. 5, pp. 45–52, September–October, 2004.This revised version was published online in May 2005 with corrections to cover date.     

Circulation and currents in the southwestern East/Japan Sea: Overview and review

A review is made of circulation and currents in the southwestern East/Japan Sea (the Ulleung Basin), and the Korea/Tsushima Strait which is a unique conduit for surface inflow into the Ulleung Basin. The review particularly concentrates on describing some preliminary results from recent extensive measurements made after 1996. Mean flow patterns are different in the upstream and downstream regions of the Korea/Tsushima Strait. A high velocity core occurs in the mid-section in the upstream region, and splits into two cores hugging the coasts of Korea and Japan, the downstream region, after passing around Tsushima Island located in the middle of the strait. Four-year mean transport into the East/Japan Sea through the Korea/Tsushima Strait based on submarine cable data calibrated by direct observations is 2.4 Sv (1 Sv = 10⁶ m³ s⁻¹). A wide range of variability occurs for the subtidal transport variation from subinertial (2–10 days) to interannual scales. While the subinertial variability is shown to arise from the atmospheric pressure disturbances, the longer period variation has been poorly understood.Mean upper circulation of the Ulleung Basin is characterized by the northward flowing East Korean Warm Current along the east coast of Korea and its meander eastward after the separation from the coast, the Offshore Branch along the coast of Japan, and the anticyclonic Ulleung Warm Eddy that forms from a meander of the East Korean Warm Current. Continuous acoustic travel-time measurements between June 1999 and June 2001 suggest five quasi-stable upper circulation patterns that persist for about 3–5 months with transitions between successive patterns occurring in a few months or days. Disappearance of the East Korean Warm Current is triggered by merging the Dok Cold Eddy, originating from the pinching-off of the meander trough, with the coastal cold water carried Southward by the North Korean Cold Current. The Ulleung Warm Eddy persisted for about 20 months in the middle of the Ulleung Basin with changes in its position and spatial scale associated with strengthening and weakening of the transport through the Korea/Tsushima Strait. The variability of upper circulation is partly related to the transport variation through the Korea/Tsushima Strait. Movements of the coastal cold water and the instability of the polar front also appear to be important factors affecting the variability.Deep circulation in the Ulleung Basin is primarily cyclonic and commonly consists of one or more cyclonic cells, and an anticyclonic cell centered near Ulleung Island. The cyclonic circulation is conjectured to be driven by a net inflow through the Ulleung Interplain Gap, which serves as a conduit for the exchange of deep waters between the Japan Basin in the northern East Sea and the Ulleung Basin. Deep currents are characterized by a short correlation scale and the predominance of mesoscale variability with periods of 20–40 days. Seasonality of deep currents is indistinct, and the coupling of upper and deep circulation has not been clarified yet.     

Late Holocene estuarine–inner shelf interactions; is there evidence of an estuarine retreat path for Tampa Bay, Florida?

The purpose of this study was to determine if and how a large, modern estuarine system, situated in the middle of an ancient carbonate platform, has affected its adjacent inner shelf both in the past during the last, post-glacial sea-level rise and during the present. An additional purpose was to determine if and how this inner shelf seaward of a major estuary differed from the inner shelves located just to the north and south but seaward of barrier-island shorelines. Through side-scan sonar mosaicking, bathymetric studies, and ground-truthing using surface grab samples as well as diver observations, two large submarine sand plains were mapped – one being the modern ebb-tidal delta and the other interpreted to be a relict ebb-tidal delta formed earlier in the Holocene. The most seaward portion of the inner shelf studied consists of a field of lobate, bathymetrically elevated, fine-sand accumulations, which were interpreted to be sediment-starved 3D dunes surrounded by small 2D dunes composed of coarse molluscan shell gravel. Additionally, exposed limestone hardbottoms supporting living benthic communities were found as well. This modern shelf sedimentary environment is situated on a large, buried shelf valley, which extends eastward beneath the modern Tampa Bay estuary. These observations plus the absence of an incised shelf valley having surficial bathymetric expression, and the absence of sand bodies normally associated with back-tracking estuarine systems indicate that there was no cross-shelf estuarine retreat path formed during the last rise in sea level. Instead, the modern Tampa Bay formed within a mid-platform, low-relief depression, which was flooded by rising marine waters late in the Holocene. With continued sea-level rise in the late Holocene, this early embayment was translated eastward or landward to its present position, whereby a larger ebb-tidal delta prograded out onto the inner shelf. Extensive linear sand ridges, common to the inner shelves to the north and south, did not form in this shelf province because it was a low-energy, open embayment lacking the wave climate and nearshore zone necessary to create such sand bodies. The distribution of bedforms on the inner shelf and the absence of seaward-oriented 2D dunes on the modern ebb-tidal delta indicate that the modern estuarine system has had little effect on its adjacent inner shelf.     

Structure of the mesoscale variability of the troposphere and stratosphere found from radio refraction measurements via CHAMP satellites

Data of an experiment on radio occultation sounding of the atmosphere with the use of GPS signals were used to obtain global distributions of the variances of mesoscale variations in the refractive index in the troposphere and stratosphere. The experiment was carried out with the CHAMP satellite during the period 2001–2005. Measured vertical profiles were smoothed inside 5–10-km-thick layers centered at different altitudes in the troposphere and stratosphere with the use of second-degree polynomials. Deviations from the smoothed quantities and the corresponding variances were obtained for each profile and averaged for each month during the analyzed interval of the CHAMP experiment. Altitude-longitude-latitude inhomogeneities in the distribution of refractive index variances were analyzed. Altitude and latitude distributions of maxima and minima of refractive index variances depend on altitude and season. Turbulence and acoustic gravity waves can be the causes of small-scale and mesoscale variations in the refractive index of the troposphere and stratosphere. The variances of variations in the refractive index are greater in the regions of tropospheric jet streams and in the zones of near-equatorial deep convection. Atmospheric disturbances increase over mountain systems.     

SeagrassNet monitoring across the Americas: case studies of seagrass decline

Seagrasses are an important coastal habitat worldwide and are indicative of environmental health at the critical land–sea interface. In many parts of the world, seagrasses are not well known, although they provide crucial functions and values to the world's oceans and to human populations dwelling along the coast. Established in 2001, SeagrassNet, a monitoring program for seagrasses worldwide, uses a standardized protocol for detecting change in seagrass habitat to capture both seagrass parameters and environmental variables. SeagrassNet is designed to statistically detect change over a relatively short time frame (1–2 years) through quarterly monitoring of permanent plots. Currently, SeagrassNet operates in 18 countries at 48 sites; at each site, a permanent transect is established and a team of people from the area collects data which is sent to the SeagrassNet database for analysis. We present five case studies based on SeagrassNet data from across the Americas (two sites in the USA, one in Belize, and two in Brazil) which have a common theme of seagrass decline; the study represents a first latitudinal comparison across a hemisphere using a common methodology. In two cases, rapid loss of seagrass was related to eutrophication, in two cases losses related to climate change, and in one case, the loss is attributed to a complex trophic interaction resulting from the presence of a marine protected area. SeagrassNet results provide documentation of seagrass change over time and allow us to make scientifically supported statements about the status of seagrass habitat and the extent of need for management action.     

Th sorption and export models in the water column: A review

Over the past few decades, the radioisotope pair of ²³⁸U / ²³⁴Th has been widely and increasingly used to describe particle dynamics and particle export fluxes in a variety of aquatic systems. The present paper is one of five review articles dedicated to ²³⁴Th. It is focused on the models associated with ²³⁴Th whereas the companion papers (same issue) are focused on present and future methodologies and techniques (Rutgers van der Loeff et al.), C / ²³⁴Th ratios (Buesseler et al.), ²³⁴Th speciation (Santschi et al.) and present and future applications of ²³⁴Th [Waples, J.T., Benitez-Nelson, C.R., Savoye, N., Rutgers van der Loeff, M., Baskaran, M., Gustafsson, Ö., this issue. An Introduction to the application and future use of ²³⁴Th in aquatic systems. Marine Chemistry, FATE special issue]. In this paper, we review current ²³⁴Th scavenging models and discuss the relative importance of the non-steady state and physical terms associated with the most commonly used model to estimate ²³⁴Th flux. Based on this discussion we recommend that for future work the use of models should be accompanied by a discussion of the effect that model and data uncertainty have on the model results. We also suggest that future field work incorporate repeat occupations of sample sites on time scales of 1–4 weeks in order to evaluate steady state versus non-steady state estimates of ²³⁴Th export, especially during high flux events (> ca. 800 dpm m^− 2 d^− 1). Finally, knowledge of the physical oceanography of the study area is essential, particularly in ocean margins and in areas of established upwelling (e.g., Equatorial Pacific). These suggestions will greatly enhance the application of ²³⁴Th as a tracer of particle dynamics and flux in more complicated regimes.