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The X-ray absorption spectra of the transition metal L3,2-edges of the dichalcogenides FeS2 (pyrite), FeSe2, FeTe2, CoS2, CoSe2, CoTe2, NiS2, NiSe2 and NiTe2 have been studied. These spectra are compared with theoretical simulations make using the atomic multiplet approach assuming on octahedral site for the metal atoms. The Ni spectra can be closely simulated using this approach but the Fe and Co spectra show less good fits to the experimental data. The reasons for this and its implications for the use of L-edge spectra in the study of such minerals are discussed in terms of the covalency and the ground states of the compounds; these results indicate the mixing of the ground states increases in the order Ni<Co<Fe.  相似文献   
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A difficulty in the interpretation of mechanical and thermo-mechanical tests on specimens drawn from large argillaceous formations is the strong inhomogeneity of void ratio, clay minerals and carbonates content.

In this paper a relationship is developed to link strength and the maximum preconsolidation stress to the initial void ratio and carbonate content. Compressibility is also correlated to carbonates.

Thermal strains in drained and undrained conditions for a Spanish, a belgian and an Italian natural clay are compared. In the elastic state strains are comparable, while in the plastic range thermal strains are highest for the Belgian clay, lower in the Spanish cemented clay and lowest in the Italian clay, very stiff and cemented.  相似文献   

25.
Water vapor plays a key role in weather and climate forming, which leads to the need for continuous monitoring of its content in different parts of the Earth. Intercomparison and validation of different methods for integrated water vapor (IWV) measurements are essential for determining the real accuracies of these methods. CIMEL photometers measure IWV at hundreds of ground-based stations of the AERONET network. We analyze simultaneous IWV measurements performed by a CIMEL photometer, an RPG-HATPRO MW radiometer, and a FTIR Bruker 125-HR spectrometer at the Peterhof station of St. Petersburg State University. We show that the CIMEL photometer calibrated by the manufacturer significantly underestimates the IWV obtained by other devices. We may conclude from this intercomparison that it is necessary to perform an additional calibration of the CIMEL photometer, as well as a possible correction of the interpretation technique for CIMEL measurements at the Peterhof site.  相似文献   
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The discovery of Mercury's magnetosphere by Mariner 10 was surprising since the conventional view of regenerative planetary dynamos had been that the spin requirement would likely have been in excess of the observed spin rate of Mercury. Also internal fluid motions were not expected to be sufficiently large. This paper explores the alternative model of the formation of Mercury's magnetosphere via electromagnetic induction forced by the solar wind. It is shown, however, that the constraints are so severe as to limit severely the applicability of such a model. Although induction is easily observed on the Moon, the modification of the magnetic boundary condition associated with a plasma magnetosphere on Mercury rules out its formation via induction except for interplanetary driving fields which are decreasing in amplitude. That model is explored but retains the difficulty that induced magnetospheres tend to be of small radial and temporal extent compared to that inferred by Ness et al. for Mercury.  相似文献   
27.
On 11 September 1973 a peculiar prominence was observed. The prominence displayed strong ( 50km s–1) systematic motions toward and away from the observer. The unusual spectrographic appearance of the prominence might have been due to downflowing material lifted into the corona during an earlier coronal transient.The National Center for Atmospheric Research is sponsored by the National Science Foundation.Operated by the Association of Universities for Research in Astronomy, Inc., under contract with the National Science Foundation.  相似文献   
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We analyze the role of weak photospheric flux concentrations that evolve in a filament channel, in the triggering of dynamic changes in the shape of a filament. The high polarimetric sensitivity of THEMIS allowed us to detect weak flux concentrations (few Gauss) associated with the filament development. The synoptic instruments (MDI, SOLIS) even if their sensitivity is much less than THEMIS were useful to follow any subsequent strengthening of these flux concentrations after their identification in the THEMIS magnetograms. We found that (1) the northern part of the filament develops an Hα barb at the same time that weak minority polarity elements develop near a plage; (2) a section in the southern part of the Hα filament gradually disappears and later reforms at the same time that several mixed-polarity magnetic elements appear, then subsequently cancel or spread away from each other. These changes correspond to increases in EUV emission, as observed by TRACE, EIT, and CDS. This suggests that the plasma is temporarily heated along the filament spine. An idealized sequence of force-free models of this filament channel, based on plasma-supporting magnetic dips occurring in the windings of a very weakly twisted flux tube, naturally explains the evolution of its southern part as being due to changes in the topology of the coronal magnetic field as the photospheric flux concentrations evolve.  相似文献   
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