Hadley and Rossby regimes in a simple model of convection of a rotating fluid

This paper analyzes the properties of solutions to the equations describing the motion of a stratified fluid in the class of velocity and temperature fields linear in coordinates. For an ideal fluid, these equations, on the one hand, are exact for the corresponding hydrodynamic problem and, on the other hand, are identical to the equations of motion for a heavy top. In a conservative case, the equations of motion of a top share common solutions with the equations of geophysical fluid dynamics and reproduce motions similar to those existing in the theory of the large-scale atmospheric circulation. This study considers the effects of viscosity and heat conduction in the fluid, which are, in a sense, similar to the effect of friction in the case of a top. The influence of deflections of the vectors of gravity and external rotation from their standard directions for a plane-parallel atmosphere is also considered. The regimes of motions that are described by the starting equations and approximations commonly used to model the atmospheric general circulation (the quasi-geostrophic approximation) are analyzed. It is shown that these equations correctly describe the Hadley and Rossby circulation regimes and transitions between them that are observed in numerical and laboratory experiments. Particular attention is given to the consistency between different regimes of the exact equations and their quasi-geostrophic approximations, which is manifested for small Rossby numbers and is generally absent for large Rossby numbers. The asymptotic behaviors of the curves of transition between the Hadley and Rossby regimes under the conditions of breaking the external symmetry of flows are obtained. These asymptotics explain the corresponding transition boundaries for the regimes observed in the known experiments in annuluses.     

Simulation of Hydrophysical Processes in Coastal Regions of the Sea

In the present work, we generalize the results of our investigations in the field of simulation of hydrophysical and ecological processes in coastal regions of various seas and some closed basins. The developed and applied mathematical models and the results of numerical experiments are briefly analyzed.     

Probing molecular-level transformations of dissolved organic matter: insights on photochemical degradation and protozoan modification of DOM from electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry

Molecular-level characterization of natural organic matter (NOM) has been elusive due to the inherent complexity of natural organic mixtures and to the fact that individual components are often polar and macromolecular. Electrospray ionization (ESI) is a “soft” ionization technique that ionizes polar compounds from aqueous solution prior to injection into a mass spectrometer. The highest resolution and mass accuracy of compounds within NOM have been achieved when ESI is combined with an ultrahigh-resolution mass spectrometer such as the Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS). With this technique, individual molecules within a variety of natural organic mixtures can be detected and their elemental composition can be determined. At low mass-to-charge (m/z) ratio, the resolution is high enough to assign exact molecular formulas allowing specific components of these mixtures to be identified. In addition to molecular identification, we can now use ESI FT-ICR MS to examine molecular-level changes in different organic mixtures as a function of relevant geo-processes, such as microbial alterations and photochemistry. Here we present the results from the application of ESI FT-ICR MS to two geochemical questions: (1) the effect of photoirradiation on the molecular composition of fulvic acids and (2) the role of protozoan grazers in the modification of DOM in aquatic systems.     

Salt Diapirs, Salt Brine Seeps, Pockmarks and Surficial Sediment Creep and Slides in the Canary Channel off NW Africa

Circular to elliptical mounds in the Canary Channel with reliefs of 75 to 375 m and diameters of 4 to 8 km partially surrounded by moats with reliefs of 25 to 75 m, were formed by piercement of the seafloor by Mesozoic evaporites. Several long gullies, < 1km wide, with abrupt terminations and pockmarks associated with these mounds were probably eroded by dense brine and hydrocarbon seeps. The salt brines that eroded the gullies were formed where salt diapirs intersect the seafloor, or in the subsurface by circulating ground water heated by igneous activity along the Canary Ridge. If the brines originated in the subsurface they reached the seafloor along faults. Displacement of the surficial sediments by sliding and creep is probably the result of the expulsion of hydrocarbons and/or vertical motion of the Mesozoic evaporites. Microtopographic features along or near the east flank of the Canary Ridge are the creation of uplift of the ridge, hydrothermal activity, mass wasting processes and turbidity currents.     

Phototoxicity of pyrene and benzo[a]pyrene to embryo-larval stages of the Pacific oyster Crassostrea gigas

There is a growing body of evidence to suggest that certain polycyclic aromatic hydrocarbons (PAHs) pose a greater hazard to aquatic organisms than previously demonstrated, due to their potential to cause photo-induced toxicity when exposed to ultraviolet (UV) radiation. The consequences of photo-induced toxicity are reported here for embryo-larval stages of the pacific oyster Crassostrea gigas, following exposure to pyrene and benzo[a]pyrene. During laboratory investigations, significant increases in toxicity were observed in the presence of environmentally attainable levels of UV-radiation, compared with embryos exposed to PAH alone, at levels previously deemed to have little acute biological effect. The phototoxicity of pyrene and benzo[a]pyrene completely inhibited the development to the D-shell larval stage when embryos were simultaneously exposed to 5 microg l(-1) PAH and ultraviolet light (UVB = 6.3 +/- 0.1 microW/cm2 and UVA = 456.2 +/- 55 microW/cm2). A linear relationship was also demonstrated for benzo[a]pyrene phototoxicity with decreasing UV light intensity.     

Uncertainty in predictions of oil spill trajectories in open sea

A method is introduced to calculate and to account for the uncertainties in the predictions of oil spill trajectories using a classic oil spill model. The method considers the output of the oil spill model as a function of random variables, which are the input parameters, and calculates the standard deviation of the output results which gives a measure of the uncertainty of the model given the uncertainties of the input parameters.Instead of a single trajectory that is calculated by the oil spill model using the mean values of the parameters, a band of trajectories can be defined when various simulations are done taking into account the uncertainties of the input parameters. This band of trajectories defines envelopes of the trajectories that are likely to be followed by the spill given the uncertainties of the input.The method is applied to an oil spill that occurred in open sea near Madeira Islands, in the Atlantic Ocean, in December 1989. The simulations allow the understanding of how a change in the wind direction drove the spill towards the Islands.The envelope of likely trajectories that is obtained with the uncertainty modelling shows a band of trajectories that is in better agreement with the observations than the single trajectory simulated by the oil spill model, based on mean parameters.     

Experimental investigation of forces and geometry of a net cage in uniform flow

A scale model of a flexible circular net with different weights attached to the bottom was tested in a flume tank. Global forces and net deformation were measured for different steady current velocities. Three different sizes of bottom weights were used in the tests. The results from these tests are presented and discussed with the emphasis on the dependency between the forces and the geometry. Comparison is also made to empirical based formulas for calculation of drag and lift forces on net structures. Findings show that i) the forces on, and deformation of a flexible net structure are mutually highly dependent on each other; ii) estimates of global forces on a flexible net structure calculated using simple drag formulas derived from stiff net panel experiments give large errors when compared to experimental measurements; iii) numerical models taking into account the dependency between force and deformation should be used to obtain accurate estimates of forces on flexible net structures; and iv) the forces on a flexible net structure are dependent on Reynolds number, and their dependency are similar to that of a regular cylinder.