Bioavailability and bacterial degradation rates of dissolved organic matter in a temperate coastal area during an annual cycle

The bioavailability and bacterial degradation rates of dissolved organic matter (DOM) were determined over a seasonal cycle in Loch Creran (Scotland) by measuring the decrease in dissolved organic carbon (DOC), nitrogen (DON) and phosphorous (DOP) concentrations during long-term laboratory incubations (150 days) at a constant temperature of 14 °C. The experiments showed that bioavailable DOC (BDOC) accounted for 29 ± 11% of DOC (average ± SD), bioavailable DON (BDON) for 52 ± 11% of DON and bioavailable DOP (BDOP) for 88 ± 8% of DOP. The seasonal variations in DOM concentrations were mainly due to the bioavailable fraction. BDOP was degraded at a rate of 12 ± 4% d^– 1 (average ± SD) while the degradation rates of BDOC and BDON were 7 ± 2% d^– 1 and 9 ± 2% d^– 1 respectively, indicating a preferential mineralization of DOP relative to DON and of DON relative to DOC. Positive correlations between concentration and degradation rate of DOM suggested that the higher the concentration the faster DOM would be degraded. On average, 77 ± 9% of BDOP, 62 ± 14% of BDON and 49 ± 19% of BDOC were mineralized during the residence time of water in Loch Creran, showing that this coastal area exported C-rich DOM to the adjacent Firth of Lorne. Four additional degradation experiments testing the effect of varying temperature on bioavailability and degradation rates of DOM were also conducted throughout the seasonal cycle (summer, autumn, winter and spring). Apart from the standard incubations at 14 °C, additional studies at 8 °C and 18 °C were also conducted. Bioavailability did not change with temperature, but degradation rates were stimulated by increased temperature, with a Q₁₀ of 2.6 ± 1.1 for DOC and 2.5 ± 0.7 for DON (average ± SD).     

Drainage response to Arabia–Eurasia collision: Insights from provenance examination of the Cyprian Kythrea flysch (Eastern Mediterranean Basin)

The Cenozoic geodynamics of the north‐eastern Mediterranean Basin have been dominated by the subduction of the African Plate under Eurasia. A trench‐parallel crustal‐scale thrust system (Misis–Kyrenia Thrust System) dissects the southern margin of the overriding plate and forms the structural grain and surface expression of northern Cyprus. Late Eocene to Miocene flysch of the Kythrea (De?irmenlik) Group is exposed throughout northern Cyprus, both at the hanging‐wall and foot‐wall of the thrust system, permitting access to an extensive Cenozoic sedimentary record of the basin. We report the results of a combined examination of detrital zircon and rutile U–Pb geochronology (572 concordant ages), coupled with Th/U ratios, Hf isotopic data and quantitative assessment of grain morphology of detrital zircon from four formations (5 samples) from the Kythrea flysch. These data provide a line of independent evidence for the existence of two different sediment transportation systems that discharged detritus into the basin between the late Eocene and late Miocene. Unique characteristics of each transport system are defined and a sediment unmixing calculation is demonstrated and explained. The first system transported almost exclusively North Gondwana‐type, Precambrian‐aged detrital zircon sourced from siliciclastic rock units in southern Anatolia. A different drainage system is revealed by the middle to late Miocene flysch sequence that is dominated by Late Cretaceous–Cenozoic‐aged detrital zircon, whose age range is consistent with the magmatic episodicity of southeast Anatolia, along the Arabia–Eurasia suture zone. Deposition of these late Miocene strata took place thereupon closure of the Tethyan Seaway and African–Eurasian faunal exchange, and overlap in time with a pronounced uplift of eastern Anatolia. Our analytical data indicate the onset of prominent suture‐parallel sediment transport from the collision zone of south‐eastern Anatolia into the Kyrenia Range of northern Cyprus, marking the drainage response to the continental collision between Arabia and Eurasia.     

High-Pressure Melting of Eclogite and the P-T-X History of Tonalitic to Trondhjemitic Zoisite-Pegmatites, Munchberg Massif, Germany

Zoisite-bearing high-pressure pegmatites from the MünchbergMassif, Germany, provide an excellent example of the characteristicsof the onset of metabasite melting at eclogite-facies conditions.The pegmatites were derived by partial melting of a mid-oceanridge basalt (MORB)-like eclogite at T 680°C/2·3GPa to 750°C/3·1 GPa, which produced small amountsof tonalitic to trondhjemitic melt. The melt concentrated locallyin isolated, small melt pockets and crystallized primary zoisiteas liquidus phase at P 2·3 GPa/680°C to 2·1GPa/750°C. Compositional zoning of pegmatite zoisite recordsan ensuing multi-stage uplift history with successive, discretecrystallization events at 1·4 ± 0·2 GPa/650–700°Cand 1·0 ± 0·1 GPa/620–650°C.Resorption textures indicate reheating and thermal perturbationof the whole system prior to each successive crystallizationevent. Final solidification of zoisite-pegmatites occurred at0·9 ± 0·1 GPa/620–650°C. Thedata suggest that isolated melt + zoisite crystal mush pocketsformed an integral part of the eclogite throughout uplift frommelt formation at T 680°C/2·3 GPa to 750°C/3·1GPa to final solidification at 0·9 GPa/620–630°C;that is, over a depth range of 45–60 km. The entire pegmatite-formingprocess was probably fluid conserving: fluid present duringmelt formation was trapped by fully or nearly water-saturatedsiliceous melts, whereas fluid liberated during pegmatite crystallizationinteracted with dehydrated eclogite-facies assemblages to formamphibolite-facies hydrous minerals. A set of empirical D^{melt/eclogite}values based on mean zoisite-pegmatite and eclogite compositionwere used to model the onset of partial high-pressure meltingof metabasites. KEY WORDS: adakite; high-pressure melting; pegmatite; trondhjemite; zoisite     

Reconstruction of the prograde PT history of high-P migmatitic paragneisses via melt-reintegration approach and thermodynamic modelling (Allochthonous Complexes,NW Iberian Massif)

The Upper Units of the allochthonous complexes of the NW Iberian Massif constitute a terrane with continental affinity. They represent the vestiges of a Cambrian magmatic arc developed in the periphery of Gondwana (West African Craton) which was involved in the Devonian Variscan collision, undergoing high-P, high-T metamorphism. This includes ultramafic rocks, high-P mafic rocks (eclogites and granulites) and high-P migmatitic paragneisses. The latter rocks show an extensive migmatization with the leucosomes oriented parallel to the regional foliation. The migmatitic paragneisses are composed of garnet, kyanite, biotite, quartz, plagioclase, K-feldspar, rutile and Ti-hematite. Thermodynamic modelling using the measured bulk composition in the NCKFMASTHO system indicates metamorphic peak conditions of ~15 kbar and ~800 to 835°C, followed by a significant cooling. The prograde evolution is assessed by means of a melt-reintegration approach, using the composition of the garnet and its inclusions. An appropriate composition of liquid is added to the measured bulk composition to emulate the pre-melting bulk composition. Modelling of this melt-reintegrated composition allows to identify a colder high-P episode below ~500°C. Zircon crystals extracted from the leucosomes show overgrowths crystallized from the partial melt at c. 389 Ma (U–Pb system). The P–T–t path proposed reveals a subduction of the peri-Gondwanan arc-derived section down to mantle depths. An isobaric heating stage occurred as a result of residence at great depths and/or inception of a transient oceanic basin at c. 395 Ma. The ensuing near-isothermal exhumation occurred due to the extension related to the inception of the basin, reaching the thermal peak shortly before c. 389 Ma. Subsequent cooling is related to the underthrusting of colder oceanic and transitional crust below the HP-HT Upper Units.