The age of SNC meteorites and the antiquity of the Martian surface

We report new Sm-Nd, Lu-Hf, and Pb-Pb mineral and whole-rock isotope data for the basaltic shergottite Zagami, as well as Pb-Pb whole-rock isotope data for the basaltic shergottite Los Angeles, the lherzolitic shergottite Dar-al-Gani 476 (DaG 476), and the clinopyroxenite Nakhla. In agreement with previous findings, our new Sm-Nd and Lu-Hf mineral ages on the Martian meteorite Zagami are young (155 and 185 Ma, respectively). The ²⁰⁷Pb/²⁰⁶Pb-²⁰⁴Pb/²⁰⁶Pb compositions of the insoluble fractions of shergottites (Zagami, Los Angeles, and literature data for Shergotty and EETA79001) form an excellent alignment indicative of a 4.0 Ga crystallization age. The range of Pb isotope compositions observed in the leachates of these samples attests to negligible contamination of the shergottites by terrestrial Pb and argues against mixing relationships. The age of 4.048 ± 0.017 Ga (MSWD = 1.5) provided by the Pb isotope compositions of the Zagami whole-rock and residues is therefore taken to date the crystallization of this rock, which, so far, was believed to be only ∼ 180 Ma old. Based on this result, we argue that the lithosphere of Mars is extremely old and that most mineral ages were reset recently by acidic aqueous solutions percolating through the Martian surface. This interpretation is consistent with photographic interpretations of erosional features on Mars. It also relieves the constraint imposed by the presence of anomalies of ¹⁴²Nd and ¹⁸²W (both products of extinct radioactive nuclides) that the Martian mantle should have preserved primordial isotopic heterogeneities, thus allowing for the planet interior to be actively convecting.     

Estimating phytolith influx in lake sediments

So far, no phytolith extraction protocols have been tested for accuracy and repeatability. Here we aim to display a phytolith extraction method combining the strengths of two widely used protocols, supplemented with silica microspheres as exogenous markers for quantifying phytolith concentrations. Phytolith concentrations were estimated for samples from two sedimentary sequences in which numerical age–depth models make it possible to calculate phytolith influxes (phytolith numbers per cm²per yr). Analysis of replicates confirmed the statistical robustness, the repeatability and the very few biases of our extraction technique for small phytoliths, since the relationship between grass silica short cells and microspheres was kept stable. Furthermore, we demonstrated that silica microspheres are robust exogenous markers for estimating phytolith concentrations. The minimum number of items (i.e., phytoliths plus silica microspheres) that must be counted to estimate phytolith concentrations and thus influxes depends on the ratio of phytoliths to microspheres (R) and is minimized when R = 1. Nevertheless, we recommend using ratios R ≤ 1 in order to avoid having the counting process become excessively time-consuming, because microspheres are easier to identify and count than phytoliths.     

An assessment of the mixed layer salinity budget in the tropical Pacific Ocean. Observations and modelling (1990–2009)

This paper investigates mechanisms controlling the mixed-layer salinity (MLS) in the tropical Pacific during 1990–2009. We use monthly 1°?×?1° gridded observations of salinity, horizontal current and fresh water flux, and a validated ocean general circulation model with no direct MLS relaxation in both its full resolution (0.25° and 5 days) and re-sampled as the observation time/space grid resolution. The present study shows that the mean spatial distribution of MLS results from a subtle balance between surface forcing (E???P, evaporation minus precipitation), horizontal advection (at low and high frequencies) and subsurface forcing (entrainment and mixing), all terms being of analogous importance. Large-scale seasonal MLS variability is found mainly in the Intertropical and South Pacific Convergence Zones due to changes in their meridional location (and related heavy P), in the North Equatorial Counter Currents, and partly in the subsurface forcing. Maximum interannual variability is found in the western Pacific warm pool and in both convergence zones, in relation to El Niño Southern Oscillation (ENSO) events. In the equatorial band, this later variability is due chiefly to the horizontal advection of low salinity waters from the western to the central-eastern basin during El Niño (and vice versa during La Niña), with contrasted evolution for the Eastern and Central Pacific ENSO types. Our findings reveal that all terms of the MLS equation, including high-frequency (<1 month) salinity advection, have to be considered to close the salinity budget, ruling out the use of MLS (or sea surface salinity) only to directly infer the mean, seasonal and/or interannual fresh water fluxes.     

Raman spectroscopy of shocked enstatite-rich meteorites

We present Raman patterns of enstatite in different classes of enstatite-rich chondrites and achondrites of various shock levels as previously reported from petrographic observations and X-ray diffraction analyses. Thin sections or mineral separates of four enstatite chondrites (LaPaz Icefield [LAP] 02225, MacAlpine Hills [MAC] 02837, Pecora Escarpment [PCA] 91020, and Itqiy), three aubrites (Larkman Nunatak [LAR] 04316, Khor Temiki, and Allan Hills [ALH] 84008), and a ureilite (Sayh al Uhaymir [SaU] 559) were examined by laser Raman spectroscopy. We find that the frequencies of fundamental Raman peaks of enstatites from the chondrites and aubrites deviate by ≤2 cm⁻¹ from the values for unshocked enstatite. This small difference implies a negligible effect of shock metamorphism on peak positions. Significant differences (<6 cm⁻¹) for peak positions are found for the pyroxenes of SaU 559 and may be attributed to minor substitution of Fe and Ca for Mg. Linear regressions of peak widths of enstatite chondrites against their established shock stages show a strong positive correlation for each mode (r² > 0.94). From this linear relationship, the 343 and 1014 cm⁻¹ peaks of the aubrites coincide with S4 determined from petrography. For Itqiy, we find S4–5, while the shock levels of SaU 559 exceed the petrologic scheme (S1–6), suggesting that the ureilite might have sustained multiple shock events or have been deformed in a high-pressure environment. Alternatively, for Itqiy (peak 343 cm⁻¹) and SaU 559 (all peaks) enstatites, minor substitutions of Fe and Ca for Mg may have further broadened their peak widths.     

The effect of dense cores on the structure and evolution of Jupiter and Saturn

We have calculated evolutionary and static models of Jupiter and Saturn with homogeneous solar composition mantles and dense cores of material consisting of solar abundances of SiO₂, MgO, Fe, and Ni. Evolutionary sequences for Jupiter were calculated with cores of mass 2, 4, 6, and 8% of the Jovian mass. Evolutionary sequences for Saturn were calculated with cores of mass 16, 18, 20, and 22% of total mass. Two envelope mixtures, representative of the solar abundances were used: X (mass fraction of hydrogen) = 0.74, Y (mass fraction of helium) = 0.24 and X = 0.77 and Y = 0.21. For Jupiter, the observations of the temperature at 1 bar pressure (T_1bar), radius and internal luminosity were best fit by evolutionary models with a core mass of ～6.5% and chemical composition of X = 0.77, Y = 0.21. The calculated cooling time for Jupiter is approximately 4.9 × 10⁹ years, which is consistent, within our error bars, with the known age of the solar system. For Saturn, the observations of the radius, internal luminosity and T_1BAR can be best fit by evolutionary models with a core mass of ～21% and chemical composition of X = 0.77, Y = 0.21. The cooling time calculated for Saturn is approximately 2.6 × 10⁹ years, almost a factor 2 less than the present age of the solar system. Static models of Jupiter and Saturn were calculated for the above chemical compositions in order to investigate the sensitivity of the calculated gravitational moments, J₂ and J₄, to the mass of the dense core, T_1BAR and hydrogen/helium ratio. We find for Jupiter that a model having a core mass of approximately 7% gives values of J₂, J₄, and T_1BAR that are within observational limits, for the mixture X = 0.77, Y = 0.21. The static Jupiter models are completely consistent with the evolutionary results. For Saturn, the quantities J₂, J₄, and J₆ determined from the static models with the most probable T_1BAR of 140°K, using modeling procedures which result in consistent models for Jupiter, are considerably below the observed values.     

The Meteoritical Bulletin,No. 103

Meteoritical Bulletin 103 contains 2582 meteorites including 10 falls (Ardón, Demsa, Jinju, Kri?evci, Kuresoi, Novato, Tinajdad, Tirhert, Vicência, Wolcott), with 2174 ordinary chondrites, 130 HED achondrites, 113 carbonaceous chondrites, 41 ureilites, 27 lunar meteorites, 24 enstatite chondrites, 21 iron meteorites, 15 primitive achondrites, 11 mesosiderites, 10 Martian meteorites, 6 Rumuruti chondrites, 5 ungrouped achondrites, 2 enstatite achondrites, 1 relict meteorite, 1 pallasite, and 1 angrite, and with 1511 from Antarctica, 588 from Africa, 361 from Asia, 86 from South America, 28 from North America, and 6 from Europe. Note: 1 meteorite from Russia was counted as European. The complete contents of this bulletin (244 pages) are available on line. Information about approved meteorites can be obtained from the Meteoritical Bulletin Database (MBD) available on line at http://www.lpi.usra.edu/meteor/ .     

The Meteoritical Bulletin,No. 105

Meteoritical Bulletin 105 contains 2666 meteorites including 12 falls (Aouinet Legraa, Banma, Buritizal, Ejby, Kamargaon, Moshampa, Mount Blanco, Murrili, Osceola, Sariçiçek, Sidi Ali Ou Azza, Stubenberg), with 2244 ordinary chondrites, 142 HED achondrites, 116 carbonaceous chondrites, 37 Lunar meteorites, 20 enstatite chondrites, 20 iron meteorites, 20 ureilites, 19 Martian meteorites, 12 Rumuruti chondrites, 10 primitive achondrites, 9 mesosiderites, 5 angrites, 4 pallasites, 4 ungrouped achondrites, 2 ungrouped chondrites, 1 enstatite achondrite, and 1 relict meteorite, and with 1545 from Antarctica, 686 from Africa, 245 from Asia, 147 from South America, 22 from North America, 14 from Europe, 5 from Oceania, 1 from unknown origin. Note: 5 meteorites from Russia were counted as European. It also includes a list of approved new Dense Collection Areas and a nomenclature of the Aletai (IIIE‐an) iron meteorites from Xinjiang, China.     

The Meteoritical Bulletin,no. 108

Meteoritical Bulletin 108 contains 2141 meteorites including 12 falls (Aguas Zarcas, Benenitra, Jalangi, Komaki, Ksar El Goraane, Mhabes el Hamra, Natun Balijan, Oued Sfayat, Shidian, Taqtaq‐e Rasoul, Tocache, Viñales), with 1640 ordinary chondrites, 149 carbonaceous chondrites, 134 HED achondrites, 45 lunar meteorites, 38 ureilites, 27 iron meteorites, 23 Martian meteorites, 22 primitive achondrites, 19 Rumuruti chondrites, 15 mesosiderites, 10 enstatite chondrites, 7 ungrouped achondrites, 4 pallasites, 4 ungrouped chondrites, and 4 angrites. Nine hundred and nine meteorites are from Africa, 747 from Antarctica, 279 from South America, 148 from Asia, 29 from North America, 18 from Oceania, 6 from Europe (including 2 from Russia), and 5 from unknown locations.