The Increase of Biogenic Sulfate Aerosol and Particle Number in Marine Atmosphere over the Northwestern North Pacific

During a cruise aboard the R/V Hakuho-maru in the northwestern North Pacific in the summer of 1998 the particle number concentrations and the major ionic components of size fractionated aerosols were measured to investigate the aerosol produced by marine biological activity. Continuous low concentrations of nitrate (<1.8 nmol m⁻³), similar to the marine air background level, were found over the northwestern North Pacific (40–45°N) and the Sea of Okhotsk (44–45°N). Over the Sea of Okhotsk, a high concentration of chlorophyll-a (5.4 mg m⁻³) in seawater was observed, and atmospheric concentrations of non sea-salt (nss-) sulfate (44 nmol m⁻³), methane sulfonic acid (MSA) (1.8 nmol m⁻³) and particle number in the size range of 0.1 < D < 0.5 μm (199 cm⁻³) were found to be 9, 7, and 2 times, respectively, higher than those in the background marine air. The increase in particle number concentrations mainly in the size range of 0.2 < D < 0.3 μm was likely caused by the increase of biogenic sulfate over the high productive region of the Sea of Okhotsk. In humid air conditions (R.H. > 96%), the increased biogenic sulfate that condensed the large amount of water vapor would not have sufficient solute mass to activate as cloud condensation nuclei (CNN) and would remain as aerosol particles in the marine air with frequent sea-fogs over the high productive region. Biogenic sulfate originating from dimethyl sulfide (DMS) would gradually grow into the CCN size and continuously supply a great number of CCN to the marine air in the northwestern North Pacific. This revised version was published online in July 2006 with corrections to the Cover Date.     

The Effects of Inner- and Outer-Layer Turbulence in a Convective Boundary Layer on the Near-Neutral Inertial Sublayer Over an Urban-Like Surface

A large-eddy simulation of the atmospheric boundary layer, large enough to contain both an urban surface layer and a convective mixed layer, was performed to investigate inner-layer and outer-layer scale motions. The objective was to determine the applicability of Monin–Obukhov similarity theory to inner-layer motions, to investigate the influence of outer-layer motions on surface-layer structure, as well as to assess the interaction of the two scales of motion. The urban surface roughness consisted of square-patterned cubic buildings of dimension H (40 m). A spatial filter was used to decompose the two scales in the inertial sublayer. The horizontal square filter of size 10H was effective in separating the inner-layer (surface-layer height ≈ 2 H) and outer-layer scales (boundary-layer height δ ≈ 30H), where the Reynolds stress contribution of the inner layer dominates in the logarithmic layer (depth 2H). Similarity coefficients for velocity fluctuations were successfully determined for inner-layer motions in the surface layer, proving the robustness of Monin–Obukhov similarity for surface-layer turbulence. The inner-layer structures exhibit streaky structures that have similar streamwise length but narrower spanwise width relative to the streamwise velocity fluctuation field, consistent with observations from an outdoor scale model. The outer-layer motions to some extent influence the location of ejections and sweeps through updraft and downdraft motions, respectively, thus, disturbing the homogeneity and similarity of inner-layer motions. Although the horizontal averages of the variances and covariance of motions reveal that the Reynolds stresses are dominated by inner-layer structures, the localized influence of the interaction of outer-layer horizontal and inner-layer vertical motions on the Reynolds stress is not insignificant.     

A web-based real-time and full-resolution data visualization for Himawari-8 satellite sensed images

It has been almost four decades since the first launch of geostationary meteorological satellite by Japan Meteorological Agency (JMA). The specifications of the geostationary meteorological satellites have shown tremendous progresses along with the generations, which are now entering their third generation. The third-generation geostationary meteorological satellites not only yield basic data for weather monitoring, but also globally observe the Earth’s environment. The development of multi-band imagers with improved spatial resolution onboard the third-generation geostationary meteorological satellites brings us meteorological data in larger size than those of the second-generation ones. Thus, new techniques for domestic and world-wide dissemination of the observational big data are needed. In this paper, we develop a web-based data visualization for Himawari-8 satellite sensed images in real time and with full resolution. This data visualization is supported by the ecosystems, which uses a tiled pyramid representation and parallel processing technique for terrain on an academic cloud system. We evaluate the performance of our techniques for domestic and international users on laboratory experiments. The results show that our data visualization is suitable for practical use on a temporal preview of observation image data for the domestic users.     

Stable isotope and chemical composition of pearls: Biomineralization in cultured pearl oysters in ago bay, Japan

The δ¹⁸O, δ¹³C and trace element composition of pearls collected from Ago Bay, Japan, were investigated in order to evaluate biomineralization in the cultured pearl oyster (Pinctada fucata martensii). The oxygen isotopic data suggest that the pearls were produced around 23–24°C, mainly in June to early July, which is consistent with their occurrence in the field. Therefore the pearls were produced under or close to isotopic equilibrium conditions, although they showed high calcification rates (higher than 0.2–1.0 g cm^{− 2}yr⁻¹) under which, for example, coral skeletons (calcification rate ∼0.28 g cm^{− 2}yr⁻¹) often show non-equilibrium isotope partitioning. The δ¹³C values were ∼− 2.9‰ lower than those calculated for offshore waters under equilibrium conditions. This may be due to low-δ¹³C bottom waters resulting from the degradation of organic matter (OM) or to a contribution of low-δ ¹³C food. In the latter case, a simple mass balance calculation gives a respiration component of 14%. Twelve trace elements of bulk pearl samples were classified into four groups on the basis of their enrichment/depletion patterns relative to seawater and inter-element relationships: group 1, Co, Cr, Pb; group 2, Ba, Cs, U; group 3, Cu, Sn, V, and group 4, Mn, Rb, Mo. Comparison with coral skeletons suggests that Ba and Mn (groups 2 and 4) were definitely much enriched in proteinaceous OM relative to aragonite crystals in pearls and that V (group 3) in pearls showed only slight enrichment in the organicrich layer. By contrast, the other elements showed small differences between both layers (enrichment factor of <3), suggesting that these elements occur largely in aragonite crystals.     

Form Drag Caused by Topographically Forced Waves in a Barotropic β Channel: Effect of Higher Mode Resonance

The relationship between form drag and the zonal mean velocity of steady states is investigated in a very simple system; a barotropic quasi-geostrophic β channel with sinusoidal topography. When a steady solution is calculated by the modified Marquardt method, keeping the zonal mean velocity constant as a parameter, the characteristic of the solution changes at a phase speed of a wave with a wavenumber higher than that of the bottom topography. For velocities smaller than this critical value, there exists a stable quasi-linear solution similar to the linear solution. For larger velocities, there exist three solutions whose form drag is very large. In addition, the resonant velocity of the mode, whose wavenumber is the same as the bottom topography, has no effect on these solutions. When the quiescent fluid is accelerated by a constant wind stress, acceleration stops around the critical velocity for a wide range of the wind stress. If the wind stress is too large for the acceleration to stop, the zonal current speed continues to increase infinitely. It is implied that the zonal velocity of equilibrium is mainly determined, not by the wind stress, but by the amplitude of the bottom topography and the viscosity coefficient.     

The layered structure of lunar maria: Identification of the HF-radar reflector in Mare Serenitatis using multiband optical images

Comparison of the Lunar Radar Sounder (LRS) data to the Multiband Imager (MI) data is performed to identify the subsurface reflectors in Mare Serenitatis. The LRS is FM-CW radar (4–6 MHz) and the 2 MHz bandwidth leads to the range resolution of 75 m in a vacuum, whereas the sampling interval in the flight direction is about 75 m when an altitude of the spacecraft with polar orbit is nominal (100 km). Horizontally continuous reflectors were clearly detected by LRS in limited areas that consist of about 9% of the whole maria. The typical depth of the reflectors is estimated to be a few hundred meters. Layered structures of mare basalts are also discernible on some crater walls in the MI data of the visible bands (VIS). The VIS range has nine wavelengths of 415, 750, 900, 950, and 1000 nm, and their spatial resolution is 20 m/pixel at a nominal altitude. The stratigraphies around Bessel and Bessel-H craters in Mare Serenitatis are examined in this paper. It was revealed that the subsurface reflectors lie on the boundaries between basalt units with different chemical compositions. In addition, model calculations using the simplified radar equation indicate that the subsurface reflectors are not compositional interfaces but layer boundaries with a high-porosity contrast. These results suggest that the detected reflectors in Mare Serenitatis are regolith accumulated during so long hiatus of mare volcanisms enough for chemical composition of magma to change, not instantaneously. Therefore combination of the LRS and MI data has a potential to reveal characteristics of a series of magmatism forming each lithostratigraphic unit in Mare Serenitatis and other maria.     

Impact of climate change on runoff from a mid‐latitude mountainous catchment in central Japan

Hydrologic balance in high‐altitude, mid‐latitude mountain areas is important in terms of the water resources available to associated lowlands. This study examined how current and historical shifts in precipitation (P) patterns and concurrent increases in temperature (T) affected runoff (Q) and other hydrologic components in a mid‐latitude mountain catchment of central Japan, using a combination of long‐term data and a simplified hydrologic model, along with their stochastic treatment. The availability of intensive meteorological and hydrological data from the period 1997–2001 allowed the derivation of key relationships for the current climate that tie the forcing term to the parameters or state variables. By using the data recorded in the period 1965–2001, the force for driving the historical simulation was generated. Based on this model and historical shifts in P and T, the probability density functions of Q (pdf(Q)) was computed. A main novelty in this study is that such a stochastic representation, which is useful for considering the influence of projected shifts in environmental factors on the hydrologic budget, was provided. Despite the large increase in the rate of T in winter and spring, pdf(Q) in spring and summer varied appreciably during the time studied mainly because of an increase in snowmelt. An interannual change in whole‐year Q was robust to shifts in T because while Q in spring increased, in summer it decreased, implying a crucial effect of global warming on mountain hydrologic regimes is change in the timing of Q. Copyright © 2009 John Wiley & Sons, Ltd.     

Determination of Selenium in Twenty-Eight Geological Reference Materials by Atomic Absorption Spectrometry

Twenty-eight geological reference samples have been analysed for selenium using atomic absorption spectrometry with hydride generation and quartz cell atomizer and/or with solvent extraction and carbon tube atomizer. Data are presented for 5 CCRMP, 6 USGS, 3 NBS, 6 NIM and 8 GSJ reference materials.     

Single particle analysis of oceanic suspended matter during the SEEDS II iron fertilization experiment

Suspended particles collected from surface seawater during the SEEDS II (Subarctic Iron Experiment for Ecosystem and Dynamics Study II) experiment were analyzed individually using an electron probe X-ray micro analyzer and characterized by size and elemental composition. Their numbers, relative abundances, and relative particle volume all showed clear differences between samples collected inside vs. outside the phytoplankton bloom that developed following the addition of iron. Throughout the study, Si-rich, Ca-rich and Organic particles were dominant and their number increased inside the fertilized patch; these particles accounted for 21%, 13% and 58% of the particles examined, respectively. Si-rich or Ca-rich particles commonly consisted of fragments of diatom frustules and coccolithophorids. There was consistently greater percentage of Ca-rich particles and lower percentage of Si-rich particles inside the patch than outside of it in number, but both types of these particles apparently occupied a larger volume inside the patch than outside of it. Organic particles, that showed having peaks in smaller diameter particles, increased apparently inside the patch with time after iron fertilization. The Organic particles had a more diverse mixture of both bio-related and crustal trace elements than the other types of particles. These results suggest that the increase in suspended particles following the iron enrichment was due to a combination of detrital material and live phytoplankton.     

Geology of the Gorny Altai subduction–accretion complex, southern Siberia: Tectonic evolution of an Ediacaran–Cambrian intra-oceanic arc-trench system

The Gorny Altai region in southern Siberia is one of the key areas in reconstructing the tectonic evolution of the western segment of the Central Asian Orogenic Belt (CAOB). This region features various orogenic elements of Late Neoproterozoic–Early Paleozoic age, such as an accretionary complex (AC), high-P/T metamorphic (HP) rocks, and ophiolite (OP), all formed by ancient subduction–accretion processes. This study investigated the detailed geology of the Upper Neoproterozoic to Lower Paleozoic rocks in a traverse between Gorno-Altaisk city and Lake Teletskoy in the northern part of the region, and in the Kurai to Chagan-Uzun area in the southern part. The tectonic units of the studied areas consist of (1) the Ediacaran (=Vendian)–Early Cambrian AC, (2) ca. 630 Ma HP complex, (3) the Ediacaran–Early Cambrian OP complex, (4) the Cryogenian–Cambrian island arc complex, and (5) the Middle Paleozoic fore-arc sedimentary rocks. The AC consists mostly of paleo-atoll limestone and underlying oceanic island basalt with minor amount of chert and serpentinite. The basaltic lavas show petrochemistry similar to modern oceanic plateau basalt. The 630 Ma HP complex records a maximum peak metamorphism at 660 °C and 2.0 GPa that corresponds to 60 km-deep burial in a subduction zone, and exhumation at ca. 570 Ma. The Cryogenian island arc complex includes boninitic rocks that suggest an incipient stage of arc development. The Upper Neoproterozoic–Lower Paleozoic complexes in the Gorno-Altaisk city to Lake Teletskoy and the Kurai to Chagan-Uzun areas are totally involved in a subhorizontal piled-nappe structure, and overprinted by Late Paleozoic strike-slip faulting. The HP complex occurs as a nappe tectonically sandwiched between the non- to weakly metamorphosed AC and the OP complex. These lithologic assemblages and geologic structure newly documented in the Gorny Altai region are essentially similar to those of the circum-Pacific (Miyashiro-type) orogenic belts, such as the Japan Islands in East Asia and the Cordillera in western North America. The Cryogenian boninite-bearing arc volcanism indicates that the initial stage of arc development occurred in a transient setting from a transform zone to an incipient subduction zone. The less abundant of terrigenous clastics from mature continental crust and thick deep-sea chert in the Ediacaran–Early Cambrian AC may suggest that the southern Gorny Altai region evolved in an intra-oceanic arc-trench setting like the modern Mariana arc, rather than along the continental arc of a major continental margin. Based on geological, petrochemical, and geochronological data, we synthesize the Late Neoproterozoic to Early Paleozoic tectonic history of the Gorny Altai region in the western CAOB.