On lipid surface films on the sea. I. A simple method for sampling and studies of composition

A method for collection of surface films on the sea has been developed and tested at various places along the Swedish West Coast. Considerable amounts of lipids on the sea surface were found even when no seaslicks were observed. Triglycerides, free fatty acids, and wax esters are the dominating constituents, and there are characteristic deviations in the fatty-acid patterns compared to the corresponding lipids dissolved in the sub-surface water. Organochlorine residues, phthalic acid esters and heavy metals also occur in considerable amounts.     

The importance and limitations of social networks and social identities for labour market integration: The case of Ghanaian immigrants in Bergen,Norway

Whereas refugees and larger immigrant groups’ integration in the Norwegian labour market has received considerable research attention, less is known about the labour market integration of small, non-refugee immigrant groups from West African countries such as Ghana. The purpose of the article is to examine the role of social networks and social identities for the differentiated labour market integration outcomes among Ghanaian immigrants in the city of Bergen. Based on data produced through in-depth interviews, participant observation and informal conversations, the authors argue that Ghanaian immigrants’ ability to obtain jobs is determined by more than simply having the appropriate educational and language qualifications, and largely depends on having favourable social identities and being embedded in social networks beyond the Ghanaian immigrant community. They find that those who mainly relied on Ghanaian networks found it difficult to circumvent labour market hindrances and they predominantly obtained menial jobs. The authors conclude that Norwegian job-seekers networks played a crucial role in the immigrants’ opportunities and for potential Norwegian employers’ perception of their employability, especially in professional and semi-professional jobs.     

Slow Crack Propagation and Slip Correlations

— The propagation of an interfacial crack through a weak plane of a transparent Plexiglas block is studied experimentally. The toughness is controlled artificially by a sand blasting procedure, and fluctuates locally in space like uncorrelated random noise. The block is fractured in mode I at low speed (10^?7?10^?4 m/s). The crack front is observed optically with a microscope and a high resolution digital camera. During the propagation, the front is pinned by micro-regions of high toughness and becomes rough. Roughness of the crack front is analyzed in terms of self-affinity. The in-plane roughness exponent is shown to be 0.63±0.05. Experimental results are compared to a numerical model. The model reproduces the self-affine behavior of the crack front, i.e., long-range correlations of the roughness. Analogies between mode I and mode III are presented in order to discuss implications of the experimental results for creeping faults. Accordingly, correlations of the slip pattern are shown to exist over scales substantially larger than the asperity sizes.     

Simplification of a Sequential Extraction Scheme To Determine the Mobilisable Heavy Metal Pool in Soils

This investigation had the purpose of evaluating the reliability of a sequential extraction procedure according to Zeien and Brümmer (1989) which is performed routinely to analyse the distribution of heavy metals to different soil phases. Reliability was tested by two hypotheses. According to the first hypothesis an error propagation increased during a morefold extraction of heavy metals from a single soil sample to such an extend that it does not allow a statistical comparison of different analyses. This assumption was confirmed in an interlaboratory study of five participants applying the sequential extraction scheme on two different soils. The heavy metal amounts extracted by the different partners were of the same magnitude, but from the results no statistical correspondence at the 95% confidence level could be observed. The second hypothesis stated that also weak extraction agents were able to release metals from the more immobile soil fractions, especially if the amount of easily soluble metals was comparatively small. To answer this question the sequential extraction was modified by carrying out selected weak extraction steps several times. As expected the intensified extraction conditions caused a decrease of the element content within the more resistant phases. However, the additional release in the first four extraction steps of Pb, Mn, Fe, and Zn was only in the range of 5 to 10%. Furthermore, it was observed that a single EDTA extraction (step four within the sequential extraction scheme) was capable to extract the same amount of metals as the first four extraction steps of the original scheme at a variation of about 15%. From these results it was concluded that the EDTA step alone already represents a reliable pool of mobilisable metals. Thus it can be maintained that such a simple single EDTA extraction can be used to assess the environmental risk from heavy metal contaminated soils or to predict the potential heavy metal release of soil remediation processes.     

The depositional architecture and facies variability of shelf deltas in the Eocene Battfjellet Formation,Nathorst Land,Spitsbergen

Deltas are commonly classified according to their plan‐view morphology as either river‐dominated, tide‐dominated or wave‐dominated. However, most deltas form under the mixed influence of these processes, commonly with laterally varying process regimes. It has also become clear that there is a mismatch between the plan‐view morphology and internal facies composition in some deltas. Combined outcrop and subsurface data from the Eocene Battfjellet Formation, Spitsbergen, provide an example of ancient shelf deltas that formed under mixed influence. Internally, these shelf deltas are characterized by wave‐dominated facies that are normally associated with strike‐extensive, nearly linear shoreline sandstones. However, the formation comprises partially overlapping sandstone bodies of limited lateral extent (<20 km in any direction). This stacking pattern is attributed to frequent autogenic lobe switching that caused localized and rapid transgressions. Such processes typify fluvial‐dominated deltas and occur less commonly in wave‐dominated ones. Thus, there is an apparent mismatch between inferred plan‐view morphology and internal facies composition. It is argued that the Battfjellet deltas were flood‐dominated and prograded mainly during periods of high fluvial discharge. However, reworking of the fluvial‐flood facies by fair‐weather and storm waves, as well as longshore currents, resulted in a wave‐dominated facies character. Delta lobes undergoing auto‐retreat were particularly prone to reworking by basinal processes, including tidal currents. It is suggested that repeated delta progradation from inner shelf settings towards the outer shelf and shelf edge was aided by high sediment supply rather than relative falls in sea‐level as previously suggested. This interpretation is supported by: (i) the lack of major facies dislocations and extensive sub‐aerial unconformities; and (ii) an overall relative rise in sea‐level as evidenced by an overall low‐angle (0·8 to 1·2°) ascending shoreline trajectory. The latter results from the combined effect of basin subsidence, eustatic highstand and sediment compaction.     

Direct 40Ar/39Ar dating of Late Ordovician and Silurian brittle faulting in the southwestern Norwegian Caledonides

Structural data as well as U–Pb zircon and ⁴⁰Ar/³⁹Ar biotite and muscovite ages were collected from the Rolvsnes granodiorite in western Norway. The granodiorite intruded at c. 466 Ma, cooled quickly and escaped later viscous deformation. Brittle top‐to‐the‐NNW thrust faults (Set I) and WNW–ESE striking dextral strike‐slip faults (Set II) formed in a NNW–SSE transpressional regime. ⁴⁰Ar/³⁹Ar dating of synkinematic mica from both sets reveals a c. 450 Ma (Late Ordovician) age of faulting, which constrains early‐Caledonian brittle deformation. Set I and II faults are overprinted by a set of lower‐grade, variably oriented chlorite‐ and epidote‐coated faults (Set III) constraining WNW–ESE shortening. A lamprophyric dyke oriented compatibly with this stress field intruded at c. 435 Ma (Silurian), indicating that Set III formed at the onset of the Scandian Baltica–Laurentia collision. The preservation of Caledonian brittle structures indicates that the Rolvsnes granodiorite occupied a high tectonic level throughout the Caledonian orogeny.     

Experimental determination of the temperature and pressure dependence of the Fe-Mg partition coefficient for coexisting garnet and clinopyroxene

An experimental study initiated to calibrate the distribution coefficient \(K_D = \frac{{({\text{FeO}}/{\text{MgO}})_{{\text{ga}}} }}{{{\text{(FeO}}/{\text{MgO)}}_{{\text{cpx}}} }}\) in eclogites as a geothermometer has been done on (a) a mineral mis, (b) a glass of the typical tholeiite composition and (c) a series of glasses of tholeiite compositions with \(6.2 < \frac{{100{\text{Mg}}}}{{{\text{Mg}} + {\text{Fe}}^{ + + } }} < 93.\) The mineral mix was found to be unsuitable as reactant due to incomplete equilibration but the minimum K _D of the mineral mix and the K _D from glass of tholeiite composition are identical within experimental uncertainty. These data constitute a reversal of the garnet/clinopyroxene partition relationship and provide justification of the use of glass as a reactant for the project. To eliminate any uncertainty in interpretation of mineral analyses due to possible variation in Fe⁺⁺⁺/Fe⁺⁺ between runs, experiments were carried out in iron capsules on the nine tholeiite glasses, thus maintaining iron as Fe⁺⁺. Microprobe analytical techniques yielded mineral analyses of comparable accuracy to analyses of natural phases for experiments within the temperature range from 600° C to 1500° C and a pressure range from 20 kb to 40 kb. It has been shown that for \(6.2 < \frac{{100{\text{Mg}}}}{{{\text{Mg}} + {\text{Fe}}^{ + + } }} < 85\) , the bulk chemical composition does not perceptibly affect the K _D value. At 30 kb the K _D value ranges from 18.0 at 600° C to 1.45 at 1400° C, defining the linear relationship in a ln K _D vs 1/T(°K) plot. The pressure dependence of the K _D -value has been shown to be greater than previously predicted. There is a straight line relationship in ln K _D vs Pressure (Kb) between 20 and 40 kb at constant temperature (1100°C). This enables us to determine K _D =fn (T, P) and \(T(^\circ {\text{K}}) = \frac{{3686 + 28.35 \times P({\text{Kb}})}}{{\ln K_D + 2.33}}\) . This expression uniquely determines the temperature of equilibration of natural eclogites of basaltic bulk composition when the K _D ^ga,cpx is known and a pressure estimate can be given.