Mineralization of Catechol by Fenton and Photo‐Fenton Processes

Catechol is one of the most abundant phenolic components of olive mill wastewaters. In this article, the mineralization of this compound in synthetic aqueous solutions by the Fenton and photo‐Fenton processes is studied. It has been found that for 1.44 mM catechol, the total organic carbon of solutions is reduced about 94.4% at best after 60 min of Fenton treatment at optimized conditions of pH 3.0, 0.2 mM Fe²⁺, 7.09 mM H₂O₂, and 25°C. A faster and overall mineralization is attained by applying photo‐Fenton with UVA irradiation. o‐Benzoquinone, 1,2,3‐trihydroxybenzene and 1,2,4‐trihydroxybenzene were identified by GC–MS as primary quinonic and polyhydroxylated derivatives. Small amounts of generated carboxylic acids like muconic, maleic, malonic, acetic, oxalic, and formic acids were detected by ion‐exclusion chromatography. The Fe(III) complexes of these acids persist in the medium under Fenton conditions, while their photolysis by UVA light and that of other by‐products account for by the faster degradation and total mineralization achieved in the photo‐Fenton process. A reaction sequence for catechol mineralization by Fenton and photo‐Fenton involving all intermediates detected is proposed.     

Indian Summer Monsoon Rainfall Characteristics During Contrasting Monsoon Years

The present paper presents a diagnostic study of two recent monsoon years, of which one is dry monsoon year (2009) and the other is wet monsoon year (2010). The study utilized the IMD gridded rainfall data set in addition to the Reynolds SST, NCEP-NCAR reanalysis wind and temperature products, and NOAA OLR. The study revealed that the months July and August are the most crucial months to decide whether the ISMR is wet or dry. However, during July 2009, most of the Indian subcontinent received more than 60 % in the central and western coastal regions. In a wet monsoon year, about 35–45 % of rainfall is contributed during June and July in most parts of India. During these years, the influence of features in the Pacific Ocean played vital role on the Indian summer monsoon rainfall. During 2009, Pacific SST was above normal in nino regions, characteristic of the El Nino structure; however, during 2010, the nino regions were clearly below normal temperature, indicating the La Nina pattern. The associated atmospheric general circulation through equatorial Walker and regional Hadley circulation modulates the tropospheric temperature, and hence the organized convective cloud bands. These cloud bands show different characteristics in northward propagation during dry and wet years of ISMR. During a dry year, the propagation speed and magnitudes are considerably higher than during a wet monsoon year.     

The Cold Tongue in the South China Sea during Boreal Winter and Its Interaction with the Atmosphere

A distinct cold tongue has recently been noticed in the South China Sea during the winter monsoon, with the cold tongue temperature minimum occurring in the January or February. This cold tongue shows significant links with the Maritime Continent’s rainfall during the winter period. The cold tongue and its interaction with the Maritime Continent’s weather were studied using Reynolds SST data, wind fields from the NCEP–NCAR reanalysis dataset and the quikSCAT dataset. In addition, rainfall from the GOES Prec...     

A GIS-based soil erosion prediction using the Revised Universal Soil Loss Equation (RUSLE) (Lebna watershed,Cap Bon,Tunisia)

Natural Hazards - Soil erosion is a natural process causing grave land degradation problems. In Tunisia, soil erosion represents a serious environmental problem. Both man-made and natural...     

Variation of continental mantle heat flow with age. Possibility of discriminating between thermal models of the lithosphere

Continental mantle heat flow values are obtained by subtracting the radiogenic heat produced in the lower crust and lithosphere beneath the crust from reduced heat flow values reported for various heat flow provinces. The significance of continental mantle heat flow values thus obtained is that they can be considered essentially as representing the residual heat of cooling of the continental lithosphere. A plot of these mantle heat flow values against 1/t where t is the geologic age of the last thermal event suggests a linear trend. It is also found that the recently proposed relationQ=500 (1/t) for the variation of oceanic heat flowQ (in mW/M²) with aget (in million years) provides a reasonably good fit to the mantle heat flow data. The constant thickness plate model however, is found to be unsatisfactory in explaining the variation of continental mantle heat flow with age.     

Rare Earth and Other Trace Element Content of NRCC HISS-1 Sandy Marine Sediment Reference Material

The National Research Council (NRC), Ottawa, Canada sandy marine sediment reference material HISS-1 was characterised for thirty-seven trace elements by neutron activation optimised irradiation, cooling and counting protocols using the low power Miniature Neutron Source Reactor (MNSR) as a neutron source. This INAA methodology quantified twenty additional elements including ten rare earth (Ce, Dy, Eu, Ho, La, Lu, Nd, Sm, Tb and Yb) and ten other elements (Ba, Br, Cs, Ga, Hf, Rb, Sc, Ta, Th and Zr) missing in the final NRCC certification. A large number of values produced by different irradiation schemes together with the use of certified reference materials in the quantification step that showed good precision, provided confidence in the results. The reliability of the REE data was checked by plotting chondrite-normalised graphs.     

Hydrogeochemistry of the Winder River and adjoining tributaries, Balochistan, Pakistan

Quantitative estimation of ground and stream waters draining through sedimentary rocks of the Pab and Mor ranges (Jurassic-Cretaceous) and the Bela ophiolite has been made. The degree of correspondence among cations and anions has been estimated in order to evaluate their mutual relationships. The abundance of major ions is interpreted to be related to bedrocks and climatic conditions, which may contribute to the genetic affiliation. The log TDS and Na/Na Ca ratio reflected supremacy of weathering of rocks with some influence of evaporation. Ionic relationship is exhibited in the form of Stiff diagrams. Patterns of ionic composition revealed high NaCl, medium Ca(HCO3)2 and low MgSO4. Piper diagram has been used to classify the hydrofacies. The important hydrogeochemical parameters have been estimated for assessment of groundwater quality for domestic purposes in accordance to WHO. Irrigation water qualities have been evaluated in terms of EC, SAR, RSC, ESP and pH.     

Development of a flood forecasting system using IFAS: a case study of scarcely gauged Jhelum and Chenab river basins

Development of a well-calibrated, distributed hydrological model for flood forecasting based on rainfall and snowmelt is quite challenging, especially when in situ data is limited or unavailable. This paper presents the study carried out to parameterise the Integrated Flood Analysis System (IFAS) model for the trans-boundary, scarcely gauged catchments of Jhelum and Chenab rivers in Pakistan. Rainfall-runoff analysis was performed with a two-layered tank configuration, integrating snowmelt and dam and barrage operation from the very upstream in India to Trimmu Barrage in Pakistan. A grid size of 5?×?5 km was considered. Global map topography, land cover and soil data was utilised. The model was tested considering different magnitudes of floods of the years 2014, 2015 and 2017. The results showed that the satellite rainfall product, i.e. Global Satellite Mapping of Precipitation (GSMaP-NRT), underestimated the rainfall volume, compared to the ground-gauged rainfall. The GSMaP-IF correction method showed poor performance owing to the lack of ground observatory rainfall data for correcting the trans-boundary part of the basin. The GSMaP-Type1 correction method showed good results, except for the confluence point where complex flow conditions were not properly reproduced by the model. In addition, the incorporation of dam and barrages in the model improved the simulated flow results. It is concluded that the satellite rainfall estimates must be corrected to improve the results. Snowmelt module estimated the snowmelt contribution as 3 to 7% and 4 to 23% of the average daily discharge during the monsoon season at Mangla Dam and Marala Barrage, respectively, during 2014 and 2015. This study assessed various correction methods and concluded that the model and methodology used in the study functioned well with suitable precipitation.