Historical measurements of the Earth's magnetic field compared with remanence directions from lava flows in Italy over the last four centuries

Direct measurements of the Earth's magnetic field in Italy since 1640 a.d. have been used to check the remanence directions derived from historically dated volcanic rocks of Etna and Vesuvius. Direct measurements consist of the records of L’Aquila and Pola geomagnetic observatories, the repeat stations of the Italian Magnetic Network and the data base of the Historical Italian Geomagnetic Data Catalogue. All have been relocated to the same reference site (Viterbo — lat. 42.45°N, long. 12.03°E) in order to draw a reference secular variation (SV) curve. The direction of the Earth's field at Viterbo has also been calculated from the historical records (2000-1600) of ref. [Jackson, A., Jonkers, A.R.T., Walker, M.R., 2000. Four centuries of geomagnetic secular variation from historical records. Phil. Trans. R. Soc. London, Ser. A 358, 957-990] database. The remanence directions from Etna show a general agreement with the trend of the SV curve, although their inclination is usually lower than that from the direct measurement. The directions from Vesuvius are more scattered. Large discrepancies occur at both volcanoes and in some cases have been ascribed in the literature to poor geographic information, making it difficult to identify the flows actually emplaced during the eruptions reported in the chronicles. Closer examination shows that the great majority of the best-defined remanence directions (semi-angle of confidence α₉₅ < 2.5°) deviate significantly from the geomagnetic direction measured at the time of the emplacement, the angle between the two directions being larger than the α₉₅ value. The value of 2.5-3.0° can thus be regarded as a conservative evaluation of the error when dealing with dating Etna and Vesuvius lava flows older than 17th century, even when the accuracy attained in remanence measurements is higher. In default of a SV curve for Italy derived from archaeological artefacts, a further error in dating is introduced when reference is made to SV curves of other countries, even if well-established, as these are from regions too far from Italy (>600 km) to confidently relocate magnetic directions.     

Late Pleistocene tectonic-geomorphological development within a passive margin — The Cariatá trough, northeastern Brazil

Studies on the geomorphological evolution of the South American passive margin have been based on the pediplanation model, which predicts that its morphology is a response to regional uniform uplift and concomitant development of erosion surfaces. We combined remote sensing, geological mapping, lithostratigraphic and facies analyses, and luminescence dating in the Cariatá trough, northeastern Brazil, in order to determine how brittle tectonics and climate influenced colluviation and the shaping of local landforms in the Quaternary. Our work indicates that Cariatá is an asymmetrical trough  40 km long,  25 km wide, 250–550 m deep, and delimited by ENE–WSW-trending faults to the north and south. We recognized an ENE–WSW-oriented compression related to a strike-slip faulting regime, which corresponds to the present-day stress field in the region. This faulting event led to the deposition of colluvial fans, shed from adjacent uplifted crustal blocks, in a tectonically controlled depression. The colluvial succession is  45 m thick and presents two facies assemblages that filled the southern and, in particular, the northern borders of the trough: non-cohesive debrisflow and mudflow deposits. Optically stimulated luminescence dates of the sedimentary infill yielded ages at 224–128 ka and 45–28 ka, dominated by debrisflow and mudflow deposits, respectively. These ages may be over-estimated due to poor bleaching of colluvium, but they and our field data suggest that the margins of the trough were tectonically uplifted and eroded twice in the Late Pleistocene. The spasmodic colluvial accretion reflects the occurrence of high-magnitude, low-recurrence episodes probably associated with climate shifts in a semi-arid hillslope system. It follows that the present-day low-lying piedmont in which the Cariatá trough occurs is a juxtaposition of surfaces of various ages. This trough may have counterparts across the region. These conclusions do not corroborate the application of the cyclical pediplanation hypothesis in the area.     

Moisture source for the Amazon Basin: a study of contrasting years

The regions where the divergence of vertically integrated water vapor flux, averaged over a season or a year, is positive (negative) are sources (sinks) of moisture for the atmosphere. An aerial river is defined as a stream of strong water vapor flux connecting a source and a sink. Moisture flux, its divergence, and sources and sinks over the tropics of South and Central America and the adjoining Atlantic Ocean are obtained for dry years and for wet years in the Amazon Basin. Results show that the Amazon Basin is a sink region for atmospheric moisture in all seasons and that there are two source regions for the moisture in the basin, one situated in the South Atlantic and the other in the North Atlantic, both located equator-ward of the respective subtropical high-pressure centers. The convergence of moisture increases over the Amazon Basin in austral summer, and at the same time it decreases in the Pacific and Atlantic ITCZs. Box model calculations reveal that the wet years, on the average, present about 55 % more moisture convergence than the dry years in the Amazon Basin. A reduction in the moisture inflow across the eastern and northern boundaries of the basin (at 45°W and at the Equator, respectively) and an increase in the outflow across the southern boundary (at 15°S) lead to dry conditions. The annual mean contribution of moisture convergence to the precipitation over the Amazon Basin is estimated to be 70 %. In the dry years, it lowers to around 50 %. The net convergence of water vapor flux over the basin is a good indicator of the wet or dry condition.     

Elucidation of different forms of organic carbon in marine sediments from the Atlantic coast of Spain using thermal analysis coupled to isotope ratio and quadrupole mass spectrometry

Analysis of river, estuary and marine sediments from the Atlantic coast of Spain using thermogravimetry–differential scanning calorimetry–quadrupole mass spectrometry–isotope ratio mass spectrometry (TG–DSC–QMS–IRMS) was used to (a) distinguish bulk chemical hosts for C within a sediment and humic acid fraction, (b) track C pools with differing natural C isotope ratios and (c) observe variation with distance from the coast. This is the first application of such a novel method to the characterisation of organic matter from marine sediments and their corresponding humic acid fractions. Using thermal analysis, a labile, a recalcitrant and a refractory carbon pool can be distinguished. Extracted humic fractions are mainly of recalcitrant nature. The proportion of refractory carbon is greatest in marine sediments and humic acid fractions. Quadrupole mass spectrometry confirmed that the greatest proportion of m/z 44 (CO₂) and m/z 18 (H₂O) were detected at temperatures associated with recalcitrant carbon (510–540 °C). Isotope analysis detected progressive enrichment in δ¹³C for the sediment samples with an increase in marine influence. Isotopic heterogeneity in the refractory organic matter in marine sediments could be due to products of anthropogenic origin or natural combustion products. Isotope homogeneity of humic acids confirms the presence of terrigenous C in marine sediments, allowing the terrestrial input to be characterised.     

On the Intensity Virtual Area Characterization in the Intensity Distribution Modelling by Macroseismic Planes

A procedure is proposed for the reconfiguration of the macroseismic planes relative to earthquakes that, being characterized by a reduced number of points of observed intensity due to a lack of information, or having the epicenter very close to the coastline, are characterized by an incomplete distribution of observed intensity levels. The design of a plurality of virtual areas, through which a distribution of intensity consistent with an anisotropic model of attenuation is depicted, allows a reliable determination of macroseismic parameters of the same seismic event.     

Feeding Habits of Trisopterus minutus capelanus (Gadidae) Off the Eastern Coast of Spain (Western Mediterranean)

Abstract. The stomach contents of poor cod, Trisopterus minutus capelanus (Lacepède), were taken at monthly intervals off the eastern coast of the Gulf of Valencia (Spain). A total of 1276 were analyzed to determine diet according to fish size and season. The basic food consists of crustaceans (Mysidacea and Decapoda) and teleosts. Feeding habits varied with size: decapods and fishes were more abundant in the stomachs of larger specimens. Little seasonal variation in food habits was recorded.     

Tide-Induced Variations in the Fatty Acid Composition of Estuarine Particulate Organic Matter

The particulate organic matter (POM) in hydrodynamically variable habitats such as the lower reaches of estuaries can change in its content and quality on very short time scales (example, hourly), and these changes can potentially influence higher-level consumers in river-estuary-marine systems. Estuarine water samples were collected hourly for 12 h downstream in a small river to evaluate the fatty acid composition of POM over a tidal cycle. Fatty acid constituents of POM collected during the flood tide were dominated by the saturated, higher plant and bacterial fatty acids, whereas unsaturated, polyunsaturated, essential, and diatom-associated fatty acids dominated the POM collected during the ebb tide. Elevated algal biomass (as indicated by high chlorophyll a concentrations), diatom, and freshness indices in the POM indicated enhanced fresh autochthonous-origin materials that dominated the mixed organic pool during the ebb tide compared to more degraded detritus during the flood tide. Tidal retention of organic matter and algal primary production were the most influential factors that differentiated the fatty acid composition of estuarine POM over the short time scale. The results of this study have important implications on the quality of POM at the time of sampling, especially in estuaries where mixed organic pools have multiple inputs and are strongly influenced by tidal cycles.     

A review of undulated sediment features on Mediterranean prodeltas: distinguishing sediment transport structures from sediment deformation

Most Mediterranean prodeltas show undulated sediment features on the foresets of their Holocene wedges. These features have been described all along the Mediterranean for the last 30 years and interpreted as either soft sediment deformation and incipient landsliding, and more recently, as sediment transport structures. We perform a review and detailed analysis of these undulated sediment features using ultrahigh-resolution seismic and bathymetric data as well as geotechnical information and hydrodynamic time series and hydrographic transects. In this study we show that the characteristics of the sediment undulations (configuration of the reflections down section and between adjacent undulations and overall morphologic characteristics) are incompatible with a genesis by sediment deformation alone and do not show evidence of sediment deformation in most cases. Various processes in the benthic boundary layer can be invoked to explain the variety of features observed in the numerous areas displaying sediment undulations.     

Contrasting interactions of sodium and potassium with H<Subscript>2</Subscript>O in haplogranitic liquids and glasses at 200 MPa from hydration–diffusion experiments

This study examines hydration–diffusion in the metaluminous haplogranite system at 200 MPa H₂O and 800–300°C. At 800°C hydration is accompanied by melting and uphill diffusion of sodium from anhydrous glass toward the region of hydration and melting, whereas potassium diffuses away from the hydration front and into anhydrous glass. Silicon and aluminum are simply diluted upon hydration. There is no change in molecular Al/(Na + K) throughout the entire hydration-diffusion aureole and, therefore, (1) there is no loss of alkalis to the vapor, and (2) K migrates to replace Na in order to maintain local charge balance required by ^IVAl. Alkali diffusion occurs over a viscosity contrast from 10^4.1 Pa s in hydrous liquid to 10^11.8–10^13.5 Pa s in anhydrous glass. From these results, we interpret that: (1) Na is structurally or energetically favored over K as a charge-balancing cation for ^IVAl in hydrous granitic liquids, whereas the opposite behavior has been observed for anhydrous melts, and (2) the diffusion of alkalis through silicate melts is largely independent of viscosity. Results from 600°C are similar to those at 800°C, but hydration at 300°C involves a loss of Na and concomitant increase in molar Al/(Na + K) in the hydration zone due to hydrogen-alkali exchange between fluid and glass. Hydration behavior at 400°C is transitional between those at 300°C and 600°C, suggesting that the change in hydration mechanism occurs near the glass transition.