In this work, we consider a new model for flow in a multiporosity shale gas reservoir constructed within the framework of an upscaling procedure where hydraulic fractures are treated as (\(n-1\)) interfaces (\(n=2,3\)). Within this framework, the hydrodynamics is governed by a new pressure equation in the shale matrix which is treated as a homogenized porous medium composed of organic matter (kerogen aggregates with nanopores) and inorganic impermeable solid (clay, calcite, quartz) separated from each other by a network of interparticle pores of micrometer size. The solution of the pressure equation is strongly influenced by the constitutive response of the retardation parameter and effective hydraulic conductivity where the former incorporates gas adsorption/desorption in the nanopores of the kerogen. By focusing our analyses on this nonlinear diffusion equation in the domain occupied by the shale matrix, an optimization strategy seated on the adjoint sensitivity method is developed to minimize a cost functional related to gas production and net present value in a single hydraulic fracture. The gradient of the objective functional computed with the adjoint formulation is explored to update the controlled pressure drop aiming to optimize production in a given window of time. The combination of the direct approach and gradient-based optimization using the adjoint formulation leads to the construction of optimal production scenarios under controlled pressure decline in the well. Numerical simulations illustrate the potential of the methodology proposed herein in optimizing gas production. 相似文献
Store Mosse (the ‘Great Bog’ in Swedish) is one of the most extensive bog complexes in southern Sweden (~77 km2), where pioneering palaeoenvironmental research has been carried out since the early 20th century. This includes, for example, vegetation changes, carbon and nitrogen dynamics, peat decomposition, atmospheric metal pollution, mineral dust deposition, dendrochronology, and tephrochronology. Even though organic matter (OM) represents the bulk of the peat mass and its compositional change has the potential to provide crucial ecological information on bog responses to environmental factors, peat OM molecular composition has not been addressed in detail. Here, a 568-cm-deep peat sequence was studied at high resolution, by attenuated reflectance Fourier-transform infrared spectroscopy (FTIR-ATR) in the mid-infrared region (4000–400 cm–1). Principal components analysis was performed on selected absorbances and change-point modelling was applied to the records to determine the timing of changes. Four components accounted for peat composition: (i) depletion/accumulation of labile (i.e. carbohydrates) and recalcitrant (i.e. lignin and other aromatics, aliphatics, organic acids and some N compounds) compounds, due to peat decomposition; (ii) variations in N compounds and carbohydrates; (iii) residual variation of lignin and organic acids; and (iv) residual variation of aliphatic structures. Peat decomposition showed two main patterns: a long-term trend highly correlated to peat age (r = 0.87), and a short-term trend, which showed five main phases of increased decomposition (at ~8.4–8.1, ~7.0–5.6, ~3.5–3.1, ~2.7–2.1 and ~1.6–1.3 ka) – mostly corresponding to drier climate and its effect on bog hydrology. The high peat accumulation event (~5.6–3.9 ka), described in earlier studies, is characterized by the lowest degree of peat decomposition of the whole record. Given that FTIR-ATR is a quick, non-destructive, cost-effective technique, our results indicate that it can be applied in a systematic way (including multicore studies) to peat research and provide relevant information on the evolution of peatlands. 相似文献
The volcanic rocks of the Colíder and Roosevelt formations are extensively exposed in the south-central portion of the Amazonian Craton where effusive and pyroclastic rocks have been mapped. Both units, topped by chemical sediments and oceanic facies as rhyolite and andesite lavas, rhyodacite, and porphyritic dacite, with frequent intercalations of pyroclastic and epiclastic deposits. Whole-rock geochemistry for 55 samples of rhyolitic to andesitic composition suggests the involvement of fertile mantle-derived components with E-MORB to OIB compositions. The analyzed rocks display calc-alkaline to shoshonitic affinity consistent with generation related to an active continental margin. The whole-rock Sm-Nd isotope data from selected felsic volcanic rocks of the Colíder and Roosevelt formations yield negative initial εNd values between –3 and –9, indicating the predominantly crustal nature of the parental magmas with early Archean to late Paleoproterozoic (ca. 2.5–2.0 Ga) depleted mantle model ages.
This paper shows how post-oil spill management measures can affect the general pattern of fishing effort exerted on two particular species of great commercial value in northern Spanish fisheries: anglerfish (Lophius piscatorius and Lophius budegassa) and mackerel (Scomber scombrus). Data time series of catches and fishing efforts were analysed corresponding to the area and time period affected by the oil spill fishing restrictions (December 2002–June 2003) and similar previous and post-spill periods. This was done to detect shifts that could be due to either the oil spill per se or the management measures taken to minimise pollution effects. Then, analyses and simulations with Arcview GIS module FAST (Fishing Activity Simulation Tool v. 1.1) were carried out with the aim of studying the fishing effort spatial distribution. Changes were observed in the Catch Per Unit Effort (CPUE) of anglerfish and mackerel by area or fishery unit. Results show a spatial displacement of fishing effort to other fishing areas in the case of anglerfish, and the transfer of fishing effort between different fishery units in the case of mackerel. Although both effects were caused primarily by the management measures in force after the oil spill, they are considered side or collateral effects. The management measures that have to be taken after any disaster should also consider these kinds of ancillary effects as well as evaluating the likely positive or negative impact of these side effects. 相似文献
Recently, ab-initio quantum mechanical potential surfaces calculated for silicate hydroxyacid molecules were used to extract covalent potentials for use in mineral physics calculations (Lasaga and Gibbs 1987). The calculations showed that these potentials are capable of generating the structure and physical properties of silicate minerals. In this paper we explore in more detail the suitability of various covalent potentials in mimicking the topography of the ab-initio potential surfaces. We also extend the use of such quantum-derived potentials in generating the structures of hydroxyacid dimers, trimers, and pentamers of silicate tetrahedra and in studying the structure and the dynamical properties of minerals and glasses. 相似文献
A technique to detect spectrum variations versus time along seismic signals is applied to coda waves of local earthquakes (Friuli, Northern Italy). The technique consists of an autoregressive modeling and utilizes nonlinear spectral analysis where the spectrum of stochastic processes is estimated as the transfer function of the filter that whitens the process under analysis. This approach appears to be particularly well suited to those investigations where automatic measurements of the instantaneous frequency have to be carried out on digital data. The detection of variations of the instantaneous frequency along the coda allows computation of seismic-Q in the lithosphere and its frequency dependence: the result obtained is $$Q = 100f^{0.4} $$ which appears to be strongly consistent with that, based on the estimate of the coda amplitude decay in the band including the most significant frequencies of the signals under analysis. 相似文献
Changes of radon concentration in the ground have been reported to correlate with seismic activity in many places over widely varying distances from the earthquake epicenters, sometimes over 100's and occasionally over 1000's of km depending on the magnitude M of the earthquakes. For proper use of such correlations in forecasting the location and size of impending earthquakes, it would be useful to establish a relation between M and the maximum distance xM at which radon can be significantly altered by preseismic effects.We have monitored radon in the ground continuously at Blue Mountain Lake, NY starting Dec. 3. 1975 and at three locations in Alaska—Icy Bay, Yakataga, and Sand Point (starting Nov. 12, 1979; March 5, 1980; and June 29, 1980 respectively). Sample correlations from visual examination of the recent radon record and tentative use of a proposed scaling relation show a number of possible earthquake-related signals at these locations. The data are compatible with scaling relations that were derived from two separate models of premonitory elastic strains. In this work xM = 100.48M, where xM is in units of km and M ≥ 3. Since tilt and strain signals correlate similarly with magnitude and distance, it is likely that most earthquake-related radon signals are mechanically induced. 相似文献