Micro-scale biogeochemical heterogeneity in sediments: A review of available technology and observed evidence

The hypothesis that reducing conditions exist in localized zones of high organic matter, termed microniches, was first suggested over a century ago, but only relatively recently have high-resolution techniques been available to investigate them. In any sediment containing benthic fauna, bioturbation affects the distribution of a number of redox-sensitive components. Direct faecal deposition and the death of fauna may be expected to cause particles of labile organic matter (microniches) to be distributed heterogeneously within the sediment. This review discusses the significance and future direction of microniche studies by considering, exclusively, data obtained on a sub-mm scale that provide significant evidence for the existence and properties of microniches. Microelectrodes and planar optodes have shown the significant effect of burrowing organisms on localized O₂ distributions and revealed distinct depletions in O₂ due to microniches. Localized increases in pCO₂ and decreases in pH measured by optodes were attributed to elevated activity at microniches. Diffusive gradients in thin-films have shown isolated supersaturation of metals and sulphide, providing evidence for possible simultaneous oxidation of organic matter by sulphate and iron oxides. The stochastic nature of these data and the lack of information for the same precise location hinders interpretation in terms of sediment diagenesis. If microniches are known to account for a significant proportion of organic matter degradation, re-examination of the current understanding of sedimentary diagenesis may be needed. Further investigation on the distribution and frequency of microniches is required, including a wider range of analytes, in order to estimate their cumulative effect on element diagenesis, immobilisation/remobilisation processes and ultimately pollutant fate.     

The partitioning of molybdenum(VI) between aqueous liquid and vapour at temperatures up to 370 °C

We have conducted experiments to evaluate the vapour-liquid fractionation of Mo(VI) in the system MoO₃-NH₃-H₂O at 300-370 °C and saturated vapour pressure, using a two-chamber autoclave that allows separate trapping of the vapour and liquid. The measured total Mo concentrations in each phase were used to calculate a distribution coefficient, , which increases as the density of the vapour approaches that of the liquid, and is greater than one for pH ? 4. Molybdenum speciation in the vapour is described by a single complex, MoO₃H₂O. By contrast, thermodynamic modeling of the distribution of Mo species in the liquid indicates that bimolybdate (HMoO₄⁻) is the dominant aqueous species at the conditions of our experiments, and that molybdate (MoO₄²⁻) and molybdic acid (H₂MoO₄⁰) are present in smaller quantities. As vapour-liquid fractionation occurs between neutral species, it is governed by the reaction H₂MoO₄⁰(aq) = MoO₃ · H₂O(g). Fractionation is therefore controlled by the concentration of H₂MoO₄⁰ in the liquid, which increases with increasing temperature and decreasing pH. Owing to the pH dependence of , it cannot be used to describe Mo fractionation in aqueous vapour-liquid systems with compositions different than those of this study. We have therefore calculated a composition-independent (Henry’s Law) constant, , for each experimental point, using the measured total Mo concentration in the vapour and the modeled concentration of H₂MoO₄⁰ in the liquid. This constant may be applied to aqueous vapour-liquid systems of known liquid composition to estimate the concentration of Mo in a vapour for which little chemical information is available, and thereby supplement the available fractionation data for natural porphyry-forming systems. The results of this study demonstrate that at conditions typical of natural porphyry ore-forming systems, a significant amount of molybdenum fractionates into the vapour over the liquid, and the vapour may transport quantities of Mo in excess of that in the liquid at pH conditions below those of the muscovite-microcline reaction boundary.     

Geochronological and isotopic constraints on Palaeoproterozoic skarn base metal mineralisation in the central Gawler Craton, South Australia

The mineralisation potential of Palaeoproterozoic strata from the central Gawler Craton, South Australia, is poorly known. This study defines the timing of Zn-rich skarn formation within Palaeoproterozoic calcsilicate and highlights this as a new mineralisation style for the Gawler Craton. Sulphides within the garnet–diopside skarn in the No. 17 Bore Prospect are predominantly in the form of sphalerite, associated with galena, minor chalcopyrite, pyrrhotite and pyrite. Sulphide is present in disseminated form and as a coarse-grained sulphide within a sericite-rich cavity-fill. Mineralisation is inferred to have formed at 1710 ± 16 Ma through a Sm–Nd isochron from garnet and diopside aliquots. A weakly mineralised and altered granite immediately below the calcsilicate skarn crystallised at 1729 ± 13 Ma (LA-ICPMS U–Pb zircon), within error of the skarn mineralisation. The skarn is interpreted to have formed through the initiation of fluid circulation as a result of high-level granite emplacement within the Palaeoproterozoic strata. Exploration for skarn Zn–Pb deposits such as the No. 17 Bore Prospect is assisted by their geophysical properties.     

Evidence for a differentiated ignimbritic activity ending the building-stage of Tahiti-Nui (French Polynesia)

A thick columnar-jointed ignimbrite-like formation occupies the upper part of the Orohena Massif on Tahiti-Nui. Differentiated products related to the ignimbrite were sampled at the base of the Orohena cliff and have been dated using the unspiked K/Ar Cassignol technique at $502\pm 7\text{ka}$. These pyroclastic volcanic rocks show chemical similarities with Ne-syenitic rocks from a shallow magma reservoir presently exposed farther south because of the dissection of the island by deep erosion. The presence of less-evolved magma blebs in the ignimbrite products suggests an incomplete magma mixing process. This likely indicates a late injection of a more basic magma into the reservoir, probably triggering the ignimbritic eruption, unique in the generally non-explosive eruptive history of Tahiti-Nui. To cite this article: A. Hildenbrand, P.-Y. Gillot, C. R. Geoscience 338 (2006).     

Consistency and fidelity of Indonesian-throughflow total volume transport estimated by 14 ocean data assimilation products

Monthly averaged total volume transport of the Indonesian throughflow (ITF) estimated by 14 global ocean data assimilation (ODA) products that are decade to multi-decade long are compared among themselves and with observations from the INSTANT Program (2004–2006). The main goals of the comparisons are to examine the consistency and evaluate the skill of different ODA products in simulating ITF transport. The ensemble averaged, time-mean value of ODA estimates is 13.6 Sv (1 Sv = 10⁶ m³/s) for the common 1993–2001 period and 13.9 Sv for the 2004–2006 INSTANT Program period. These values are close to the 15-Sv estimate derived from INSTANT observations. All but one ODA time-mean estimate fall within the range of uncertainty of the INSTANT estimate. In terms of temporal variability, the scatter among different ODA estimates averaged over time is 1.7 Sv, which is substantially smaller than the magnitude of the temporal variability simulated by the ODA systems. Therefore, the overall “signal-to-noise” ratio for the ensemble estimates is larger than one. The best consistency among the products occurs on seasonal-to-interannual time scales, with generally stronger (weaker) ITF during boreal summer (winter) and during La Nina (El Nino) events. The scatter among different products for seasonal-to-interannual time scales is approximately 1 Sv. Despite the good consistency, systematic difference is found between most ODA products and the INSTANT observations. All but the highest-resolution (18 km) ODA product show a dominant annual cycle while the INSTANT estimate and the 18-km product exhibit a strong semi-annual signal. The coarse resolution is an important factor that limits the level of agreement between ODA and INSTANT estimates. Decadal signals with periods of 10–15 years are seen. The most conspicuous and consistent decadal change is a relatively sharp increase in ITF transport during 1993–2000 associated with the strengthening tropical Pacific trade wind. Most products do not show a weakening ITF after the mid-1970s’ associated with the weakened Pacific trade wind. The scatter of ODA estimates is smaller after than before 1980, reflecting the impact of the enhanced observations after the 1980s. To assess the representativeness of using the average over a three-year period (e.g., the span of the INSTANT Program) to describe longer-term mean, we investigate the temporal variations of the three-year low-pass ODA estimates. The average variation is about 3.6 Sv, which is largely due to the increase of ITF transport from 1993 to 2000. However, the three-year average during the 2004–2006 INSTANT Program period is within 0.5 Sv of the long-term mean for the past few decades.     

Evaluation of the WAMME model surface fluxes using results from the AMMA land-surface model intercomparison project

The West African monsoon (WAM) circulation and intensity have been shown to be influenced by the land surface in numerous numerical studies using regional scale and global scale atmospheric climate models (RCMs and GCMs, respectively) over the last several decades. The atmosphere–land surface interactions are modulated by the magnitude of the north–south gradient of the low level moist static energy, which is highly correlated with the steep latitudinal gradients of the vegetation characteristics and coverage, land use, and soil properties over this zone. The African Multidisciplinary Monsoon Analysis (AMMA) has organised comprehensive activities in data collection and modelling to further investigate the significance land–atmosphere feedbacks. Surface energy fluxes simulated by an ensemble of land surface models from AMMA Land-surface Model Intercomparison Project (ALMIP) have been used as a proxy for the best estimate of the “real world” values in order to evaluate GCM and RCM simulations under the auspices of the West African Monsoon Modelling Experiment (WAMME) project, since such large-scale observations do not exist. The ALMIP models have been forced in off-line mode using forcing based on a mixture of satellite, observational, and numerical weather prediction data. The ALMIP models were found to agree well over the region where land–atmosphere coupling is deemed to be most important (notably the Sahel), with a high signal to noise ratio (generally from 0.7 to 0.9) in the ensemble and a inter-model coefficient of variation between 5 and 15%. Most of the WAMME models simulated spatially averaged net radiation values over West Africa which were consistent with the ALMIP estimates, however, the partitioning of this energy between sensible and latent heat fluxes was significantly different: WAMME models tended to simulate larger (by nearly a factor of two) monthly latent heat fluxes than ALMIP. This results due to a positive precipitation bias in the WAMME models and a northward displacement of the monsoon in most of the GCMs and RCMs. Another key feature not found in the WAMME models is peak seasonal latent heat fluxes during the monsoon retreat (approximately a month after the peak precipitation rates) from soil water stores. This is likely related to the WAMME northward bias of the latent heat flux gradient during the WAM onset.     

A study of impact of the geographic dependence of observing system on parameter estimation with an intermediate coupled model

Observational information has a strong geographic dependence that may directly influence the quality of parameter estimation in a coupled climate system. Using an intermediate atmosphere-ocean-land coupled model, the impact of geographic dependent observing system on parameter estimation is explored within a “twin” experiment framework. The “observations” produced by a “truth” model are assimilated into an assimilation model in which the most sensitive model parameter has a different geographic structure from the “truth”, for retrieving the “truth” geographic structure of the parameter. To examine the influence of data-sparse areas on parameter estimation, the twin experiment is also performed with an observing system in which the observations in some area are removed. Results show that traditional single-valued parameter estimation (SPE) attains a global mean of the “truth”, while geographic dependent parameter optimization (GPO) can retrieve the “truth” structure of the parameter and therefore significantly improves estimated states and model predictability. This is especially true when an observing system with data-void areas is applied, where the error of state estimate is reduced by 31 % and the corresponding forecast skill is doubled by GPO compared with SPE.     

Drought and water policy in Australia: Challenges for the future illustrated by the issues associated with water trading and climate change adaptation in the Murray–Darling Basin

This paper reviews historical and existing drought and water policy in Australia in order to gain a sense of the strengths and weaknesses in enabling effective adaptation to climate change. In particular, (a) the social, economic, and environmental costs and benefits of water trading and (b) the limitations of using ‘market-based’ instruments (MBIs), like water trading, for adapting to drought and water security related climate change impacts are investigated. It was found that water trading has potential as a climate change adaptation strategy with many benefits experienced in previous and current versions of water trading. However, there are also limitations and those negatively impacted by water trading are hit hard. These social impacts of water trading have not been thoroughly investigated and are not well understood. Significant uncertainty also exists around the impacts of water trading on the environment (e.g. changed hydrological regimes, underestimation of sustainable environmental flows etc.). Proper quantification of these impacts is needed, however, it is a complex task given Australia's large hydroclimatic variability and the current lack of understanding as to how to optimise water needs of the environment, humans, agriculture and other industries. It appears that ‘cap and trade’ quantity-based MBIs such as water trading will eventually do what they are designed to do (i.e. reallocate a resource to ‘high value’ users). However, given that the ‘low value’ users in this case are agriculture and town/urban water supply (not including drinking water) and the ‘high value’ users are mining, manufacturing, and electricity production (i.e. high greenhouse gas emissions), do we really want the water trading MBI to achieve its objective? And, what would the social and environmental ramifications of such a shift in water use within Australia be? These questions, along with the limitations and potential implications of using water trading (and MBIs in general) as a climate change adaptation tool, must be carefully considered if past Australian drought and water policy failures are not to be repeated.     

Towards a genealogy of tropical architecture: Historical fragments of power‐knowledge,built environment and climate in the British colonial territories

In this paper, we trace the history of tropical architecture beyond its supposed founding moment, that is, its institutionalization and naming‐as‐such, in the mid‐twentieth century. We note that many of the planning principles, spatial configurations and environmental technologies of tropical architecture could be traced to knowledge and practices from the eighteenth century onwards, and we explore three pre‐1950s moments of ‘tropical architecture’ in the British empire through building types such as the bungalow, military barrack and labourers' housing in the tropics. Unlike the depoliticized technical discourse of tropical architecture in the mid‐twentieth century, this earlier history shows that so‐called tropical architecture was inextricably entangled with medical and racial discourses, biopolitics and the political economy of colonialism. We argue that tropical architecture should not be understood as an entity with a fixed essence that is overdetermined by a timeless and unchanging external tropical nature. Rather, tropical architecture should be understood as a set of shifting discourses that privilege tropical nature, especially climate, in various ways as the prime determinant of built form according to different constellations of sociocultural and technoscientific conditions. We thus see ‘tropical architecture’ not as a depoliticized entity but as a power‐knowledge configuration inextricably linked to asymmetrical colonial power relations.     

Petrography and composition of Martian regolith breccia meteorite Northwest Africa 7475

The Northwest Africa (NWA) 7475 meteorite is one of the several stones of paired regolith breccias from Mars based on petrography, oxygen isotope, mineral compositions, and bulk rock compositions. Its inventory of lithic clasts is dominated by vitrophyre impact melts that were emplaced while they were still molten. Other clast types include crystallized impact melt rocks, evolved plutonic rocks, possible basalts, contact metamorphosed rocks, and siltstones. Impact spherules and vitrophyre shards record airborne transport, and accreted dust rims were sintered on most clasts, presumably during residence in an ejecta plume. The clast assemblage records at least three impact events, one that formed an impact melt sheet on Mars ≤4.4 Ga ago, a second that assembled NWA 7475 from impactites associated with the impact melt sheet at 1.7–1.4 Ga, and a third that launched NWA 7475 from Mars ~5 Ma ago. Mildly shocked pyroxene and plagioclase constrain shock metamorphic conditions during launch to >5 and <15 GPa. The mild postshock‐heating that resulted from these shock pressures would have been insufficient to sterilize this water‐bearing lithology during launch. Magnetite, maghemite, and pyrite are likely products of secondary alteration on Mars. Textural relationships suggest that calcium‐carbonate and goethite are probably of terrestrial origin, yet trace element chemistry indicates relatively low terrestrial alteration. Comparison of Mars Odyssey gamma‐ray spectrometer data with the Fe and Th abundances of NWA 7475 points to a provenance in the ancient southern highlands of Mars. Gratteri crater, with an age of ~5 Ma and an apparent diameter of 6.9 km, marks one possible launch site of NWA 7475.