Mineralogy and geochemistry studies on the Nusab El Balgum granitic batches,South Western Desert,Egypt

Igneous rocks of Nusab El Balgum are formed as an elongated complex mass covering an area of about 4 km?×?12.5 km (50 km²), in the NNE-SSW direction of the Tarfawi-Qena-South Sinai trend, which is a branch of the Trans-African shear zone at the intersection with the Kalabsha fault, which is a branch from Guinean-Nubian lineaments. The continuous reactivation of these two major weakness zones from the late Triassic to recent times has created many generations of the magma batches. The exposed granitic rocks of these batches at Nusab El Balgum were represented by the fresh peralkaline granite (youngest) and hydrothermally altered granites (oldest). The fresh peralkaline granite takes the form of a small stock composed essentially of perthites, quartz, sodic pyroxenes, amphiboles (secondary), and rare albite according to the proportion of presence, respectively. The accessory minerals are zircon, bastnaesite-(Ce), columbite-(Fe), magnetite, barite, and sphalerite. The geochemical study indicated that this granite is peralkaline, ferroan, A-type (specifically belongs to the A1-subgroup), anorogeny, emplaced in a within-plate, and crystallized at relatively shallow depth from the alkali basaltic magma similar to the OIBs. Furthermore, it is enriched in the HFSE (e.g., Th, U, Nb, REE, and Zr). The hydrothermally altered granites are formed as an incomplete ring shape and a small stock. They were formed during the late Cretaceous age and were altered due to the hydrothermal solutions from the continuous reactivation affected weakness zones and the new magmatic batches. The hydrothermally altered granites are extremely rich in HFSE found in the accessory minerals such as zircon (different in shape, size, and contains inclusions of bastnaesite and columbite), columbite-(Fe&Mn), rare gittinsite, pyrochlore minerals (ceriopyrochlore and plumbopyrochlore) carlosbarbosaite, changbaiite, bastnaesite-(Ce), monazite-(Ce), stetindite, cerianite-(Ce), thorite, and uranothorite. These rocks were subjected to many highly superimposed hydrothermal alteration types, including propylitic, sericitic, potassic, silicification, argillic, and Fe-Mn oxy-hydroxides. The hydrothermal solutions with low temperatures and containing F^1? and CO₃^2?, PO₄^3? and H₂O caused redistribution; transportation and redeposition of the HFSE in these rocks, in addition to the clay minerals and K-metasomatism, were formed. The relations between the silicification index (SI?=?SiO₂/(SiO₂ + Al₂O₃) and Zr, Nb, Th, U, LREE, and HREE are positive but they become negative with the K-metasomatism.     

The oceanic anoxic event 2 at Es Souabaa (Tebessa,NE Algeria): bio-events and stable isotope study

At the southern margin of the Tethys, the Es Souabaa area recorded traces of Oceanic Anoxic Event 2 (OAE2) around the Cenomanian-Turonian boundary (C/Tb). The dark, laminated, filament- and pyrite-bearing limestones represent the typical facies of this event. In terms of sedimentary environment, these features reflect a transgressive drowning that had induced hypoxia in these sedimentary environments. Such conditions favored the deposition and preservation of organic matter of marine origin, the distribution of which was controlled by paleogeography and halokinetic tectonics at that period. The OAE2 reached a climax between the last upper Cenomanian occurrence of Rotalipora cushmani and the lower Turonian occurrence of Whiteinella praehelvetica. Positive shift of the δ¹³C excursion along with relatively high total organic carbon (TOC) contents during OAE2 both indicate palaeo-environmental modifications enhanced by a significant change in primary marine productivity. Meanwhile, negative δ¹⁸O peaks in carbonates reflect increasing temperatures. Comparison of the data from this study with those from the neighboring Kalaat Senan section (Tunisia) suggests close similarities of events, although OAE2 is much more enhanced in Algeria.     

A multidisciplinary-based conceptual model of a fractured sedimentary bedrock aquitard: improved prediction of aquitard integrity

A hydrogeologic conceptual model that improves understanding of variability in aquitard integrity is presented for a fractured sedimentary bedrock unit in the Cambrian-Ordovician aquifer system of midcontinent North America. The model is derived from multiple studies on the siliciclastic St. Lawrence Formation and adjacent strata across a range of scales and geologic conditions. These studies employed multidisciplinary techniques including borehole flowmeter logging, high-resolution depth-discrete multilevel well monitoring, fracture stratigraphy, fluorescent dye tracing, and three-dimensional (3D) distribution of anthropogenic tracers regionally. The paper documents a bulk aquitard that is highly anisotropic because of poor connectivity of vertical fractures across matrix with low permeability, but with ubiquitous bed parallel partings. The partings provide high bulk horizontal hydraulic conductivity, analogous to aquifers in the system, while multiple preferential termination horizons of vertical fractures serve as discrete low vertical hydraulic conductivity intervals inhibiting vertical flow. The aquitard has substantial variability in its ability to protect underlying groundwater from contamination. Across widespread areas where the aquitard is deeply buried by younger bedrock, preferential termination horizons provide for high aquitard integrity (i.e. protection). Protection is diminished close to incised valleys where stress release and weathering has enhanced secondary pore development, including better connection of fractures across these horizons. These conditions, along with higher hydraulic head gradients in the same areas and more complex 3D flow where the aquitard is variably incised, allow for more substantial transport to deeper aquifers. The conceptual model likely applies to other fractured sedimentary bedrock aquitards within and outside of this region.     

Synthesizing multifaceted characterization techniques to refine a conceptual model of groundwater sources to springs in valley settings (Minnesota,USA)

Springs are commonly used as low-cost monitoring locations to assess groundwater quality and long-term trends. However, spring waters in many settings are a mixture of groundwater sources that range in physical properties and water chemistry. The objective of this work was to determine water sources of springs emerging from the North American midcontinent Cambrian-Ordovician aquifer system at a fish hatchery near Lanesboro, Minnesota (USA), and compare and contrast the sources to shallower and deeper sources. The hydrology of the Lanesboro State Fish Hatchery has been studied for decades using a combination of dye tracing, thermal monitoring, geochemical sampling, and nearby borehole and outcrop observations. Previous studies are integrated with recently collected dye tracing results and geochemical data to develop a comprehensive conceptual model of groundwater flow. Dye trace findings and geochemistry indicate well-developed karst and bedrock fractures in shallowly buried unconfined carbonate formations are important transport pathways to convey anthropogenically influenced waters from the land surface to the hatchery springs. However, borehole dye traces, thermal monitoring, continuous nitrate monitoring, and mixing calculations show that a deeper confined siliciclastic aquifer is responsible for delivering relatively pristine water that accounts for about half of hatchery spring flux. Characterization of the hatchery’s groundwater systems provides fishery managers with information to protect this vital resource and improved context to interpret water-quality-monitoring data that track agricultural contaminants. The methods and results of this study may be widely applicable across a large extent of the Cambrian-Ordovician aquifer system, and to multiaquifer sedimentary bedrock systems elsewhere.

     

A long-term analysis of thundersnow events over the Marmara Region,Turkey

This study aimed to reveal the temporal statistics, formation mechanisms, suitable land/sea surface (LS/SS) and upper-level atmospheric conditions, and predictability of thundersnow (TSSN) events that occurred between 2000 and 2021 in the Marmara Region with atmospheric stability indexes. Aviation reports from 11 airports were analyzed throughout the period, and no TSSN events were found at four airports. A total of 19 TSSN events were identified, and six events were found in 2015, when the sea-effect snow (SES) mechanisms were observed four times. The majority of TSSN events were of very short duration (0–1 h), and no significant trend was observed in terms of intraday distribution. SES mechanism was observed in 17 of the 19 TSSN events, and the dominance of northern flows was detected at all airports and at the sub-inversion upstream levels. In terms of air-sea interaction, suitable temperature differences between the SS and 850/700 hPa (17 °C and 27 °C on average), and the transfer of heat-moisture fluxes from the SS to the upper-atmosphere were possible in almost all TSSN events. In this way, meteorological parameters were sufficient for the formation and strengthening of the convective layer. In addition, the presence of directional wind shear and the observation of inversion layers restricting convective movements at higher levels instead of near the surface ensured that the moisture requirement, lifting mechanism, and unstable atmospheric conditions required for the formation of TS were provided. The CAPE values were very low for winter TSs. Total Total Index and TQ Index produced the most appropriate results for TSSN prediction.

     

Integrating GIS‐Based Geo‐Atom Theory and Voxel Automata to Simulate the Dispersal of Airborne Pollutants

Environmental processes are usually conceptualized as complex systems whose dynamics are best understood by examining the relationships and interactions of their constituent parts. The cellular automata paradigm, as a bottom‐up modeling approach, has been widely used to study the macroscopic behavior of these complex natural processes. However, the cellular automata models are largely restricted to the two‐dimensional spatial perspective even though the process dynamics they represent evolve in the three spatial dimensions. The objective of this study is to develop a voxel‐based automata approach for modeling the propagation of airborne pollutants in three‐dimensional space over time. The GIS‐based geo‐atom theory was used to manage the data within the automaton. The simulation results indicate the model has the capability to generate effective four‐dimensional (4D) simulations from simple transition rules that describe the processes of particle advection and diffusion. The application of voxel‐based automata and the geo‐atom concepts allows for a detailed 4D analysis and tracking of the changes in the voxel space at every time‐step. The proposed modeling approach provides new means to examine the relationships between pattern and process in 4D.     

Geography and postgenomics: how space and place are the new DNA

For many geographers, postgenomics is a relatively new perspective on biological causality. It is a non-dualistic way to conceptualize DNA, genes and environment. It also presents an opportunity for a broad critical engagement with biology through geography’s insights into socionature and the fallacies of spatial inference. In postgenomics, mapping of the spatial and temporal contexts and circumstances surrounding DNA, rather than DNA sequence alone, has become prioritized. Consequently, scientific and economic value in postgenomics accrues through the enclosure and mapping of the ‘omes’. These include the more familiar epigenome and microbiome, but also the interactome, the phenome, and the exposome among many others. The omes represent the cartographic translation of biological spatialities that modify the outcomes of DNA sequence from within as well as from outside of human bodies. In this article, we show how postgenomics leverages this omic ontologicalization of space and puts it to productive use. Drawing upon recent studies of the human microbiome, we illustrate how problematic geographies of difference arise through the way this omic mapping unfolds.     

Mineralogy,alteration patterns,geochemistry, and fluid properties of the Ag-Au epithermal deposit Nová Baňa,Slovakia

Mineralogy and Petrology - In this contribution, we report new data on mineralogy, alteration patterns, geochemistry, fluid properties and source of fluids for the deposit Nová Baňa, one...     

Source component mixing controls the variability in Cu and Au endowment along the strike of the Eastern Andean Cordillera in Peru

Mississippian arc magmatic suites of the Au-rich Pataz and Cu-dominated Montañitas regions in Peru reveal distinct modes of magmatic-hydrothermal petro- and metallogenesis. The distinction is remarkable due to their broad contemporaneity (336–322 Ma), arc-parallel position, and close distance (<?50 km) to each other. In both arc regions, petrography, geochemistry, and the tectonic setting of magmatic suites suggest a rapid switch from syn-collisional/compressional to post-collisional/extensional (with ‘A₂-type’ signature) emplacement regime. Rocks of the Au-rich Pataz region originate from mixed sources with a contribution from the mantle (εHf?>?0 and δ¹⁸O of ~?5.3‰) and assimilated old crust (variously low εHf and δ¹⁸O >?5.3‰). The ultimate source of Au in the mineralised Pataz batholith was oxidised (fO₂ at FMQ buffer; based on zircon trace chemistry) and alkali-, LILE- and HFSE-enriched, most likely represented by the metasomatised mantle. The syn-extensional emplacement of the relatively reduced (ΔFMQ?<?0), but unmineralised, A₂-type suite involved assimilation of reduced crust. Associated, reduced, magmatic-hydrothermal fluids infiltrated the Au-bearing batholith suite and effectively mobilised and transported and concentrated Au. In the Montañitas region, rocks are oxidised (ΔFMQ?>?0) and dominantly mantle derived without significant incorporation of crustal material. Samples from the Cu-mineralised suites indicate the additional contribution of a δ¹⁸O <?5.3‰ source, potentially melted layer-2 gabbro. In addition, the elevated whole-rock La/Yb and Sr/Y ratios are compatible with minor addition of slab-derived material, which may have enhanced Cu endowment in this region. Late-magmatic, oxidised fluids derived from the younger A₂-type suite controlled Cu mobilisation and concentration, while Au behaved largely refractory. In general terms, it is postulated that source mixing in continental arcs is a first-order control of contrasting Cu and Au endowment and that sequential intrusion processes facilitate late-magmatic-hydrothermal mobilisation and concentration of specific metal assemblages.     

Voltammetric evidence for soluble FeS complexes in anoxic estuarine muds

Voltammetric methods using direct insertion of a gold-amalgam microelectrode with a sensitive, computercontrolled voltammeter detected soluble iron(II) sulfide, [FeS]_aq, in the porewaters of anoxic, sulfidic, fine-grained sediments from the Loughor Estuary, Wales. The voltammetric results are reproducible. Studies of cores stored in sealed, refrigerated containers for up to 21 d reveal no measurable oxidation. [FeS]_aq forms in this estuarine environment as a result of the dissolution of amorphous FeS, and appears to be involved in the formation of pyrite. [FeS]_aq makes no significant contribution to the total sulfide and iron contents of the sediment but could constitute an important component of the dissolved Fe(II) and S(−II) contents of the porewater. Mass balance calculations show pyrite forms in this system by the addition of sulfur to FeS rather than by the loss of iron from FeS. The overall process appears to involve [FeS]_aq as an intermediary. Although the porewaters of the Loughor Estuary sediments are iron-rich relative to seawater, the iron sulfide-forming process is iron-limited rather than sulfide-limited. Reactive iron is bound to sulfide rapidly in the sediment. After the reactive iron is bound to sulfide, additional sulfide produced is fixed as pyrite.