High-pressure neutron diffraction study on H–D isotope effects in brucite

A neutron powder diffraction study of hydrogenated and deuterated brucite was conducted at ambient temperature and at pressures up to 9 GPa, using a Paris–Edinburgh high-pressure cell at the WAND instrument of the ORNL High Flux Isotope Reactor. The two materials were synthesized by the same method and companion measurements of neutron diffraction were conducted under the same conditions. Our refinement results show that the lattice-parameters of the a axis, parallel to the sheets of Mg–O octahedra, decrease only slightly with pressure with no effect of H–D substitution. However, the c axis of Mg(OD)₂ is shorter and may exhibit greater compressibility with pressure than that of Mg(OH)₂. Consequently, the unit-cell volume of deuterated brucite is slightly, but systematically smaller than that of hydrogenated brucite. When fitted to a third-order Birch–Murnaghan equation in terms of the normalized unit-cell volume, values of the bulk modulus for hydrogenated and deuterated brucite (K ₀ = 39.0 ± 2.8 and 40.4 ± 1.3 GPa, respectively) are, however, indistinguishable from each other within the experimental errors. The measured effect of H–D substitution on the unit-cell volume also demonstrates that brucite (and other hydrous minerals) preferentially incorporate deuterium over hydrogen under pressure, suggesting that the distribution of hydrogen isotopes in deep-earth conditions may differ significantly from that in near-surface environments.     

Using helicopter electromagnetic data to predict groundwater quality in fractured crystalline bedrock in a semi-arid region, Northeast Brazil

Geostatistical modeling, using airborne and borehole electromagnetic data, was used to estimate electrical conductivity in groundwater within fractured paragneisses and migmatites in a semi-arid climate in northeastern Brazil. Despite the geologic heterogeneity of crystalline aquifers, the use of high resolution helicopter electromagnetic (HEM) data enabled the characterization of groundwater electrical conductivity where data from drilled wells were insufficient. The tacit assumption is that HEM measurements can be used to relate rock electrical conductivity to groundwater electrical conductivity. In this study, the HEM data were used as an external drift variable in non-stationary estimation and stochastic simulation to identify the variability of groundwater electrical conductivity. Validation tests, comparing predicted values for groundwater conductivity with measurements in new wells, confirmed the success of these models in locating fresh groundwater sources in crystalline bedrock.     

The effect of the "Prestige" oil spill on the plankton of the N-NW Spanish coast

Chlorophyll, primary production, zooplankton biomass and the species composition of phytoplankton and zooplankton were studied in 2003, after the Prestige shipwreck. The information obtained was compared to previous data series available for the area affected by the spill. A large data series on plankton variables for the N-NW Spanish coast existed, and therefore a realistic evaluation of the effects by comparison with the range of natural variability could be carried out. We emphasized the evaluation of impact during the spring bloom, the first important biological event after the spill. Some minor changes were observed occasionally, but they did not show any clear pattern and were more related to the natural variability of the ecosystem than to effect of the spill. Plankton community structure did not undergo any changes. Only a few species were more abundant during spring 2003 than in previous years. No significant changes were detected in the planktonic community during productive periods, such as the spring bloom and the summer blooms related to intrusions of East North Atlantic Central Waters. The lack of evidence of the effects of the spill on planktonic communities is discussed in terms of the characteristics of the fuel, the high dynamics of the water masses, the biological mechanisms through which the fuel from the surface waters is transferred to the sea floor and, particularly, the influence of the natural variability by means of large and meso-scale hydrographic processes in the area under study. At the present time it is not possible to determine any minor effects the spill may have had on the plankton owing to the great variability of the planktonic cycles and the short-term impact of the oil from the Prestige on the pelagic system.     

Degradation of Monoazo Pigments Red 53:1 and Red 48:2 by Fenton,Photo‐Fenton and UV/Peroxide Reactions

The degradation reactions of two monoazo pigments, namely, Red 53:1 and Red 48:2, by Fenton, photo‐Fenton and UV/H₂O₂ systems have been studied. The efficiencies of the Fenton reactions increased with temperature, but the formation of solid agglomerates was observed when the reactions were carried out above 50°C indicating a coagulant action of Fe⁺² or Fe⁺³. Photo‐Fenton reactions irradiated by sunlight presented the best rate constants for cleavage of the azo bond and the naphthalene rings. The UV/H₂O₂ system exhibited the highest efficiency with respect to the consumption of H₂O₂. The presence of a carbonyl group in the ortho position of the naphthol ring hampered the oxidation of pigment Red 48:2 by hydroxyl radicals. This finding may be explained in terms of the acceptor character of the COOH group, and suggests the formation of a complex containing two six‐membered rings between Fe⁺³ and the pigment molecule.     

Free rocking response of a regular stone masonry wall with equivalent block approach: experimental and analytical evaluation

The evaluation of the dynamic behaviour of rocking elements is directly correlated to the energy dissipated because of the impacts at the base interface, which can be represented by means of a coefficient of restitution. This schematization is commonly accepted as representative of the out‐of‐plane response of stone masonry walls. An experimental campaign (in a lab environment) aiming at assessing the value of this coefficient for a sacco granite masonry wall is presented in this work. The rocking motion at a predefined bed joint level was induced in the tested specimens in order to validate a novel test setup designed to assess the coefficient of restitution value by means of a realistic reproduction of the rocking behaviour of a single element, under the hypothesis of an infinitely stiff system above the bed joint level. As the main objective of the work was to assess the rocking behaviour of a masonry wall that looses energy at the impacts at a certain joint level, the flexural behaviour was not desirable and had to be avoided. For this purpose, a test setup based on the equivalent block approach was developed. In the final section of this work, comparisons between experimental and numerical results are presented together with some preliminary conclusions on the appropriate modelling strategy and the values of the coefficient of restitution to be used for the seismic assessment of the out‐of‐plane rocking behaviour of this type of sacco stone masonry walls. Copyright © 2013 John Wiley & Sons, Ltd.     

Solar irradiance and total ozone over El Arenosillo (Spain) during the solar eclipse of 3 October 2005

The ground track of the annular eclipse of 3 October 2005 crossed the Iberian Peninsula. The main objective of this work was to analyze the variability of the solar irradiance and the total ozone column during the course of this event at El Arenosillo (Southwestern Spain). For achieving this goal, two Kipp & Zonen broadband radiometers (one for measuring total solar irradiance and other for measuring ultraviolet erythemal solar irradiance), one NILU-UV multi-band instrument and one Brewer spectroradiometer were used in this work. Total irradiance (310–2800 nm), and ultraviolet erythemal radiation (UVER) were recorded at a high frequency of 5 s, showing a strong reduction (higher than 80%) of the irradiance at the maximum solar obscuration which was of 79.6%. The irradiance decrease during the course of the eclipse was positively correlated with the percentage of eclipse obscuration, showing a very high agreement (R²～0.99). The irradiance recorded at selected wavelengths from the NILU-UV instrument shows a more pronounced decrease in the UV irradiance at the lower wavelengths during the solar eclipse. Finally, the evolution of the total ozone column (TOC) derived from Brewer and NILU instruments during the eclipse presented an opposite behavior: while the Brewer derived TOC values increase about 15 DU, the NILU derived TOC values decrease about 11 DU. This opposite behavior is mainly related to an artifact in the spectral irradiances recorded by the two instruments.     

Seismotectonic versus man-induced morphological changes in a cave on the Arrábida chain (Portugal)

Abstract

Distinctions between cave morphologies originating from seismic or active tectonics and those generated by natural clastic breakdown or by human activity must be made using unambiguous interpretative criteria.

Easily accessible caves in particular, which may have been visited for centuries or millennia, or caves located near engineering works or quarries using great quantities of explosives, may have broken speleothems, breakdowns or detachment joints unrelated to seismic events or tectonic movements.

Zambujal cave lies near neotectonic and seismic structures associated with a Plio-Quatemary 200 m uplift of the Arrábida chain and has suffered impacts resulting from quarrying, followed by possible vandalism. It is thus an example for which it is difficult to decipher morphological agents as there is the possibility that identical forms have been generated by several causes, which may have repeated at different episodes of its evolution. However, a careful morphological interpretation makes it possible to accept the existence of two seismic episodes, an “ancient” one and a “modern” one. The detection of other episodes between these is only possible using absolute dating. © Elsevier, Paris     

An evaluation of solar radiation pressure strategies for the GPS constellation

The subtle effects of different Global Positioning System (GPS) satellite force models are becoming apparent now that mature processing strategies are reaching new levels of accuracy and precision. For this paper, we tested several approaches to solar radiation pressure (SRP) modeling that are commonly used by International GNSS Service (IGS) analysis centers. These include the GPS Solar Pressure Model (GSPM; Bar-Sever and Kuang in The Interplanetary Network Progress Report 42-160, 2005) and variants of the so-called DYB model (Springer et al. in Adv Space Res 23:673–676, 1999). Our results show that currently observed differences between GPS orbit solutions from the various IGS analysis centers are in large part explained by differences between their respective approaches to modeling SRP. DYB-based strategies typically generate orbit solutions that have the smallest differences with respect to the IGS final combined solution, largely because the DYB approach is most commonly used by the contributing analysis centers. However, various internal and external metrics, including ambiguity resolution statistics and satellite laser ranging observations, support continued use of the GSPM-based approach for precise orbit determination of the GPS constellation, at least when using the GIPSY-OASIS software.     

An evaluation of wave propagation simulations over a barred beach with a Boussinesq-type model

The FUNWAVE model is used for simulating simulation of monochromatic and irregular wave propagation in a channel with a bar-trough profile. FUNWAVE is based upon the extended Boussinesq equations. The study aims to analyze the model's performance when simulating shoaling, wave breaking and nonlinear interactions that are present in nearshore wave propagation. For that, high-order time domain statistics (root mean-square wave height, skewness, asymmetry and the kurtosis) of the model simulations and of the observations were compared along the whole channel. Also, a frequency domain analysis including standard spectral analysis and the bispectrum was carried out in selected points of the flume. The evaluation included the role of the wave breaking internal model parameters. The main conclusion is that, in general, the one-dimensional version of FUNWAVE simulates quite well the nonlinear transformation of a wave over a bottom with a bar-tough profile, for both regular and irregular wave conditions. The model reproduces the transformation of the wave shape, specially the increasing sharper wave crests and flatter troughs and also the lack of vertical symmetry with crests pitching forward, as it propagates along the domain. However, some differences persist after wave breaking, mainly due to the nature of the wave-breaking module. In this module, the energy dissipation is induced by the increase of viscosity, a rather simple mechanism, without the modification of the wave shape. Also, the energy dissipation develops in a smooth way which is appropriated for spilling breaking waves, but not for plunging breaking waves where the dissipation starts more abruptly.     

A snapshot of suspended sediment and fluid mud occurrence in a mixed-energy embayment, Tijucas Bay, Brazil

Along the southern Brazilian coast, Tijucas Bay is known for its unique muddy tidal flats associated with chenier plains. Previous field observations pointed to very high suspended sediment concentrations (SSCs) in the inner parts of the bay, and in the estuary of the Tijucas River, suggesting the presence of fluid mud. In this study, the occurrences of suspended sediments and fluid mud were examined during a larger-scale, high-resolution 2-day field campaign on 1–2 May 2007, encompassing survey lines spanning nearly 80 km, 75 water sampling stations for near-bottom density estimates, and ten sediment sampling stations. Wave refraction modeling provided qualitative wave energy estimates as a function of different incidence directions. The results show that SSC increases toward the inner bay near the water surface, but seaward near the bottom. This suggests that suspended sediment is supplied by the local rivers, in particular the Tijucas. Near-surface SSCs were of the order of 50 mg l⁻¹ close to the shore, but exceeded 100 mg l⁻¹ near the bottom in the deeper parts of the bay. Fluid mud thickness and location given by densimetry and echo-sounding agreed in some places, although being mostly discordant. The best agreement was observed where wave energy was high during the campaign. The discrepancy between the two methods may be an indication for the existence of fluid mud, which is recorded by one method but not the other. Agreement is considered to be an indication of fluidization, whereas disagreement indicates more consolidation. Wave modeling suggests that waves from the ENE and SE are the most effective in supplying energy to the inner bay, which may induce the liquefaction of mud deposits to form fluid mud. Nearshore mud resuspension and weak horizontal currents result in sediment-laden offshore flow, which explains the higher SSCs measured in the deeper parts of the bay, besides providing a mechanism for fine-sediment export to the inner shelf.