High-altitude charged aerosols in the atmosphere of Titan

Observations by several instruments onboard the Cassini spacecraft revealed the existence of heavy hydrocarbon and nitrile species with masses of several thousand atomic mass units in the ionosphere of Titan. These very large molecules are in fact aerosols. The goal of this paper is to compute the concentrations of the charged aerosols in the upper atmosphere (950-1200 km) of Titan. The charging of these aerosols has been studied using the charge balance equations, where positive ions, negative ions, electrons, neutral and charged aerosols are included. Number concentrations of charged aerosols are compared with those observed by the Cassini instruments. The present work estimates the aerosol mass density as 1-10 kg/m³, which is within the predicted range. The results show that the aerosols must be smaller than 10 nm in order to have reasonable agreement with observations by the Cassini Plasma Spectrometer.     

The fossil Coleoptera of the Two Creeks forest bed,Wisconsin

A 21-kg sample of plant detritus from the Two Creeks forest bed at the junction of Kewaunee and Manitowoc Counties, Wisconsin, has produced a small, but well-preserved fauna of Coleoptera, Hymenoptera, and Diptera. Among the Coleoptera the majority of Carabidae (ground beetles) indicate moderately moist to fairly dry, open ground conditions with a sparsely vegetated substrate. Another significant beetle group is represented by the Scolytidae (bark beetles) nearly all of which inhabit spruce. The restricted number of Coleoptera species (21) is believed to represent an in situ assemblage and is part of about 50 taxa. Most of the Coleoptera identified to the species level have a transcontinental distribution, with the exception of two carabids which are extreme western forms, and nearly all reside within the boreal forest. The beetles indicate that the mean July temperature at Two Creeks approximately 11,850 yr B.P. was 14° to 16°C.     

Les paléokarsts du Hainaut (Belgique)

Résumé

Les calcaires d’âge carbonifère de la province du Hainaut, en Belgique, presque toujours cachés par une couverture méso-cénozoïque et quaternaire sont intensément karstifiés.

Endokarsts et cryptokarsts caractérisent une morphologie karstique classique à laquelle s’ajoute une forme bien particulière d’altération en masse du calcaire que nous définissons sous le vocable de “fantôme de roche”.

Ces paléokarsts datent pour la majeure partie du Crétacé. Cependant, lorsque le manteau tertiaire et quaternaire recouvre directement le Paléozoïque et est plus ou moins perméable, le processus de karstification peut se poursuivre. Suite aux pompages industriels ou domestiques qui rabattent la nappe aquifère, une réactivation du processus karstique entraîne la formation de fontis à jour (appelés dans la région, puits naturels).

La localisation de ces formes karstiques cachées a une importance économique considérable, tant comme obstacle à l’exploitation et à la qualité de la pierre calcaire qu’à l’implantation des ouvrages d’art. Mais leur attrait scientifique ne cède en rien à l’impact économique. Les remplissages sédimentaires de ces paléokarsts constituent en effet des témoins irremplaçables de périodes continentales et permettent de cerner l’évolution paléogéographique locale avec la possibilité de reconstitution d’anciens réseaux hydrographiques.     

Diagenetic alterations in temperate shelf carbonates from southeastern Australia

Temperate shelf carbonates form in cool marine waters and have skeletal and mineralogical compositions which are different from their tropical counterparts. They commonly lack non-skeletal grains and are often composed of low- and high-magnesium calcite with subordinate aragonite. Many of the aragonitic components found in tropical carbonates, such as corals, ooids, blue-green algae and lime mud, are absent.

Temperate shelf carbonates undergo diagenesis in marine waters with lower carbonate saturation than do tropical carbonates, and are exposed to cool climates with moderate to low rainfall. Marine cementation is rare because of low carbonate saturations in the surrounding waters. However, aragonite and high-magnesium calcite cements have been reported forming under specialized conditions associated with biogenic precipitation, submarine methane and sulphate-reducing bacteria, and more commonly in the intertidal environment where evaporation has increased carbonate concentrations.

In Pleistocene and Tertiary temperate shelf carbonates from southeastern Australia, evidence of marine diagenesis is rare to absent. Diagenetic stabilization of aragonite and high-magnesium calcite has taken from 80,000 y to 1 My, or longer, during subaerial exposure. This is slower than rates reported from tropical climates. A general lack of aragonite in some facies within these temperate carbonates leads to a lack of secondary porosity and only sparse low-magnesium calcite cement, even after prolonged fresh-water diagenesis. However, with lengthy exposure and under the right climatic conditions, karstic solution and calcrete precipitation can occur.

In sequences containing siliciclastic clays, pyrite and glauconite, abundant iron is present in interstitial waters leading to the precipitation of ferroan calcite cements in the phreatic and shallow burial environments, and to the substitution of iron for magnesium in stabilizing high-magnesium calcite skeletal material.

A unique void-filling, micritic internal sediment occurs in discrete layers in many of the Tertiary temperate shelf carbonate sequences in southeastern Australia. This internal sediment is localized as a pore-filling material above permeability barriers such as fine-grained sediments or volcanics, and above paleo-water tables which formed during periods of subaerial exposure. It is a feature of the vadose zone and lithifies to form a dense micritic low-magnesium calcite cement with characteristic pink/brown coloration, often associated with erosion surfaces and nodule beds.

Dolomite is uncommon in the southeastern Australian temperate shelf carbonates. It forms associated with preferential fluid pathways or mixing zones. Ferroan dolomite forms in siliciclastic clay-rich carbonates in the shallow burial environment. The ubiquitous fine, evaporite-related dolomite so common in tropical carbonates is absent.     

Unexpected records of ‘deep‐sea’ carnivorous sponges Asbestopluma hypogea in the shallow NE Atlantic shed light on new conservation issues

Marine cave communities have been a continued source of ecological surprises, among other things because of their close ecological and evolutionary ties with the deep sea. The discovery of cladorhizid sponges, the deepest occurring poriferan family, in shallow Mediterranean caves in the 1990s was one such surprise, leading to the generally accepted hypothesis that the whole family was carnivorous, an unprecedented feeding mode for sponges. The recent observation of the cave species Asbestopluma hypogea in the Mediterranean bathyal, confirmed the view that some shallow caves can occasionally shelter otherwise deep‐dwelling species. Here we present new distribution data of A. hypogea, from deep Mediterranean locations, and for the first time from Atlantic locations. Among the new Atlantic records, the most surprising ones are located in three different geographic areas (Ria de Arousa, Groix Island and Cherbourg) of the NW European coasts, from the Iberian Peninsula to the English Channel, where A. hypogea reaches SCUBA depths (5–50 m), while not sheltered in marine caves. The carnivorous sponge however reaches its shallowest occurrence (5 m), in a small cave at Groix Island. The ecological significance of these discoveries, particularly the very patchy distribution and peculiar dynamics, are noteworthy, and the shallow occurrence of A. hypogea, together with other deep‐water or uncommon species, constitute unique assemblages that must be considered in conservation plans.     

Preliminary study on the preservation of giant clam (Tridacnidae) shells from the Balobok Rockshelter archaeological site,south Philippines

Tridacnidae shells, a valuable archive of past environments, are common in the Balobok Rockshelter archaeological site on Sanga‐Sanga Island in the south Philippines. This site was occupied during the mid‐Holocene (ca. 5000–8800 ¹⁴C yr B.P.), a period of Neolithic cultural expansion in the Philippines. This paper focuses on the preservation of two shell specimens, Hippopus hippopus and Tridacna maxima, unearthed from two mid‐Holocene layers within the rockshelter. The shells' mineralogy and microstructure (prismatic and crossed‐lamellar) were studied using micro‐Fourier transform infrared spectroscopy and scanning electron microscopy to determine if the samples were suitable as paleoenvironmental records. Both shells are still aragonitic but aragonite crystals of both microstructure types are partly dissolved. This dissolution, characteristic of meteoric water alteration, precludes their utility in paleoenvironmental geochemical studies. Nevertheless, these shells are abundant in archaeological sites in the region and may be better preserved in other depositional contexts; more studies on Philippine Tridacnidae shell diagenesis are needed. © 2011 Wiley Periodicals, Inc.