Magnetic anisotropy of calcite at room-temperature

The intrinsic room temperature magnetic properties of pure calcite were determined from a series of natural crystals, and they were found to be highly dependent on the chemical composition. In general, dia-, para-, and ferromagnetic components contribute to the magnetic susceptibility and the anisotropy of magnetic susceptibility (AMS). With a combination of magnetic measurements and chemical analysis these three contributions were determined and related to their mineralogical sources. The intrinsic diamagnetic susceptibility of pure calcite is − 4.46 ± 0.16 × 10^− 9 m³/kg (− 12.09 ± 0.5 × 10^− 6 SI) and the susceptibility difference is 4.06 ± 0.03 × 10^− 10 m³/kg (1.10 ± 0.01 × 10^− 6 SI). These diamagnetic properties are easily dominated by other components. The paramagnetic contribution is due to paramagnetic ions in the crystal lattice that substitute for calcium; these are mainly iron and manganese. The measured paramagnetic susceptibility agrees with the values calculated from the known concentration of paramagnetic ions in the crystals according to the Curie law of paramagnetic susceptibility. Substituted iron leads to an increase in the AMS. The paramagnetic susceptibility difference was found to correlate linearly with the iron content for concentrations between 500 and 10,000 ppm. An empirical relation was determined: (k₁ − k₃)^para (kg/m³) = Fe-content (ppm) × (1 ± 0.1) × 10^− 12 (kg/m³/ppm). The maximum susceptibility difference (Δk = k₁ − k₃) was found to be unaffected by iron contents below 100 ppm. Ferromagnetic contributions due to inclusions of ferromagnetic minerals can dominate the susceptibility. They were detected by acquisition of isothermal remanent magnetization (IRM) and their contribution to the AMS was separated by high-field measurements.     

Optimization strategies for sediment reduction practices on roads in steep,forested terrain

Many forested steeplands in the western United States display a legacy of disturbances due to timber harvest, mining or wildfires, for example. Such disturbances have caused accelerated hillslope erosion, leading to increased sedimentation in fish‐bearing streams. Several restoration techniques have been implemented to address these problems in mountain catchments, many of which involve the removal of abandoned roads and re‐establishing drainage networks across road prisms. With limited restoration funds to be applied across large catchments, land managers are faced with deciding which areas and problems should be treated first, and by which technique, in order to design the most effective and cost‐effective sediment reduction strategy. Currently most restoration is conducted on a site‐specific scale according to uniform treatment policies. To create catchment‐scale policies for restoration, we developed two optimization models – dynamic programming and genetic algorithms – to determine the most cost‐effective treatment level for roads and stream crossings in a pilot study basin with approximately 700 road segments and crossings. These models considered the trade‐offs between the cost and effectiveness of different restoration strategies to minimize the predicted erosion from all forest roads within a catchment, while meeting a specified budget constraint. The optimal sediment reduction strategies developed by these models performed much better than two strategies of uniform erosion control which are commonly applied to road erosion problems by land managers, with sediment savings increased by an additional 48 to 80 per cent. These optimization models can be used to formulate the most cost‐effective restoration policy for sediment reduction on a catchment scale. Thus, cost savings can be applied to further restoration work within the catchment. Nevertheless, the models are based on erosion rates measured on past restoration sites, and need to be updated as additional monitoring studies evaluate long‐term basin response to erosion control treatments. Copyright © 2006 John Wiley & Sons, Ltd.     

Dispersion and cost analysis of some finite difference schemes in one-parameter acoustic wave modeling

Given a precision threshold to be imposed on the group velocity error and a finite difference scheme for the acoustic wave equation, it is possible to determine time-step and grid-spacing in an optimal manner, i.e., so as to minimize the computational cost. Using this optimal cost as a criterion, it becomes easy to compare schemes for efficiency in homogeneous media. Heterogeneous media with constant density can be accommodated to a certain extent by minimizing the cost over a range of Courant numbers. Such analysis shows that, amongst the second-order Taylor series schemes in time, higher-order schemes are generally more efficient than lower-order schemes. However, this result does not extend to very high order schemes.     

Isotopic evidence for the magmatic and tectonic histories of the Carolina terrane: implications for stratigraphy and terrane affiliation

Establishing the age and crustal nature of exotic terranes and their underlying basements helps to determine their paleogeographic origin and tectonic histories. We present U–Pb ages of zircons and Sm–Nd whole rock isotopic data for volcanic and plutonic rocks of the Carolina terrane, one of several peri-Gondwanan terranes that were accreted to the margins of the circum-Atlantic continents during the Paleozoic. Volcanism in this subduction-related arc culminated in the eruption of the Morrow Mountain rhyolite, at ca. 540 Ma; thus, magmatism in the Carolina terrane ceased at the beginning of the Cambrian. The presence of inherited zircons and non-juvenile depleted mantle model ages of Carolina slate belt rocks favor a basement that is, at least in part, composed of evolved continental crust. Ages of inherited xenocrystic zircons cluster at ca. 1000, 2100 and 2500 Ma. These ages, in addition to volcanism at ca. 618–540 Ma, correlate best with well-known tectonic events in present-day northern South America. Specifically, the Orinoquian-Sunsas, the Trans-Amazonian and the Central Amazonian orogenic zones are likely candidates for potential basement correlatives to the Carolina terrane. Sm–Nd isotopic signatures vary significantly, but permit assimilation of Orinoquian age (1000 Ma) crust by magmas derived from the depleted mantle in a subduction (arc-related) setting. Our findings are also consistent with proposed correlations between the Carolina terrane and Avalonia which is likewise believed to have formed along the northern margin of present-day South America.     

First interactions with the hydrologic cycle determine pyrogenic carbon's fate in the Earth system

Fires produce an aromatic particulate residue commonly referred to as pyrogenic carbon (PyC). Particulate PyC is low density, high porosity, and is predominantly deposited on the soil surface in post-fire landscapes. These characteristics create a material that is prone to mobility, both vertically down the soil profile and laterally across the landscape even in low-relief landforms. Because of its tendency for lateral mobilization, we argue here that PyC's first interaction with water determines its environmental fate and persistence, not its interactions with soil minerals or microbes. PyC's first interactions with water determine: the amount of PyC that will enter the soil profile and experience microbial and geochemical alterations, whether it will be buried in depositional environments and stored on the landscape, or if it will be transported to streams and eventually to the ocean. Here we posit that this crucial first interaction with the hydrologic cycle occurs on the timescale of days to weeks, and therefore supersedes microbial decomposition as the primary control on PyC's environmental persistence. © 2020 John Wiley & Sons, Ltd.     

Assessing the significance of wet-canopy evaporation from forests during extreme rainfall events for flood mitigation in mountainous regions of the United Kingdom

There is increased interest in the potential of tree planting to help mitigate flooding using nature-based solutions or natural flood management. However, many publications based upon catchment studies conclude that, as flood magnitude increases, benefit from forest cover declines and is insignificant for extreme flood events. These conclusions conflict with estimates of evaporation loss from forest plot observations of gross rainfall, through fall and stem flow. This study explores data from existing studies to assess the magnitudes of evaporation and attempts to identify the meteorological conditions under which they would be supported. This is achieved using rainfall event data collated from publications and data archives from studies undertaken in temperate environments around the world. The meteorological conditions required to drive the observed evaporation losses are explored theoretically using the Penman–Monteith equation. The results of this theoretical analysis are compared with the prevailing meteorological conditions during large and extreme rainfall events in mountainous regions of the United Kingdom to assess the likely significance of wet canopy evaporation loss. The collated dataset showed that event Ewc losses between approximately 2 and 38% of gross rainfall (1.5 to 39.4 mm day⁻¹) have been observed during large rainfall events (up to 118 mm day⁻¹) and that there are few data for extreme events (>150 mm day⁻¹). Event data greater than 150 mm (reported separately) included similarly high percentage evaporation losses. Theoretical estimates of wet-canopy evaporation indicated that, to reproduce the losses towards the high end of these observations, relative humidity and the aerodynamic resistance for vapour transport needed to be lower than approximately 97.5% and 0.5 to 2 s m⁻¹ respectively. Surface meteorological data during large and extreme rainfall events in the United Kingdom suggest that conditions favourable for high wet-canopy evaporation are not uncommon and indicate that significant evaporation losses during large and extreme events are possible but not for all events and not at all locations. Thus the disparity with the results from catchment studies remains.     

High Arctic sea ice conditions influence marine birds wintering in Low Arctic regions

Ocean climate change is having profound biological effects in polar regions. Such change can also have far-reaching downstream effects in sub-polar regions. This study documents an environmental relationship between High Arctic sea ice changes and mortality events of marine birds in Low Arctic coastal regions. During April 2007 and March 2009, hundreds of beached seabird carcasses and moribund seabirds were found along the east and northeast coasts of Newfoundland, Canada. These seabird “wrecks” (i.e. dead birds on beaches) coincided with a period of strong, persistent onshore winds and heavily-accumulated sea ice that blocked bays and trapped seabirds near beaches. Ninety-two percent of wreck seabirds were Thick-billed Murres (Uria lomvia). Body condition and demographic patterns of wreck murres were compared to Thick-billed Murres shot in the Newfoundland murre hunt. Average body and pectoral masses of wreck carcasses were 34% and 40% lighter (respectively) than shot murres, indicating that wreck birds had starved. The acute nature of each wreck suggested that starvation and associated hypothermia occurred within 2–3 days. In 2007, first-winter murres (77%) dominated the wreck. In 2009, there were more adults (78%), mostly females (66%). These results suggest that spatial and temporal segregation in ages and sexes can play a role in differential survival when stochastic weather conditions affect discrete areas where these groups aggregate. In wreck years, southward movement of Arctic sea ice to Low Arctic latitudes was later and blocked bays longer than in most other years. These inshore conditions corresponded with recent climate-driven changes in High Arctic ice break-up and ice extent; coupled with local weather conditions, these ice conditions appeared to be the key environmental features that precipitated the ice-associated seabird wrecks in the Low Arctic region.