Rapid incorporation of lipids into macromolecules during experimental decay of invertebrates: Initiation of geopolymer formation

Diagenetic alteration is critical for the preservation of fossil cuticles of plant and animal origin and to the formation of kerogen. The process takes place over millions of years, but the stage at which it is initiated is not known. Laboratory decay experiments were carried out on shrimps, scorpions and cockroaches to monitor changes in the chitin–protein of the arthropod cuticle and associated lipids. The cockroach and scorpion exoskeleton remained largely unaltered morphologically, but the shrimp experienced rapid decomposition within a month, which progressed through the 44 week duration of the experiment as revealed using electron microscopy. Mass spectrometry and ¹³C NMR (nuclear magnetic resonance) spectroscopy revealed the association of an n-alkyl component with labile lipids, such as fatty acids with up to 24 carbon atoms, which were incorporated into the decaying macromolecule. The scorpion and cockroach cuticle did not reveal the incorporation of additional lipids, indicating that decay is important in initiating in situ lipid association. This experiment provides evidence that lipids can become associated with carbohydrate and proteinaceous macromolecules during the very early stages of decay, representing the first stage in the transformation process that contributes to the aliphatic rich composition ubiquitous in organic fossils and kerogen.     

A family of physically realizable perfect fluid spheres representing a quark–stars in general relativity

In the present article, a family of static spherical symmetric well behaved interior solutions is derived by considering the metric potential g ₄₄=B(1−Cr ²)⁻ⁿ for the various values of n, such that (1+n)/(1−n) is positive integer. The solutions so obtained are utilised to construct the heavenly bodies’ like quasi-black holes such as white dwarfs, neutron stars, quarks etc., by taking the surface density 2×10¹⁴ gm/cm³. The red shifts at the centre and on the surface are also computed for the different star models. Moreover the adiabatic index is calculated in each case. In this process the authors come across the quarks star only. Least and maximum mass are fond to be 3.4348M _Θ and 4.410454M _Θ along with the radii 21.0932 km and 23.7245 km respectively.     

The nature of the intranight variability of radio-quiet quasars

We select a sample of 10 radio-quiet quasars with confirmed intranight optical variability and with available X-ray data. We compare the variability properties and the broad-band spectral constraints to the predictions of intranight variability by three models: (i) irradiation of an accretion disc by a variable X-ray flux, (ii) an accretion disc instability, (iii) the presence of a weak blazar component. We concluded that the third model, e.g. the blazar component model, is the most promising if we adopt a cannonball model for the jet variable emission. In this case, the probability of detecting the intranight variability is within 20–80 per cent, depending on the ratio of the disc to the jet optical luminosity. Variable X-ray irradiation mechanism is also possible but only under additional requirement: either the source should have a very narrow Hβ line or occasional extremely strong flares should appear at very large disc radii.     

Multifrequency integrated profiles of pulsars

We have observed a total of 67 pulsars at five frequencies ranging from 243 to 3100 MHz. Observations at the lower frequencies were made at the Giant Metre-Wave Telescope in India and those at higher frequencies at the Parkes Telescope in Australia. We present profiles from 34 of the sample with the best signal-to-noise ratio and the least scattering. The general 'rules' of pulsar profiles are seen in the data; profiles get narrower, the polarization fraction declines and outer components become more prominent as the frequency increases. Many counterexamples to these rules are also observed, and pulsars with complex profiles are especially prone to rule breaking. We hypothesize that the location of pulsar emission within the magnetosphere evolves with time as the pulsar spins down. In highly energetic pulsars, the emission comes from a confined range of high altitudes, in the middle range of spin down energies the emission occurs over a wide range of altitudes whereas in pulsars with low spin-down energies it is confined to low down in the magnetosphere.     

Open-source support toward validating and falsifying discrete mechanics models using synthetic granular materials—Part I: Experimental tests with particles manufactured by a 3D printer

Acta Geotechnica - This article presents a new test prototype that leverages the 3D printing technique to create artificial particle assembles to provide auxiliary evidences that supports the...     

Rainstorm-generated sediment yield model based on soil moisture proxies (SMP)

This study develops improved Soil Moisture Proxies (SMP) based suspended sediment yield (SMPSY) models corresponding to three antecedent moisture conditions (AMCs) (i.e., AMC-I-AMC-III) by coupling the improved initial abstraction (I_a-λ) model, the SMA procedure and the SMP concept for modelling the rainfall generated suspended sediment yield. The SMPSY models specifically incorporate a watershed storage index (S) model to accentuate the transformation from storm to storm and to avoid the sudden jumps in sediment yield computation. The workability of the SMPSY models is tested using a large dataset of rainfall and sediment yield (98 storm events) from twelve small watersheds and a comparison has been made with the existing MSY model. The goodness-of-fit (GOF) statistics is evaluated in terms of the Nash Sutcliffe efficiency (NSE), and error indices, i.e., root mean square error (RMSE), normalized root mean square error (nRMSE), standard error (SE), mean absolute error (MAE), and RMSE-observations standard deviation ratio (RSR). The NSE values vary from 74.31% to 96.57% and from 75.21% to 91.78%, respectively for the SPMSY and MSY model. The NSE statistics indicate that the SMPSY model has lower uncertainty in simulating sediment yield as compared to the MSY model. The error indices are lower for the SMPSY model than the MSY model for most of the watersheds. These results show that the SMPSY model has less uncertainty and performs better than the MSY model. A sensitivity analysis of the SMPSY model shows that the parameter β is most sensitive followed by parameter S, α and A. Overall, the results show that the characterization of soil moisture variability in terms of SMPs and incorporation of improved delivery ratio and runoff coefficient relationship improves the simulation of the erosion and sediment yield generation process.     

Landscape transform and spatial metrics for mapping spatiotemporal land cover dynamics using Earth Observation data-sets

Analysis of Earth observation (EO) data, often combined with geographical information systems (GIS), allows monitoring of land cover dynamics over different ecosystems, including protected or conservation sites. The aim of this study is to use contemporary technologies such as EO and GIS in synergy with fragmentation analysis, to quantify the changes in the landscape of the Rajaji National Park (RNP) during the period of 19 years (1990–2009). Several statistics such as principal component analysis (PCA) and spatial metrics are used to understand the results. PCA analysis has produced two principal components (PC) and explained 84.1% of the total variance, first component (PC1) accounted for the 57.8% of the total variance while the second component (PC2) has accounted for the 26.3% of the total variance calculated from the core area metrics, distance metrics and shape metrics. Our results suggested that notable changes happened in the RNP landscape, evidencing the requirement of taking appropriate measures to conserve this natural ecosystem.     

Measurement of Kodaikanal White-Light Images – II. Rotation Comparison and Merging with Mount Wilson Data

Sunspot umbral positions and areas were measured for 82 years (1906–1987) of daily, full-disk photoheliogram observations at the Kodaikanal station of the Indian Institute of Astrophysics. The measurement technique and reduction procedures used were nearly identical to those used earlier for the reduction of Mount Wilson daily full-disk photoheliograms, covering an overlapping interval of 69 years. In this paper we compare the differential rotation of the Sun from the analysis of the Kodaikanal data with the Mount Wilson results. In addition, we analyze the data set formed by combining the data from the two sites for differential rotation. While doing this, it has become apparent to us that small, subtle optical effects at both sites produce systematic errors that have an influence on rotation (and other) results from these data. These optical effects are analyzed here, and corrections are made to the positional data of the sunspots from both sites. A data set containing the combined positional data of sunspots from both sites, corrected for these optical aberrations, has been constructed. Results for both sunspot groups and individual sunspots are presented. It is pointed out that optical aberrations similar to those found in the Kodaikanal data may also exist in the Greenwich photoheliograph data, because these two sets of solar images were made with similar telescopes.