Use of sedimentary diatoms from multiple lakes to distinguish between past changes in trophic state and climate: evidence for climate change in northern Germany during the past 5,000 years

Fossil diatoms from lake sediments have been used to infer both past trophic state and climate conditions. In Europe, climate reconstructions focused on northern and alpine regions because these areas are climatically sensitive and anthropogenic impact was low. In contrast, anthropogenic impact was often high in the central European lowlands, such as northern Germany, beginning in the Neolithic Age, ~3700 BC. Since that time, trophic state change was the main factor that affected diatom assemblages in central European lowland lakes. Therefore, it was considered difficult or impossible to identify climate changes in the region using sedimented diatoms. We used diatom assemblage changes, diatom-inferred total phosphorus concentrations and the relative abundance of planktonic diatoms from sediments of three lakes that differ in their location, size, morphology, catchment area and current trophic state to test whether we could distinguish between trophic state and climate signals over the past 5,000 years in northern Germany. In this study, changes in trophic state and climate were well differentiated. In the study lakes, relative abundance of planktonic diatoms seems to be linked to the length of lake mixing phases. Planktonic diatom abundance decreased during years with shorter mixing duration, and these shorter mixing times probably reflect colder winters. The diatom-inferred periods of short mixing phases from 1000 BC to AD 500 and from AD 1300 to 1800 coincide well with two known cooling phases in Europe and the North Atlantic region.     

Holocene and Pleistocene fringing reef growth and the role of accommodation space and exposure to waves and currents (Bora Bora,Society Islands,French Polynesia)

Holocene fringing reef development around Bora Bora is controlled by variations in accommodation space (as a function of sea‐level and antecedent topography) and exposure to waves and currents. Subsidence ranged from 0 to 0·11 m kyr^?1, and did not create significant accommodation space. A windward fringing reef started to grow 8·7 kyr bp , retrograded towards the coast over a Pleistocene fringing reef until ca 6·0 kyr bp , and then prograded towards the lagoon after sea‐level had reached its present level. The retrograding portion of the reef is dominated by corals, calcareous algae and microbialite frameworks; the prograding portion is largely detrital. The reef is up to 13·5 m thick and accreted vertically with an average rate of 3·12 m kyr^?1. Lateral growth amounts to 13·3 m kyr^?1. Reef corals are dominated by an inner Pocillopora assemblage and an outer Acropora assemblage. Both assemblages comprise thick crusts of coralline algae. Palaeobathymetry suggests deposition in 0 to 10 m depth. An underlying Pleistocene fringing reef formed during the sea‐level highstand of Marine Isotope Stage 5e, and is also characterized by the occurrence of corals, coralline algal crusts and microbialites. A previously investigated, leeward fringing reef started to form contemporaneously (8·78 kyr bp ), but is thicker (up to 20 m) and solely prograded throughout the Holocene. A shallow Pocillopora assemblage and a deeper water Montipora assemblage were identified, but detrital facies dominate. At the Holocene reef base, only basalt was recovered. The Holocene windward–leeward differences are a consequence of less accommodation space on the eastern island side that eventually led to a more complex reef architecture. As a result of higher rates of exposure and flushing, the reef framework on the windward island side is more abundant and experienced stronger cementation. In the Pleistocene, the environmental conditions on the leeward island side were presumably unfavourable for fringing reef growth.     

Significance of boulder shape,shoreline configuration and pre-transport setting for the transport of boulders by tsunamis

Research on tsunami-induced coarse-clast transport is a field of rising interest since such deposits have been identified as useful proxies for extreme-wave events (tsunamis, storm waves) that provide crucial information for coastal hazard assessment. Physical experiments are, beside in-situ observations, the foundation of our understanding of how boulders are transported by tsunamis and provide clues to the development of empirical equations and numerical models describing the processes and fundamental mechanics. Nevertheless, investigating tsunami-induced boulder transport is a comparatively young discipline and only a few experimental studies focusing on this topic have been published so far. To improve the knowledge on nearshore tsunami hydrodynamics, physical experiments utilizing real-world boulder shapes have been carried out simulating three different shore types in a wave flume. Crucial insights were gained into boulder transport hydrodynamics and data resulting from the experiments were analysed in an empirical, statistical, quantitative and qualitative manner. The regular cuboid boulder – one of the specific shapes used in the experiments – showed the longest transport distances compared to a complex, natural boulder and a flat cuboid boulder, but also significant fluctuations regarding the total transport distance. The experiments indicate a strong influence of the shore shape on boulder transport behaviour. Experimental setups of increased mean transport distances also led to a higher spreading of results. This spreading was further amplified between the idealized-shaped cuboid and the complex-shaped boulder, which is associated with a lower drag coefficient. Due to the highly sensitive boulder reaction to divergent experimental setups, the need to recognize boundary conditions overcoming commonly considered parameters (e.g. roughness or Flatness Index) in field studies and numerical models is underlined. Beside the strong influence of initial boulder submergence and alignment, both the boulder shape and shore type influence the boulder transport pattern, increasing the total transport distance by more than 350% in some cases. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

IMPACTS OF URBANIZATION ON SURFACE HYDROLOGY,LITTLE EAGLE CREEK,INDIANA, AND ANALYSIS OF LTHIA MODEL SENSITIVITY TO DATA RESOLUTION

Land-use change in urbanizing areas can significantly alter the hydrology of a watershed and can have serious impacts on wetland water balances, downstream flooding, and groundwater recharge. Most currently available models used in determining the hydrologic impacts of urbanization are not well suited to long-term hydrologic analysis or are too complex and data intensive for widespread practical application. The Long-Term Hydrologic Impact Assessment (LTHIA) model run on a Geographic Information System (GIS) is a relatively simple, user-friendly model that uses the Curve Number method to estimate changes in surface runoff between different stages of development. Application of the model to a large, rapidly urbanizing watershed near Indianapolis, Indiana, suggests that average annual runoff depths increased by more than 60% from 1973 to 1991, with even greater increases for some individual sub-basins. These results are consistent with runoff changes estimated from historical stream flow data in the watershed. A sensitivity analysis to determine minimum data requirements shows that a precipitation record length of 15 years or more is required to produce consistent results with LTHIA and that the highest possible resolution land-use and soils data should be used. The LTHIA model is now available on the Internet at http://www.ecn.purdue.edu/runoff. [Key words: hydrology, urbanization, modeling, GIS.]     

Single-crystal polarized FTIR spectroscopy and neutron diffraction refinement of cancrinite

We relate a single-crystal FTIR (Fourier transform infrared) and neutron diffraction study of two natural cancrinites. The structural refinements show that the oxygen site of the H₂O molecule lies off the triad axis. The water molecule is almost symmetric and slightly tilted from the (0001) plane. It is involved in bifurcated hydrogen bridges, with Ow···O donor–acceptor distances >2.7 Å. The FTIR spectra show two main absorptions. The first at 3,602 cm^?1 is polarized for E ⊥ c and is assigned to the ν₃ mode. The second, at 3,531 cm^?1, is also polarized for E ⊥ c and is assigned to ν₁ mode. A weak component at 4,108 cm^?1 could possibly indicate the presence of additional OH groups in the structure of cancrinite. Several overlapping bands in the 1,300–1,500 cm^?1 range are strongly polarized for E ⊥ c, and are assigned to the vibrations of the CO₃ group.     

The Amazon River headstream area in the Cordillera Chila,Peru: hydrographic,hydrological and glaciological conditions

Abstract

The source of the world's largest river has fascinated scientists and adventurers for a long time. Extensive studies have been undertaken in the unexplored Llogueta River valley, Cordillera Chila, to identify the main stream of the Amazon River. Analysis of the Lloqueta River network and measurements of its hydrographic and hydrometric characteristics are presented in this study. On the basis of the acquired data, the northern hillside of the Cordillera Chila massif, concretely the basins of four mountainous courses—the Carhuasanta, Apacheta, Ccaccansa and Sillanque rivers—should be regarded as the headwaters territory of the Amazon River. Factors influencing the river system—glaciers and soils—were examined for each catchment. Glacier retreat in the last 50 years has left perennial snowfields only in the highest part of the study area, resulting in modification of the headwater runoff regimes. Preliminary results are afforded by the continual automatic water-level monitoring of the Lloqueta River since June 2008. Our investigations have determined that all types of soil in the area could be classified into two main categories: hydromorphic soils or poorly developed cryic soils.

Citation Janský, B., Engel, Z., Kocum, J., ?efrna, L. & ?esák, J. (2011) The Amazon River headstream area in the Cordillera Chila, Peru: hydrographical, hydrological and glaciological conditions. Hydrol. Sci. J. 56(1), 138–151.     

Biogeochemistry and carbon mass balance of a coccolithophore bloom in the northern Bay of Biscay (June 2006)

Primary production (PP), calcification (CAL), bacterial production (BP) and dark community respiration (DCR) were measured along with a set of various biogeochemical variables, in early June 2006, at several stations at the shelf break of the northern Bay of Biscay. The cruise was carried out after the main spring diatom bloom that, based on the analysis of a time-series of remotely sensed chlorophyll-a (Chl-a), peaked in mid-April. Remotely sensed sea surface temperature (SST) indicated the occurrence of enhanced vertical mixing (due to internal tides) at the continental slope, while adjacent waters on the continental shelf were stratified, as confirmed by vertical profiles of temperature acquired during the cruise. The surface layer of the stratified water masses (on the continental shelf) was depleted of inorganic nutrients. Dissolved silicate (DSi) levels probably did not allow significant diatom development. We hypothesize that mixing at the continental slope allowed the injection of inorganic nutrients that triggered the blooming of mixed phytoplanktonic communities dominated by coccolithophores (Emiliania huxleyi) that were favoured with regards to diatoms due to the low DSi levels. Based on this conceptual frame, we used an indicator of vertical stratification to classify the different sampled stations, and to reconstruct the possible evolution of the bloom from the onset at the continental slope (triggered by vertical mixing) through its development as the water mass was advected on-shelf and stratified. We also established a carbon mass balance at each station by integrating in the photic layer PP, CAL and DCR. This allowed computation at each station of the contribution of PP, CAL and DCR to CO₂ fluxes in the photic layer, and how they changed from one station to another along the sequence of bloom development (as traced by the stratification indicator). This also showed a shift from net autotrophy to net heterotrophy as the water mass aged (stratified), and suggested the importance of extracellular production of carbon to sustain the bacterial demand in the photic and aphotic layers.     

Simulated diagenesis and catagenesis of marine kerogen precursors: Melanoidins as model systems for light hydrocarbon generation

Amino acids and sugars are principal constituents of marine organisms. The condensation of amino acids and sugars is one possible nonenzymatic, early diagenetic pathway for the incorporation of these compounds into more complex geopolymers. In this study, aqueous solutions consisting of l-lysine, l-histidine, l-arginine and d-(+)-glucose were heated (100°C) for up to 288 h. Portions of the melanoidin polymer isolated after heating were reheated in the presence of water (hydrous pyrolysis) for 72 h at 325°C. Reaction products were identified by GC and GC/MS. Stable isotopic (δ¹³C) and elemental analyses were used to follow thermal evolution.While the initial melanoidin was synthesized from a simple, four component system, the products generated during hydrous pyrolysis are of considerable complexity, and include straightchain and branched alkanes, alkadienes, alkynes, indole, dimethyl indane, ethyl phenol, quinoline, and xylenes, in addition to a multitude of as yet, unidentified components. Stable carbon isotopic values for the reactants and products correspond to trends observed for naturally generated geopolymers and light gases. Elemental analyses of the melanoidin prior and subsequent to hydrous pyrolysis indicate a kerogen evolution pathway similar to that observed for natural samples. Considering the intractable nature of kerogen, laboratory simulation studies of simple systems can provide an alternative approach for elucidating the origins of geopolymers and their potential for hydrocarbon generation.     

Dynamic adjustment of training sets (‘moving-window’ reconstruction) by using transfer functions in paleolimnology—a new approach

This paper presents a new method (moving-windows) that optimizes diatom-based paleolimnological reconstructions of past environmental conditions from supra-regional training sets. The moving-window method identifies the best number of nearest neighbours (window size) from a merged supra-regional EDDI and local (MV) training set (n = 429) for each fossil diatom assemblage and the best type of transfer function (ML, WA-PLS) based on the error statistic of each transfer function (highest cross-validated R ², lowest cross-validated average bias, maximum bias and RMSEP). At first we evaluated the moving-window approach by comparing measured TP-values with inferred TP-values using both the moving-window approach and the WA-PLS method. The relative errors of the moving-window approach were not significantly different for 208 samples that had an error <15 μg/l TP using the WA-PLS method. However, for the remaining 221 samples with errors >>15 μg/l TP using the WA-PLS method, the moving window approach significantly reduced the relative error of the inferred TP levels. Secondly, the moving- window approach was used to reconstruct epilimnetic total phosphorous (TP) for Lake Dudinghausen, Lake Rugensee, Lake Tiefer See and Lake Drewitzer See (Northern Germany) using both the supra-regional EDDI training set and a local training set from Northern Germany (MV training set). The moving-window inferred TP-levels of the four study lakes were compared with published reconstructed TP-values and with inferred TP-values based on the local MV training set. Overall, the moving-window and the published TP-trends agree well with each other. However, the moving-window reconstructions generally indicated lower TP-levels throughout the past ∼5,000 to 12,000 years, including past maxima. Thus, the moving-window method seems to generate more realistic absolute TP levels due to the optimized window size (highest number of modern analogues, best error statistics). The identification of more realistic absolute historic TP-values is important for the validation of reference conditions for inland waters. This study also demonstrates that a robust local training set may, similar to moving-window training sets, also lead to reliable reconstructions, if the geological settings of the local training set lakes and the study lakes are similar.