Trace ambient levels of particulate mercury and its sources at a rural site near Delhi

Atmospheric particle-bound mercury levels were measured in PM₁₀ aerosols (HgP) at a rural site (Mahasar, Haryana) during winter 2014–15 and summer 2015. The PM₁₀ HgP was determined by using Differential Pulse Anodic Stripping Voltammetry through standard addition methods while the trace metals were determined by using an Atomic Absorption Spectroscopy. The mass concentrations of HgP varied from 591 to 1533 pg/m³ with an average of 1009?±?306 pg/m³ during the winter, while the mass concentrations of HgP varied from 43 to 826 pg/m³ with an average of 320?±?228 pg/m³ during the summer. However, it is difficult to assess whether these levels are harmful or not because there is no standard value available as National Ambient Air Quality Standard. The higher concentrations of HgP during winters were possibly due to favourable local meteorological conditions for the stagnation of particulate matter in the lower atmosphere and the increased emissions from existing natural or anthropogenic sources, regional sources and long-range transportation. Relatively low concentrations of HgP during summer might be due to increased mixing heights as well as scavenging effect because some light to heavy rain events were observed during summer time sampling. However, among other metals determined, the concentration of HgP was the lowest during both the seasons. The study may be useful in assessing the health impacts of PM₁₀ HgP and other metals.     

Nonequilibrium chemical analysis of the coma of comet P/Stephan-Oterma

A computer code to calculate the time-dependent nonequilibrium chemistry taking place within the coma of a comet has been developed. This code incorporates 1249 chemical reactions involving 128 species. Models were fit to data on Comet P/Stephan-Oterma (A. L. Cochran and E. S. Barker, 1985, Icarus62, 72–81). It was shown that (1) HCN is the parent for CN; (2) C₂H₂ is a parent for C₂; (3) pure gas-phase chemistry with known species cannot adequately reproduce the observed C₃ but a single step process can; and (4) at least prior to perihelion, the vaporization rate seems to have been controlled by water vaporization.     

Spectroscopic diagnostics for the N III ion

Spectroscopic diagnostics for the Niii ion have been studied using an atomic model including the first eleven energy levels and taking account of various physical processes. New calculations for the line emissivities as a function of electron density and temperature have been carried out. Density-sensitive and temperature-sensitive line emissivity ratios are presented and their diagnostic applications to the solar atmosphere are discussed with the help of available observations.Paper presented at the IAU Colloquium 154 on Solar and Interplanetary Transients, Pune, 1995 January 23–27.     

Spectrophotometry of Pluto from 3500 to 7350 Å

We have obtained spectra of Pluto on six nights during February 1979 using the Cassegrain Digicon spectrograph on the 2.1-m Struve reflector and the IDS spectrograph on the 2.7-m reflector of McDonald Observatory. These spectra, with nominal resolution of 6–7 Å, have been reduced to relative fluxes. Relative albedos were then calculated using the solar irradiances of Arvesen et al. (1969). The spectra taken in the blue show no indication of the upturn in albedo at $\text{λ < 3800}\text{A}\text{?}$ previously reported by Fix et al. (1970). The lack of a uv upturn cannot be interpreted in terms of a Rayleigh scattering atmosphere unless the albedo of the underlying surface is known. From the lack of methane absorption at the wavelength of the 6190- or 7270-Å methane bands we derive an upper limit of 1–3 m-am of gaseous CH₄. The albedo curve has a constant slope between 3500 and 7300 Å. The only other solar system body which has this feature is an S-type asteroid.     

Geometric methods for estimating representative sidewalk widths applied to Vienna’s streetscape surfaces database

Space, and in particular public space for movement and leisure, is a valuable and scarce resource, especially in today’s growing urban centres. The distribution and absolute amount of urban space—especially the provision of sufficient pedestrian areas, such as sidewalks—is considered crucial for shaping living and mobility options as well as transport choices. Ubiquitous urban data collection and today’s IT capabilities offer new possibilities for providing a relation-preserving overview and for keeping track of infrastructure changes. This paper presents three novel methods for estimating representative sidewalk widths and applies them to the official Viennese streetscape surface database. The first two methods use individual pedestrian area polygons and their geometrical representations of minimum circumscribing and maximum inscribing circles to derive a representative width of these individual surfaces. The third method utilizes aggregated pedestrian areas within the buffered street axis and results in a representative width for the corresponding road axis segment. Results are displayed as city-wide means in a 500 by 500 m grid and spatial autocorrelation based on Moran’s I is studied. We also compare the results between methods as well as to previous research, existing databases and guideline requirements on sidewalk widths. Finally, we discuss possible applications of these methods for monitoring and regression analysis and suggest future methodological improvements for increased accuracy.     

Estimation of background levels of contaminants

Samples from hazardous waste site investigations frequently come from two or more statistical populations. Assessment of background levels of contaminants can be a significant problem. This problem is being investigated at the U.S. Environmental Protection Agency's Environmental Monitoring Systems Laboratory in Las Vegas. This paper describes a statistical approach for assessing background levels from a dataset. The elevated values that may be associated with a plume or contaminated area of the site are separated from lower values that are assumed to represent background levels. It would be desirable to separate the two populations either spatially by Kriging the data or chronologically by a time series analysis, provided an adequate number of samples were properly collected in space and/or time. Unfortunately, quite often the data are too few in number or too improperly designed to support either spatial or time series analysis. Regulations typically call for nothing more than the mean and standard deviation of the background distribution. This paper provides a robust probabilistic approach for gaining this information from poorly collected data that are not suitable for above-mentioned alternative approaches. We assume that the site has some areas unaffected by the industrial activity, and that a subset of the given sample is from this clean part of the site. We can think of this multivariate data set as coming from two or more populations: the background population, and the contaminated populations (with varying degrees of contamination). Using robust M-estimators, we develop a procedure to classify the sample into component populations. We derive robust simultaneous confidence ellipsoids to establish background contamination levels. Some simulated as well as real examples from Superfund site investigations are included to illustrate these procedures. The method presented here is quite general and is suitable for many geological and biological applications.     

Sealing Features of Fluid-Rock System and its Control on Acidic Dissolution in Cretaceous Sandstone Reservoirs, Kuqa Subbasin

The Cretaceous Bashijiqike Formation is the main gas-bearing strata in the northern structural deformation zone of Kuqa subbasin. The acidic dissolution of this formation arose at 5–4Ma, which corresponds to the late burial stage of the Bashijiqike Formation. Variability of interlayer due to rock composition is negligible. Differentiation of acidic dissolution in sandstones was controlled by difference in amount of exogenous acid fluid from underlying strata. For the absence of sedimentary and structural carrier system between the isolated sandstone reservoirs, most fluid-rock systems show relative sealing feature during later burial stage by sealing feature of formation pressure, geochemical characteristics of formation water and content of diagenetic products in sandstones. Variation of sealing effects for different fluid-rock systems is obvious. The pressure coefficient is inversely proportional to acidic dissolved porosity of sandstone reservoirs, indicating that the variation of sealing effects for fluidrock system mainly controls the differentiation of acidic dissolution.     

Seasonal Temperature and Precipitation Fluctuations in Selected Parts of Europe During the Sixteenth Century

The article in hand presents a comparative analysis of unweighted thermic and hygric index series of different European regions (northern Switzerland, Germany, the Czech Republic, northern Italy, ancient Hungary, Poland and Spain). Besides methodological aspects about the formation of indices, especially the progress as well as the question of similarity development of these series in the 16th century are discussed and shown on the balance sheet. It becomes evident that with respect to the temperature on the level of unweighted indices the European regions of Germany, the Czech Republic and Switzerland are very similar during all seasons. In winter and summer these correlations are especially evident, during the transitional seasons they are smaller. Larger differences exist between the central European core region and the adjacent areas of research. In principle, the hygric differences are larger than the thermic ones.In the course of the sixteenth century marked cooling phases occurred during all seasons with increasing accentuation. These phases were typical for the climate of the Little Ice Age. In addition to this long-term analysis, some outstanding years of extreme weather like those of 1540, 1573 and 1587 are presented, in the course of which questions of climatic impact are included. Finally, recent instrumental data was used to conduct an analysis that compared the similarities between the respective regions and the similarities between the empirical data and indices. On the one hand, this confirmed the spatial pattern, on the other hand the usability of the indices.     

Phenocryst-poor rhyolites of bimodal, tholeiitic provinces: the Rattlesnake Tuff and implications for mush extraction models

We consider the origin of rhyolites associated with tholeiitic basalt in bimodal provinces, as exemplified by the Rattlesnake Tuff of the High Lava Plains of eastern Oregon, in comparison to rhyolites associated with calcalkaline suites in light of recent models of extraction of rhyolite from crystal mush (Hildreth, J Volcanol Geotherm Res, 136:169–198, 2004; Bachmann and Bergantz, J Petrol, 45:1565–1582, 2004). The High Lava Plains encompass a strongly bimodal, tholeiite-rhyolite suite, spatially and compositionally related to the Snake River Plain and Yellowstone Plateau. In our assessment we draw the distinction between fractionation dominated processes to make rhyolites from rhyolites and processes required to make the parental rhyolite melt. New isotopic data and compositional zoning profiles in phenocrysts confirm that crystal fractionation dominated the generation of progressively more evolved, discrete rhyolites in the zoned Rattlesnake Tuff and are consistent with an origin of the least evolved high-silica rhyolites by partial melting of a mafic crust. While the most evolved rhyolites are compositionally virtually indistinguishable from those of calcalkaline suites, the parental rhyolites from bimodal suites are more Fe-rich than their calcalkaline counterparts. Oxygen isotope thermometry yields pre-eruptive temperatures of 860°C, in keeping with 800–880°C zircon saturation temperatures. High magmatic temperatures are common among rhyolites of bimodal suites, distinguishing them from cooler rhyolites of calcalkaline suites. Extraction of interstitial melt from a granodioritic mush cannot produce compositions of the Rattlesnake Tuff on the basis of major and trace element arguments (especially Fe, Ba, Sr, and Eu) and on the basis of temperature considerations. Chemically viable parental crystal mushes are syenite and alkali (A-type) granites for the production of all more evolved Rattlesnake Tuff rhyolites; ferro-dacitic mush is required for production of the least-evolved, parental Rattlesnake Tuff rhyolite. Paucity of such ferro-dacitic compositions in tholeiitic bimodal suites, especially compared to the abundance of dacitic (granodioritic) compositions in calcalkaline suites, argues against the mush extraction model for the parental rhyolite. Furthermore, rhyolites of bimodal suites lack associated voluminous eruptions of crystal-rich ignimbrite that might represent a parental mush, as exemplified by the “monotonous intermediate” Fish Canyon Tuff in calcalkaline suites. We conclude that extensive fractionation is common among rhyolites and may obscure their ancestry. Fe-rich parental rhyolites common in bimodal tholeiitic suites, as represented by Rattlesnake Tuff, may often be the result of partial melting of mafic to intermediate crust, in contrast to calcalkaline high-silica rhyolites that are related to voluminous suites of intermediate intrusive rocks where the pre-plutonic mush-extraction model works better. This paper constitutes part of a special issue dedicated to Bill Bonnichsen on the petrogenesis and volcanology of anorogenic rhyolites.     

Sedimentation of particulate matter in the Dona Paula Bay, West Coast of India during November to May 1995–1997

Data on hydrography, nutrients, suspended particles, and sedimented particles were collected at weekly intervals from November to May during 1995 to 1997 at a station in the coastal waters of Dona Paula Bay, India. Suspended and sedimented particles were analyzed for total suspended matter (SPM), total sedimented particulate matter (TPM), particulate organic carbon (POC), particulate organic nitrogen (PON), chlorophylla (chla), and diatom abundance. Variations in hydrography and nutrients influenced the quantity and composition of sedimented particles. The TPM, POC, PON, and chla fluxes showed small-scale seasonal variations and were higher in the summer (February to May) than in the winter (November to January). Resuspension of carbon accounted for approximately 25% of the gross POC and was highest in April 1997 (45%). The mean net POC flux was 197±90 mg C m⁻² d⁻¹ and accounts for 4.6% of the TPM. The average C∶N (w∶w) ratio of the sedimented material was 13.2±6.6. The POC:chla ratio was relatively higher in the sedimented material as compared to the suspended material. The particulate carbon reaching the bottom sediment was 39% of the primary production. The low organic carbon concentration (approximately 0.1% of dry sediment) in the sediments implies that about 98% of the sedimented carbon was either consumed at the sedimentwater interface or resuspended/advected before it was finally buried into the sediments.