Mechanism of arrested charnockite formation at Nemmara, Palghat region, southern India

The formation of arrested charnockite is an excellent example of structurally controlled channellised fluid flow along specific sites accompanied by selective elemental mobility and mineralogical changes. The present paper recognises and focuses study on three types of arrested charnockite formation from Palghat region, namely, shear-controlled, foliation parallel and boudin-neck types, and address their spatio-temporal relations to regional-scale charnoenderbite. The shear-controlled and foliation parallel types post-date deformation and migmatisation. The boudin-neck type, on the contrary, is coeval with partial melting and followed the path of cooling and decreasing water activity in the gneiss. K-feldspar veining around plagioclase and quartz, symplectitic intergrowth of biotite+quartz after orthopyroxene and K-feldspar, and fluid inclusion data suggests the presence of alkalic supercritical brine and low-density CO₂-rich fluid during charnockite formation. Charnockite domains developed following the breakdown of hornblende, biotite and quartz are characterised by a more or less pronounced depletion of Fe, Ca, Mg and Ti and trace elements Y and Zr, compared to their counterpart gneiss. REE spectra indicate a subtle depletion in the HREE near the centre of the charnockite domain. Although close-pair samples of gneiss–charnockite are isochemical, on a scale of a few millimetres, bi-directional element movement, related to the formation of new mineral was noted. It is postulated that arrested charnockite formation developed in situ on local scale within the granitic domains of the hornblende-biotite gneiss, in the presence of CO₂-rich fluids and alkalic supercritical saline brine. This process post-dated the time of regional granulite (charnoenderbite) and large regional scale retrogression and migmatisation.     

C-isotope Composition of Carbonates from Indravati Basin, India: Implications for Regional Stratigraphic Correlation

The Indravati Basin represents an unmetamorphosed and unfossiliferous sequence and shows a broad similarity in lithological association with other Purana Basins of Central India. The carbonates belonging to Indravati Basin have on average, moderately positive δ13 C values (up to +4.5). Numerous successions reported from other parts of world, show similar δ13 C values and contain evidence to suggest that the latest Mesoproterozoic to early Neoproterozoic period may represent an isotopically recognizable interval globally. The elevated δ13 C values of Indravati Basin are also correlatable with other Purana Basins in India including Upper Vindhyan Supergroup.     

Hydrography of the eastern Arabian Sea during summer monsoon 2002

Hydrographic observations in the eastern Arabian Sea (EAS) during summer monsoon 2002 (during the first phase of the Arabian Sea Monsoon Experiment (ARMEX)) include two approximately fortnight-long CTD time series. A barrier layer was observed occasionally during the two time series. These ephemeral barrier layers were caused byin situ rainfall, and by advection of low-salinity (high-salinity) waters at the surface (below the surface mixed layer). These barrier layers were advected away from the source region by the West India Coastal Current and had no discernible effect on the sea surface temperature. The three high-salinity water masses, the Arabian Sea High Salinity Water (ASHSW), Persian Gulf Water (PGW), and Red Sea Water (RSW), and the Arabian Sea Salinity Minimum also exhibited intermittency: they appeared and disappeared during the time series. The concentration of the ASHSW, PGW, and RSW decreased equatorward, and that of the RSW also decreased offshore. The observations suggest that the RSW is advected equatorward along the continental slope off the Indian west coast.     

Estimation of petrol and diesel adulteration with kerosene and assessment of usefulness of selected automobile fuel quality test parameters

Kerosene is common adulterant utilized for mixing with diesel. Five fuel-adulterant mixtures in different proportions by volume were prepared and individually tested for density and kinematic viscosity. The mixtures were administered to six light cargo vehicles and the tail pipe exhaust emission was tested for opacity value. No appreciable density variation at different levels of adulteration was observed. Density was within the prescribed value even at higher adulteration. Considerable decrease in kinematic viscosity, a departure from prescribed viscosity, was noted at higher adulteration level. The percent opacity value decreased sharply even at small level of adulteration. The probable amount of kerosene present as an adulterant in diesel dispensed at filling stations in Kathmandu city ranged between 35% and 50%. The observations suggest density test is not a good indicator of diesel adulteration. Kinematic viscosity and opacity value are useful diesel adulteration test parameters. Existing diesel adulteration warrants initiation of strict compliance regulation.     

An innovative priming system - emulsion-based booster

The mineral industry is leading towards a technology driven optimization process. Drilling and blasting are such unit operations in a mine, which can alter the balance sheet of the mine if not planned properly. The development, improvement and utilization of innovative technologies in terms of blast monitoring instruments and explosives technology are important for cost effectiveness and safety of mineral industries.

The ever-growing demand for minerals has compelled the industry to adopt large opencast projects using heavy equipment. This has necessitated use of a few hundred tonnes of explosives in each blast. The bulk delivered fourth generation explosives have solved the problem of explosive loading to a large extent as it provides improved safety in manufacturing, transportation and handling. Bulk delivered emulsion is non-explosive until gasification is complete and a large quantity of explosive can be transported and loaded into blast holes efficiently and with safety. The priming of bulk delivered explosives in Indian mines uses the conventional PETN/TNT-based boosters. The conventional booster possesses safety problems in terms of handling and use, so Indian Explosives Ltd has developed an emulsion-based booster (Powergel Boost).

This paper explores the potential of an emulsion-based booster used as a primer to initiate bulk delivered emulsion explosives used in mines. An attempt has been made at a comparative study between the conventional booster and the emulsion-based booster in terms of the initiation process developed and their capability of developing and maintaining a stable detonation process in the column explosives. The study has been conducted using a continuous velocity of detonation (VOD) measuring instrument, the VODMate two channel system manufactured by Instantel Inc. of Canada. During this study three blasts were monitored. In each blast two holes were selected for study, the first hole was initiated using a conventional booster while the other one used an emulsion-based booster. The findings of the study advocates that the emulsion-based booster is capable of the efficient priming of bulk delivered column explosive with a stable detonation process in the column.     

Geotechnical Properties of Low Calcium and High Calcium Fly Ash

In this paper, a comparative study has been made for physical and engineering properties of low calcium and high calcium Indian fly ash. The grain size distribution of fly ash is independent of lime content. Fly ash particles of size >75 μm are mostly irregular in shape whereas finer fractions are spherical for low calcium fly ash. For high calcium fly ash, chemical and mineralogical differences have been observed for different size fractions. Compared to low calcium fly ash, optimum moisture content is low and maximum dry density is high for high calcium fly ash. Optimum moisture content is directly proportional and maximum dry density is inversely proportional to the carbon content. The mode and duration of curing have significant effect on strength and stress–strain behavior of compacted fly ash. The gain in strength with time for high calcium fly ash is very high compared to that of low calcium fly ash due to presence of reactive minerals and glassy phase.     

Metamorphism of Proterozoic agpaitic nepheline syenite gneiss from North Singhbhum Mobile Belt, eastern India

Sushina nepheline syenite gneisses of Early Proterozoic North Singhbhum Mobile Belt (NSMB), eastern India suffered regional metamorphism under greenschist-amphibolite transitional facies condition. The Agpaitic Sushina nepheline syenite gneisses consist of albite, K-feldspar, nepheline (close to Morozewicz-Buerger composition), aegirine, biotite, epidote, piemontite, sodalite, cancrinite, natrolite and local alkali amphibole. Accessory phases include zircon, hematite, magnetite, rare pyrochlore and occasional eudialyte and manganoan calcic zirconosilicates. Mineral chemistry of albite, K-feldspar, nepheline, aegirine, alkali amphibole, natrolite and zirconium silicate minerals are described. The detailed textural features together with chemical data of some minerals indicate metamorphic overprint of these rocks. A new reaction is given for the genesis of metamorphic epidote. Metamorphic piemontite suggests greenschist facies metamorphism under high fO₂ (Hematite-Magnetite buffer). Up to 15.34 mol% of jadeite component in aegirine suggests that the metamorphic grade of the nepheline syenite gneiss reached at least to greenschist-amphibolite transitional facies or higher. Nepheline geothermometry suggests temperature of metamorphism <500 °C, which is consistent with greenschist facies metamorphism of surrounding chlorite-biotite-garnet phyllite country rock.     

Photodegradation of amaranth in aqueous solution catalyzed by immobilized nanoparticles of titanium dioxide

The use of suspensions of nanoparticles of titanium dioxide in photocatalytic degradation of dye solution has disadvantages of inconvenient separation of fine particles for reuse and limited penetration of light for effective degradation. These problems can be minimized by supporting titanium dioxide on various inert supports. The present study involves the preparation of immobilized titanium dioxide films by three different techniques and characterization of the prepared films. The immobilized films of nanocrystals of titanium dioxide were prepared using sol?Cgel technique, polyvinyl alcohol?Cformaldehyde binder and acrylic emulsion. The photocatalytic performance of the prepared films for degradation of amaranth dye has also been evaluated and compared. Combination of photodegradation and adsorption processes induces strong beneficial effects on removal of dyes. Addition of high adsorption capacity activated carbon to photoactive titanium dioxide in photodegradation of dyes improves the efficiency of dye mineralization. The activated carbon has also been immobilized along with titanium dioxide in the present work to examine the dual effect of photodegradation and adsorption in the removal of amaranth. The films formed with the help of polyvinyl alcohol?Cformaldehyde binder showed better dye degradation capabilities.     

Redox Condition,Nature and Tectono-magmatic Environment of Granitoids and Granite gneisses from the Karbi Anglong Hills,Northeast India: Constraints from Magnetic Susceptibility and Biotite Geochemistry

The Karbi Anglong hills (erstwhile Mikir hills) in northeast India are detached and separated from the Meghalaya plateau by a NW-SE trending Kopili rift. The Karbi Anglong hills granitoids (KAHG) and its granite gneissic variants belong to Cambrian plutons formed during Pan-African orogenic cycle, which commonly intrude the basement granite gneisses and Shillong Group metasediments. The KAHG can be broadly classified into three major granitoid facies viz., coarse grained porphyritic granitoid, medium grained massive non-porphyritic granitoid, and granite gneiss, which share a common mineral assemblage of plagioclase-K-feldspar-quartz-biotite±hornblende-apatite-titanite-zircon-magnetite but differ greatly in mineral proportion and texture. Modal mineralogy of KAHG, granite gneiss and basement granite gneiss largely represents monzogranite and syenogranite. The magnetic susceptibility (MS) of the KAHG, granite gneiss and basement granite gneiss varies widely between 0.11×10^-3 and 43.144×10^-3 SI units, corresponding to ilmenite series (<3×10^-3 SI; reduced type) and magnetite series (>3×10^-3 SI; oxidized type) of granitoids respectively. The observed MS variations are most likely intrinsic to heterogeneous source regions, modal variations of orthomagnetic and ferromagnetic minerals, and tectonothermal and deformational processes that acted upon these rocks. The primary and re-equilibrated compositions of biotites from the KAHG, granite gneiss and basement granite gneiss suggest calcalkaline, metaluminous (I-type) nature of felsic host magma formed in a subduction or post-collisional to peraluminous (S-type) host magma originated in syn-collisional tectonic settings, which were evolved and stabilized between FMQ and NNO buffers typically corresponding to reducing and oxidising magma environments respectively.     

Magnetite Dyke in Precambrian Banded Iron Formation,Singhbhum Craton,India: Mineralogical and Chemical Characteristics

Banded iron formation (BIF) of the Gorumahisani–Sulaipat–Badampahar (GSB) belt in Singhbhum Craton, India, consists predominantly of magnetite. This BIF is intruded by a magnetite dyke. The magnetite dyke is massive and compact with minor sulphide minerals while the host banded magnetite ore, a component of the BIF, shows thin lamination. The magnetite ore of the dyke is fine to medium grained and exhibits interlocking texture with sharp grain boundaries, which is different from the banded magnetite that is medium to coarse grained and show irregular martitised and goethitised grain boundaries. Relics of Fe–Ca–Mn–Mg‐carbonate and iron silicates (grunerite and cummingtonite) are observed in the banded magnetite. The intrusive magnetite is distinctly different in minor, trace and REE geochemistry from the banded magnetite. The banded magnetite contains higher amounts of Si, Al, Mn, Ca, Mg, Sc, Ga, Nb, Zr, Hf, Co, Rb and Cu. In contrast, the massive magnetite is enriched in Cr, Zn, V, Ni, Sr, Pb, Y, Ta, Cs and U with higher abundance of HREE. In the chondrite normalized plot, the massive magnetite shows a slight positive Eu anomaly while the banded ore does not show any Eu anomaly. Field disposition, morphology, mineralogy and chemistry show that the intrusive magnetite dyke is of igneous origin, while magnetite in BIF formed from a carbonate protolith through the process of sedimentation.