The degassing behavior of Au, Tl, As, Pb, Re, Cd and Bi from silicate liquids: Experiments and applications

We investigate the degassing of volatile heavy metals from natural basalt and dacite and synthetic rhyolite melts doped with Bi, Pb, Tl, Au, Re, Sb, Sn, Cd, Mo, As, Cu in Pt capsules over a range of temperatures (1200-1430 °C) exposed to air at 0.1 MPa. We also investigated the effects of ligands on degassing by adding known concentrations of Cl and S. During the experiments concentration gradients normal to the melt/gas interface arose for the trace metals Au, Tl, As, Cd, Re, Bi and Pb, as shown by measurements by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) on the quenched glasses. In contrast, erratic concentration gradients occurred for Cu, Mo, Sn, Sb due to the development of compositional cords in the glass for those elements. The diffusivities for Au, Tl, As, Cd, Re, Bi and Pb (in decreasing order of volatility) followed an Arrhenius relationship with log D at 1260 °C varying from −12 to −17. The addition of Cl and S were shown to increase by two-to five-fold the volatilities of all metals, with S having a more profound effect. Diffusivities from the experiments were applied in a bubble growth model to examine the behavior of Tl and Pb in volcanic gases. The Tl/Pb ratio in gases shows much greater variation than can be explained by partitioning and magma composition alone, with diffusion serving to drastically enrich or deplete the Tl/Pb of gases to values significantly different from that of the melt.     

A depositional history of particulate organic carbon in a floodplain lake from the lower Ob’ River, Siberia

Northern, high latitude soils have stored vast amounts of organic carbon (OC) in permafrost and peats for many millennia, however, climate change may mobilize and release this particulate OC (POC) to arctic rivers. Deltaic and floodplain lakes that receive fluvial sediments, primarily during the spring freshet, may provide records of such changes in riverine POC. Here, we examine properties of OC in a sediment core from a lake in the lower floodplain of the Ob’ River, west Siberia, to determine how the properties of OC deposited in this lake varied over many decades and to evaluate use of this sedimentary OC as a recorder of riverine POC load and properties. The core predates the most recent, dramatic changes in arctic climate and hence may serve as a benchmark against which to contrast future variations in fluvial POC discharge. Elemental, stable carbon and radiocarbon isotopic analyses, along with nuclear magnetic resonance (NMR) spectroscopy and molecular-level information (lignin phenol composition), indicate two major sources of OC to most of the sediments in this lake: plant-derived OC and algal-derived OC. However, a mixing model indicates that the nature and ¹⁴C content of these two sources change with depth in the sediment, resulting in three distinct layers: surface horizons, a “high-OC” layer and “mixing” horizons found above and below the high-OC layer. The plant-derived component is significantly aged throughout the core (¹⁴C ages of 1300-3900 years) and appears to derive from primarily local, tundra sources, whereas the algal component is modern. Our analysis suggests that the usual mode of OC deposition, as exemplified by the “mixing” and surface horizons, involved mixing of varying amounts of new algal production (35-65%) with aged permafrost- or peat-derived OC. This deposition was interrupted by an event, such as the collapse of a riverbank, which laid down the compositionally distinct “high-OC” layer in which plant-derived OC mixes with aged mineral-soil-derived OC without clear input from algae. The relative amounts of the plant and algal components in the lake sediments appear to be controlled primarily by local hydrological conditions rather than by river-wide processes, suggesting that comparison of sediment records from multiple lakes within a floodplain will be important to assess changes in POC export by arctic rivers. However, the flux and nature of the higher plant-derived OC may carry important information on the sources and dynamics of OC stored within the drainage basin.     

“I Still Have the Old Tradition”: The co-production of sweetgrass basketry and coastal development

Scholars working around the world have drawn attention to the physical and social changes associated with rural gentrification. Case studies from the United States have focused on how these patterns lead to the cultural displacement and replacement of land-based livelihoods, including non-timber forest product (NTFP) practices. Scholars have also documented the persistence of culturally and economically important NTFP practices in urban and suburban areas. We reconcile these disparate outcomes, displacement on the one hand and persistence on the other, by focusing on the social relationships that co-produce land use and livelihood change. Our case investigates how African American sweetgrass basketmakers in Mount Pleasant South Carolina negotiate the complex terrain of a rapidly urbanizing and gentrifying landscape.Analysis of interviews with basketmakers and participant observation at public meetings suggests that gathering materials and selling baskets occur across spaces not typically considered important for NTFP practices. Access to these sites depends upon continually reinforced and negotiated social relationships between a variety of actors. Findings illustrate that, by themselves, development and gentrification are insufficient for explaining livelihood and land use patterns that emerge in places experiencing intensive development. Using a co-production framework, we acknowledge the wide variety of complex trajectories and local power dynamics shaping land use and livelihoods. Findings also have implications for connecting global research on housing, employment, and demographic transitions associated with rural gentrification, to international NTFP research, which is increasingly turning to rural–urban interfaces for insights on how livelihoods are linked to land development and migration.     

High-temperature vesuvianite: crystal chemistry and surface considerations

A multi-methodical approach has been applied for characterizing the bulk and surface crystal chemical features of a high-temperature vesuvianite crystal from skarns of Mount Somma-Vesuvius Volcano (Naples, Italy). Vesuvianite belongs to the space group P4/nnc with unit cell parameters a = 15.633(1) Å, c = 11.834(1) Å and chemical formula (Ca_18.858 Na_0.028 Ba_0.004 K_0.006 Sr_0.005 □_0.098)_19.000 (Al_8.813 Ti_0.037 Mg_2.954 Mn_0.008 Fe_0.114²⁺ Fe_1.375³⁺ Cr_0.008 B_0.202)_13.511 Si_18.000(O_0.261 F_0.940 OH_7.799)_9.000. Structure refinement, which converges at R = 0.0328, demonstrates a strong positional disorder down the fourfold axes, indicating that the Y1 site is split into two positions (Y1A and Y1B) alternatively occupied. However, because of X4 proximity to Y1B and Y1A, X4 cannot be occupied if Y1B or Y1A are. Overall Y1 occupancy (Y1A + Y1B) reaches approximately 0.5, as common in vesuvianite and occupancy of Y1B site is extremely limited. Moreover, T1 position, limitedly occupied, accommodates the excess of cations generally related to Y position. A small quantity (0.202 apfu) of boron is sited at the T2 site that, like T1, is poorly occupied. The determination of the amount of each element on the (100) vesuvianite surface, obtained through X-ray photoelectron spectroscopy high-resolution spectra in the region of the Si_2p, Al_2p, Mg_1s, and Ca_2p core levels, evidences that a greater amount of aluminum and a smaller amount of calcium characterize the surface with respect to the bulk. Although both of these features require further investigation, we may consider the Al increase can be related to preferential orientation of Al-rich sites on the (100) plane. Furthermore, the surface structure of vesuvianite suggests that Al, Ca, and Mg cations maintain coordination features at the surface similar to the bulk. Silica, however, while presenting fourfold coordination, shows also a [1]-fold small coordinated component at binding energy 99.85 eV, due to broken Si–O bonds at the surface. The presence of eight- and nine-coordinated Ca cations is suggested by a large XPS feature resulting from the merging of Ca_2p3/2 and Ca_2p1/2 peaks at 348.45 and 352.05 eV, respectively.     

Morphological features of the Apennines foreland/accretionary-wedge boundary in the Ionian Sea

A detailed reconstruction of the morphology and recent tectonic activity of the Northern Ionian basin is provided on the basis of newly acquired high-resolution swath bathymetric and single and multichannel seismic profiles. The tectonic domains in this area are the Calabrian accretionary wedge and the Apulian foreland. The contact between the two domains, oriented NW–SE, morphologically coincides with a sea-bottom erosional channel (Taranto canyon) characterized on both sides by mass movements induced by slope instability. Along the accretionary wedge/Apulian foreland boundary three different morphological sectors have been recognized whose main characters are represented by a southward stepped increase of erosional canyon activity resulting in a pronounced slope acclivity and a superficial sediment instability. By means of seismic data we correlate the morphology of the sea-bottom to different contractional and flexural processes of the accretionary wedge/foreland system. The interaction between the different rheological domains in the subduction/collision processes could have also induced horizontal stress represented by areas of tectonic release. In an area like this, where very few detailed surveys have been carried out, this study represents the first attempt in correlating the recent tectonic activity to the morphological features and in locating possible slope instability that has to be evaluated for the positioning of offshore infrastructures.     

Use of radon isotopes,gamma radiation and dye tracers to study water interactions in a small stream in Brazil

In this study, natural (²²²Rn) and fluorescent (uranin) tracers were used to investigate the interactions between surface and subsurface waters in a small hydrographical basin located in the southeast region of Brazil. Levels of ²²²Rn were measured in 117 water samples with the use of an alpha solid-state detector. After the identification of the probable discharge sections along the stream, a measurement of the natural flows, upstream and downstream of these sections, was done with the use of a fluorimeter and fluorescent tracers. Also, scanning was done to verify a correlation between the natural gamma radiation and the ²²²Rn in the areas where its activity was higher. The results showed some sections where the ²²²Rn activity is more significant and contributed to the growth of the flows along the stream. It was possible to confirm a correlation between the discharge sections and the natural gamma radiation, what can be used as a preliminary approach to finding these sections in scenarios similar to the one studied here.     

The legacy of river channel modification in wadeable,lowland rivers: Exploring overdeep rivers in England

Many lowland fluvial systems are suspected to possess a morphological legacy from a long history of channel modifications as a consequence of limited energy and sediment supply to facilitate recovery. We explore the extent of such modifications using a regionally extensive dataset of physical habitat surveys compiled by non-specialist surveyors. Representative photographs for each surveyed site were used to quality check channel width, depth and bed grain size information derived from Modular River Physical (MoRPh) surveys. Following checking, 1659 surveys were retained for analysis from alluvial sites, almost entirely in England. The photographs were also inspected for evidence of clear ‘overdeepening’ that would preclude frequent overtopping of the lower bank top. Results indicated that almost one-third of the sites were overdeepened, that width-to-depth ratios defined using the active bed width showed stronger discrimination of overdeepening than bankfull width, that highly statistically significant identification of overdeepened channels was possible in channels up to 10 m wide and with only minimal differences attributable to channel bed materials. Stepwise regression analysis estimated relationships between channel width-to-depth ratios and channel size for overdeepened and non-overdeepened channels. We demonstrate that large data sets collected by numerous non-specialist surveyors can, with careful filtering, generate statistically robust results of geomorphological value over areas larger than is otherwise practicable. Furthermore, we reveal a notable legacy of overdeepening in the analysed lowland rivers, which presents a significant ‘hydromorphological’ management challenge.     

A prototype system for space–time assessment of rainfall-induced shallow landslides in Italy

In the last decades, physically based distributed models turned out rather promising to achieve the space–time assessment of shallow landslides at large spatial scale. This technical note deals with the application of a physically based stability model named Shallow Landslides Instability Prediction (SLIP), which has been adopted by the Department of National Civil Protection of Italy as a prototype early warning system for rainfall-induced shallow landslides on national scale. The model is used as a main methodology to create space–time shallow landslide susceptibility maps based on a simple deterministic slope-stability approach, combined with high-resolution rainfall information and geographic information system-based geospatial datasets. The safety factor as an index to measure slope instability is modeled as function of topographic, geologic, geotechnical and hydrologic variables. Although the main aim of this work was to prove the operational viability of such model on a nationwide domain and some simplification are adopted at this stage, hind cast tests on some relevant case histories of shallow landslides occurred between October 2009 and October 2011 showed that the model has skill in representing both timing and location of those shallow landslides.     

PheniX: a new vision for the hard X-ray sky

We are proposing a mission devoted to high energy X-ray astronomy that is based on a focusing telescope operating in the 1?C200?keV energy range but optimized for the hard X-ray range. The main scientific topics concern: Physics of compact objects: The proximity of compact objects provides a unique laboratory to study matter and radiation in extreme conditions of temperature and density in strong gravitational environment. The emission of high energy photons from these objects is far from being understood. The unprecedented sensitivity in the high energy domain will allow a precise determination of the non-thermal processes at work in the vicinity of compact objects. The full 1?C200?keV energy coverage will be ideal to disentangle the emission processes produced in the spacetime regions most affected by strong-gravity, as well as the physical links: disk?Cthermal emission?Ciron line?Ccomptonisation?Creflection?Cnon-thermal emission?Cjets. Neutron stars?Cmagnetic field?Ccyclotron lines: Time resolved spectroscopy (and polarimetry) at ultra-high sensitivity of AXP, milliseconds pulsars and magnetars will give new tools to study the role of the synchrotron processes at work in these objects. Cyclotron lines?Cdirect measurement of magnetic filed?Cequation of state constraints?Cshort bursts?Cgiant flares could all be studied with great details. AGN: The large sensitivity improvement will provide detailed spectral properties of the high energy emission of AGN??s. This will give a fresh look to the connection between accretion and jet emission and will provide a new understanding of the physical processes at work. Detection of high-redshift active nuclei in this energy range will allow to introduce an evolutionary aspect to high-energy studies of AGN, probing directly the origin of the Cosmic X-ray Background also in the non-thermal range (> 20?keV). Element formation?CSupernovae: The energy resolution achievable for this mission (<0.5?keV) and a large high energy effective area are ideally suited for the 44Ti line study (68 and 78?keV). This radioactive nuclei emission will give an estimate of their quantities and speed in their environment. In addition the study of the spatial structure and spectral emission of SNR will advance our knowledge of the dynamics of supernovae explosions, of particles acceleration mechanisms and how the elements are released in the interstellar medium. Instrumental design: The progress of X-ray focusing optics techniques allows a major step in the instrumental design: the collecting area becomes independent of the detection area. This drastically reduces the instrumental background and will open a new era. The optics will be based on depth-graded multi-layer mirrors in a Wolter I configuration. To obtain a significant effective area in the hundred of keV range a focal length in the 40?C50 meters range (attainable with a deployable mast) is needed. In addition such a mission could benefit from recent progress made on mirror coating. We propose to cover the 1?C200?keV energy range with a single detector, a double-sided Germanium strip detector operating at 80?K. The main features will be: (a) good energy resolution (.150?keV at 5?keV and <.5?keV at 100?keV), (b) 3 dimensional event localization with a low number of electronic chains, (c) background rejection by the 3D localization, (d) polarisation capabilities in the Compton regime.