Density and conductivity properties of Na−CO3−Cl−SO4 brine from Mono Lake, California, USA

Relationships among conductivity, temperature, total dissolved solids (TDS), and density were determined for hypersaline brine (TDS, 83 g kg⁻¹) from Mono Lake. A theoretical estimate of density based on ionic composition and calculated partial molar volumes compared well with actual measurements (difference, 390 ppm). However, an empirically derived equation of state based on temperature and conductivity provides the most accurate density estimates (residual errors, 190 ppm) and can be used with data collected with CTD profilers.     

Seasonal temperatures for the past ∼400 years reconstructed from diatom and chironomid assemblages in a high-altitude lake (Lej da la Tscheppa,Switzerland)

We analysed a 42 cm long sediment record from Lej da la Tscheppa, a high-altitude lake (2,616 m a.s.l.) in the Upper Engadine valley (Switzerland) for subfossil diatoms, chironomids and pollen. The chronology of the top 21 cm of the record was established using ²¹⁰Pb analysis using a constant-rate-of-supply model, and validated with ¹³⁷Cs measurements and the content of spheroidal carbonaceous particles. A tentative chronology for the lower part of the core was obtained through extrapolation of the sedimentation rates in the uppermost part of the record. Pollen assemblages in the record reflect regional changes in forestation and land-use patterns in the Upper Engadine valley and show no evidence of significant local human activity in the lake’s catchment. Diatom assemblages record a distinct increase in planktonic taxa since the early 19th century, suggesting a decrease in the duration of ice-cover. In contrast, chironomid assemblages remained stable during a large part of the record. We applied an established chironomid-based July air temperature transfer function and a newly developed diatom-based spring air temperature transfer function to reconstruct past seasonal air temperature changes at Lej da la Tscheppa. The reconstructions indicate a diatom-inferred warming trend in spring temperatures during the past ca. 400 years, whereas chironomid-inferred summer temperatures suggest a slight cooling trend. These biota-based reconstructions are in good agreement with the centennial-scale temperature trend in an independent reconstruction of regional temperatures in the Upper Engadine region based on instrumental records and documentary proxy evidence from the Alps. Our results suggest that, in high-altitude lakes, independent chironomid- and diatom-based seasonal temperature reconstruction is possible and can be successfully used to track seasonal temperature trends.     

A mass ratio limit for primordial black holes

We augment our scenario for the formation of astronomical objects from macroscopic superstrings by the assumption that the central matter keeps its identity in the fragmentation. From the condition that the angular momentum per mass squared of this matter should be less than the Kerr limit G/c, we obtain upper limits for the ratio of the mass of central black holes M(BH) to the mass M of the host object. This limit is M(BH)/M ≈ 0.001, and, expressed in observed quantities, approximately M(BH)/M ≈ σ²/(v · c) where σ is the r.m.s. velocity, v the rotational velocity and c the velocity of light. The valuesM(BH) agree with the observed behaviour both in order of magnitude and in the variation with velocity dispersion. (© 2003 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Dynamical attitude model for Gaia

The Dynamical Attitude Model (DAM) is a simulation package developed to achieve a detailed understanding of the Gaia spacecraft attitude. It takes into account external physical effects and considers internal hardware components controlling the satellite. The main goal of the Gaia mission is to obtain extremely accurate astrometry, and this necessitates a good knowledge of Gaia’s behaviour as a spinning rigid body under the influence of various perturbations. This paper describes these perturbations and how they are modelled in DAM.     

Observation of Precipitating Systems over Complex Orography with Meteorological Doppler Radars: A Feasibility Study

Summary  This paper concerns the use of airborne or ground-based Doppler radars to observe precipitating systems over complex orography. As nearly all of the previous experiments involving Doppler radars were conducted over flat surfaces over the continents or the oceans, new techniques are needed firstly to separate ground clutter from meteorological signal and, in the case of airborne Doppler observations, to deduce navigational errors. Secondly, it is necessary to take the atmospheric circulation induced by orography into account in the three-dimensional wind field analysis. Variational techniques are presented to solve these problems. The proposed methods are tested with simulated ground-based and airborne Doppler radar observations for analytic flows over analytic terrains and for numerically simulated wind and reflectivity fields for the Brig event (22 September 1993) of heavy precipitation over the southern flank of the Alps (Cosma and Richard, 1998), and with actual airborne Doppler data relative to weak snow showers over the Rocky Mountains on 12 March 1995. Received March 22, 1999/Revised June 1, 1999     

Geocentre motion from the DORIS space system and laser data to the Lageos satellites: comparison with surface loading data

Surface mass redistribution within the Earth system, especially in the atmosphere, oceans, continents and ice sheets, causes the position of the centre of mass to vary in a reference frame attached to the solid Earth. Space techniques are now precise enough to measure the centre of mass motion. Here we present a determination of the centre of mass coordinates at regular monthly intervals using DORIS data on SPOT‐2, SPOT‐3 and Topex–Poseidon (1993–1997) and laser data on Lageos‐1 and Lageos‐2 (1993–1996). The amplitude and phase of the space‐geodesy‐derived annual cycle for each coordinate are further compared to estimates based on surface mass redistribution at the Earth surface derived from various climatic data sources: surface pressure, soil moisture, snow depth and ocean mass variations.     

Climatic variability in the Late Copper Age: stable isotope fluctuation of prehistoric Unio pictorum (Unionidae) shells from Lake Balaton (Hungary)

Geochemical records of bivalve shells have been increasingly studied in the last decade to obtain information on climate conditions. In this paper we present stable isotope compositions of living and prehistoric shells of freshwater mussels (Unionidae) and their relationships with climate conditions in a shallow lake environment of Lake Balaton, West-Central Hungary. Physical conditions and stable oxygen isotope compositions of lake water samples were monitored where living bivalves were collected. Comparisons between seasonal variations in ambient temperature, water composition and within-shell isotopic variations indicate that the shells of Unio pictorum do reflect local changes at high resolution and thus can be used to study past conditions. Additionally, shells covering the last two decades were gathered at several locations along the lake in order to determine spatial and temporal variations in the shells’ isotopic compositions as a function of weather conditions. As an application, prehistoric shells collected in archaeological excavations were analysed in order to study past environmental variations. Climate variations during the Late Copper Age (5460–4870 cal. yr BP) have been assumed on the basis of geomorphological and archaeozoological observations at the site Balatonkeresztúr-Réti-dűlő (south of Lake Balaton), that suggested increasing humidity as a cause of changes in settlement location and domestic livestock husbandry. Stable carbon and oxygen isotope compositions of prehistoric bivalve shells were analyzed from excavations representing five archaeological subphases (Boleráz subphase, 5460–5310 cal. yr BP; two transitional subphases around 5310 cal. yr BP; Early Classic subphase, 5310–5060 cal. yr BP; Late Classic subphase, 5040–4870 cal. yr BP). The analyses revealed significant negative C and O isotope shifts in the transitional subphases relative to the earlier and later subphases. The isotopic variations indicate that the local climate became relatively wet and possibly cold around 5310 cal. yr BP, then it returned to drier (and likely warmer) conditions during the Classic subphases. This interpretation is in agreement with previous studies on climate changes related to the “5.3 ky event” in the European continental area and the North Atlantic Region, indicating an Atlantic influence in the Carpathian Basin.     

Local‐government data sharing: Evaluating the foundations of spatial data infrastructures

This paper presents a typology of local‐government data sharing arrangements in the US at a time when spatial data infrastructures (SDI) are moving into a second generation. In the first generation, the US National Spatial Data Infrastructure (NSDI) theoretically involved a pyramid of data integration resting on local‐government data sharing. Availability of local‐government data is the foundation for all SDI‐related data sharing in this model. However, first‐generation SDI data‐sharing activities and principles have gained only a tenuous hold in local governments. Some formalized data sharing occurs, but only infrequently in response to SDI programmes and policies. Previous research suggests that local‐government data sharing aligns with immediate organizational and practical concerns rather than state or national policies and programmes. We present research findings echoing extending these findings to show that local‐government data sharing is largely informal in nature and is undertaken to support existing governmental activities. NSDI principles remain simply irrelevant for the majority of surveyed local governments. The typology we present distinguishes four distinct types of local‐government data sharing arrangements that reflect institutional, political, and economic factors. The effectiveness of second generation, client‐service‐based SDI will be seriously constrained if the problems of local government take‐up fail to be addressed.     

Redetermination of the transformation enthalpies of the xanthoconite–proustite, pyrostilpnite–pyrargyrite and trechmannite–smithite phase transitions

 We report here refined values of the transformation enthalpy for xanthoconite to proustite (54.81 kJ/mol) and pyrostilpnite to pyrargyrite (40.32 kJ/mol). Additionally, the enthalpy for the transformation of trechmannite to smithite (5.82 kJ/mol) has been determined. The refinement was possible by taking into account a previously unknown dependence of electrochemical signals on the amount of substance undergoing the reduction process. Received December 21, 1995/Revised, accepted June 29, 1996