Waldsteinit

Ohne Zusammenfassung     

Der Tektonische Bau der Ostflanke der Patagonischen Kordillere Südlich 46ℴ S-Breite

Zusammenfassung Die Patagonisdie Kordillere weist südlich des 46. Breitengrades eine durch tertiäre Bewegungen bestimmte Struktur auf. Es lassen sich auf der Ostflanke 2 Zonen unterscheiden. Innere Zone: Falten- und Bruchstruktur in Jura-Kreide-Sedimenten. Den Ostrand bildet die äußere Zone, die aus leicht gefalteten Sedimenten der Oberkreide und des Alttertiärs besteht; sie geht nach Osten in die außerandine, hohe Meseta Central Über, oder aber sie ist von Längsbrüchen begrenzt.     

High-pressure X-ray study of LiCrSi2O6 clinopyroxene and the general compressibility trends for Li-clinopyroxenes

High-pressure single-crystal X-ray diffraction measurements of synthetic LiCrSi₂O₆ clinopyroxene (with space group P2₁/c) were performed in a diamond-anvil cell up to 7.970 GPa. No phase transition has been observed within the pressure range investigated, but the elastic behavior at lower pressures (up to ~2.5 GPa) is affected by an anomalous softening due to the proximity of the phase transition to the HT-C2/c phase at 330 K and at ambient pressure. A third-order Birch–Murnaghan equation of state fitted to the compression data above 2.5 GPa yields a bulk modulus K _T0 = 93(2) GPa and its first derivative K′ = 8.8(6). The structural data measured up to 7.970 GPa confirm that the space group P2₁/c is maintained throughout the whole pressure range investigated. The atomic parameters, obtained from the integrated diffraction intensities, suggest that the Li coordination polyhedron changes its coordination number from 5 to 6 at 6–7 GPa by means of the approach of the bridging O atom, related to the increased kinking of the B tetrahedral chain. Furthermore, at higher pressures, the structural evolution of LiCrSi₂O₆ provides evidence in the variation of kinking angles and bond lengths of a potential phase transition above 8 GPa to the HP-C2/c space group. A comparison of the Li-clinopyroxenes (M1 = Cr, Al, Sc, Ga, Mg + Fe) previously investigated and our sample shows that their elastic behavior and structural mechanisms of compression are analogous.     

Ornithogenic weathering of an ultramafic plutonic rock: St. Peter and St. Paul Archipelago,Central Atlantic

A phosphatic alteration rind is described comprising a leucophosphite crust above a phosphatised substrate of serpentinized peridotite from an exceptionally isolated location experiencing high rainfall conditions. The formation of the rind is intimately linked to the deposition and subsequent leaching of guano associated with the high concentration of seabirds that nest on the islands and its transformation into a ‘weathering rind’. The favoured pathway into the substrate appears to be along a pre-existing microfracture network, via the alteration of its carbonate infill into soluble apatite. This apatite is only retained within the protected environment of the microfracture network. Surrounding the network, there is evidence of the continued inward migration of the leachate into the surrounding peridotite resulting in its gradual phosphatisation in the form of a ‘halo’ around individual fractures. On the exposed rock surface, the consequence of the reaction between the guano leachate and the underlying substrate is its transformation into a ‘weathering rind’ composed principally of leucophosphite. It appears that the widespread formation of a phosphate crust is constrained by continual surface loss in a high energy, salt-rich maritime environment exposed to extensive overwash, wave attack and ultimately erosion.     

Recent progress on the Columbus Project and the Miror Laboratory program

This paper summarizes recent advances on the Columbus Project telescope and in the University of Arizona Mirror Lab. The Columbus telescope structure has been re-optimized to allow rapid changes between foci, while still maintaining high rigidity. Room has been made to translate secondary and tertiary spiders out of the light path to the center. A bill allowing construction of the telescope on Mt. Graham, Arizona, has been passed by Congress and signed into law. Two alternative enclosure designs, one with a co-rotating building and a second which opens like a flower, are being explored.A common baseline design for the 8 m honeycomb mirrors for both the Columbus and Magellan telescopes has been developed. It has stiffness comparable to that of the Palomar 200 inch mirror. The Mirror Lab has successfully cast two 3.5 m honeycomb blanks and expects to begin casting at the 6.5 and 8 m scale at the end of 1990. Interferometric tests of the Vatican f/1 1.8 m borosilicate honeycomb mirror show good stability of figure with the air jet ventilation system. A 60 cm stressed lap has been completed, and will be used to parabolize this mirror which is now polished as an f/1 sphere. Plans for a polishing facility to house two 8 m machines and a test tower are complete, with construction starting in April 1989.Paper presented at the Symposium on the JNLT and Related Engineering Developments, Tokyo, November 29–December 2, 1988.     

Tilting and distortion of CaSnO<Subscript>3</Subscript> perovskite to 7 GPa determined from single-crystal X-ray diffraction

The structural changes of CaSnO₃, a GdFeO₃-type perovskite, have been investigated to 7 GPa in a diamond-anvil cell at room temperature using single-crystal X-ray diffraction. Significant changes are observed in both the octahedral Sn–O bond lengths and tilt angles between the SnO6 octahedra. The octahedral (SnO6) site shows anisotropic compression and consequently the distortion of SnO6 increases with pressure. Increased pressure also results in a decrease of both of the inter-octahedral angles, Sn–O1–Sn and Sn–O2–Sn, indicating that octahedral tilting increases with increasing pressure, chiefly equivalent to rotation of the SnO6 octahedra about the pseudocubic <001>_p axis. The distortion in the CaO12 and SnO6 sites, along with the octahedral SnO6 tilting, is attributed to the SnO6 site being less compressible than the CaO12 site.Acknowledgments The authors acknowledge with gratitude the financial support for this work from NSF grant EAR-0105864. Ruby pressure measurements were conducted with the Raman system in the Vibrational Spectroscopy Laboratory in the Department of Geosciences at Virginia Tech with the help of Mr. Charles Farley.     

美国国家级干旱监测业务产品介绍

美国需要改进干旱监测与评估方法。干旱是代价昂贵的自然灾害(联邦应急管理局(FEMA),1995;W ilhite,2000),但经常被评估和预报产品的开发者忽略。相比于其他灾害,干旱表现得更模糊并且不适合用传统的评估或预报方法,它相对缓慢的发生以及其影响的复杂性,需要有一套新的方法来对它进行评估。干旱监测和预报技术的提高会使我们为应对干旱灾害做更好的准备工作,进行更好的应对实践,从而减少社会对干旱及其影响的脆弱性。为追踪和展示全美国干旱的程度、空间范围以及其影响,开发了新的干旱监测工具,研发了每周发布的国家级干旱监测业务产品(th…     

The differential system method for parameter identification; unconfined aquifer case

We present the applicability of differential system (DS) method for identification of hydraulic conductivity and effective porosity in a phreatic aquifer. In the original setting, the first step of the DS system is to solve an overdetermined algebraic system in the least squares sense. A natural extension of the method is to pose a least squares problem in an appropriate functional space. We show an improvement of the identification by considering the least square problem in the space of square integrable functions in the time variable for a finite interval.