Seismic evidence for preservation of the Archean Uchi granite–greenstone belt by crustal-scale extension

In the westernmost Superior Province of Canada, the east–west alignment of granite–greenstone belts and the adjacent, highly deformed gneiss belts led to the first proposals that plate tectonics existed before 2.5 Ga ago, with the belts thrust against one another by east–west-oriented subduction zones. Here, we present seismic reflection data, which demonstrate that in this region the present juxtaposition of the Uchi granite–greenstone belt and the North Caribou gneiss terrane occurred along a late southeast-dipping extensional shear zone that extends from the surface into the lower crust. The preservation of the Uchi belt and probably the English River metasedimentary belt is directly related to their dropping along extensional shear zones, which limited subsequent erosion. The relative lateral transport of these greenstone rocks implies that they were neither derived from the immediately underlying crust, nor preserved by vertical crustal movements as might occur in the absence of plate tectonics. Extension may have been associated with the emplacement of mantle-derived magmas at 2700 Ma, which has been linked to slab break-off or lithospheric delamination, making the extension approximately coeval with local gold mineralisation. Since crustal-scale faults can facilitate the circulation of gold-bearing fluids, we suggest that greenstone rocks preserved in the hanging walls of syn- to post-accretion extensional shear zones may preferentially host Archean lode-gold deposits. In the westernmost Superior Province, our seismic observations imply that some of the late structures in the well-developed belts defined by surface mapping arose through the collapse of a collage of laterally accreted terranes.     

Gas exchange responses of a desert herbaceous perennial to variable sunlight in contrasting microhabitats

Over the course of a day, aridland plants experience a range of incident photosynthetic photon flux (PPF) spanning three orders of magnitude. Rapid photosynthetic responses to changes in PPF have large effects on individual plant carbon gain and water use patterns, hence are important to plant distribution and success. We investigated the response over time of photosynthesis (A), stomatal conductance (g), and inter-cellular CO₂ concentration (C_i) to step changes in PPF in a long-lived aridland perennial that typically occurs in two contrasting microhabitats, shade under shrubs of other species and unshaded inter-shrub spaces. An initial rapid response in A and C_i for plants in both microhabitats occurred after abrupt changes in PPF. This was followed by slower changes in these parameters during the rest of the light or dark period. Stomatal conductance responded more gradually to step changes in PPF. The initial increase in A after a dark cycle was significantly greater for plants under shrubs than for plants in inter-shrub spaces, but other changes in A, g and C_i did not differ. We attribute the similar responses in plants from different microhabitats to natural variations in solar radiation and limited selection for differentiation due to population gene pools dominated by plants in the open. Our results support the hypothesis that variable light regimes select for photosynthetic gas exchange processes that closely track changes in incident PPF. Our data also support the hypothesis that gas exchange responses to variable light regimes in aridland plants minimize trade-offs between carbon gain and water loss.     

Biomimetic phosphoryl transfer catalysed by iron(II)-mineral precipitates

Iron(II) minerals have been found to catalyse the formation of pyrophosphate from activated phosphate compounds and inorganic phosphate at near neutral pH in water. Iron(II) phosphate catalyses the formation of pyrophosphate, from either acetyl phosphate or phosphoenolpyruvate as the activated phosphoryl donor, in yields of up to 25% and 14% respectively. Under similar conditions, these minerals also retard the hydrolysis of pyrophosphate. The catalysis of pyrophosphate formation is tolerant of sulfide ions: pyrophosphate being produced from acetyl phosphate in 12% yield in the presence of equimolar amounts of sulfide. These reactions mimic the extant biosynthesis of ATP from acetyl phosphate or phosphoenolpyruvate; they counter the concern that hydrolysis of polyphosphates would out-compete their accumulation under prebiotic conditions; and hence suggest a possible prebiotic route to polyphosphates under conditions that may have occurred on the early earth.     

Direct observation of heavy metal-mineral association from the Clark Fork River Superfund Complex: Implications for metal transport and bioavailability

Two sets of samples from riverbeds and adjacent floodplains, separated by 80 river kilometers, were collected from the Clark Fork River Superfund Complex, Montana, (the largest Superfund site in the United States), and studied primarily with transmission electron microscopy (TEM) with several supporting techniques to determine heavy metal-mineral association. Seven of the eight samples studied were strongly influenced by material that once resided in mining and smelting dumps and impoundments; this material was transported downstream sometime during the last century and a half from the Butte/Anaconda areas. The eighth sample was from a deeper floodplain level and dates to premining days. The TEM observations afford a direct look, down to the nanometer level, at secondary mineral formation as a result of the breakdown of sulfides and silicates in the acid environment of this massive mine-drainage system. In the shallow, oxic floodplain sediments, heavy metals of concern in this system (As, Cu, Pb, and Zn) are taken up by the formation of sulfates (particularly Pb in jarosite), as well as hydrous metal oxides (As, Cu, Pb, and Zn in and on ferrihydrite, and a possibly new vernadite-like mineral). The oxides are long-lived in these systems, as they were also found in the anoxic riverbeds. Metals are also taken up by the formation of sulfides in sulfate-reducing environments as observed in the formation of nanoclusters of chalcopyrite and sphalerite. In all samples, clays make up between 5 and 20% of the sediment and carry significant amounts of Cu and Zn. The hydrous oxides, secondary sulfides, and clays provide several routes for metal transport downstream over long distances. Besides the potential bioavailability of heavy metals exchanged on and off the hydrous metal oxides and clays, nanometer-sized sulfides may also be highly reactive in the presence of biologic systems.     

Climatological Drought in Arizona: An Analysis of Indicators for Guiding the Governor's Drought Task Force

Lacking a federal policy to address local water deficiencies within the United States, many states have developed their own methods for monitoring drought in an effort to mitigate its effects. This article provides an overview of efforts to standardize the use of drought indices in order to compare recent and historical drought both spatially and temporally for Arizona. Yearly averages of the Palmer Drought Severity Index and the Standardized Precipitation Index are placed into a frequency distribution to create standardization among the indices. The 1896–1904 drought ranked as the most severe, although the 1996–2004 drought was a close second.     

Backscattering from spherical elastic inclusions and accuracy of the Kirchhoff approximation for curved interfaces

The Kirchhoff (or tangent plane) approximation, derived from the theoretically complete Kirchhoff–Helmholtz integral representation for the seismic wavefield, has been used extensively for the analysis of seismic-wave scattering from irregular interfaces; however, the accuracy of this method for curved interfaces has not been rigorously established. This paper describes an efficient Kirchhoff algorithm to simulate scattered waves from an arbitrarily curved interface in an elastic medium. Synthetic seismograms computed using this algorithm are compared with exact synthetics computed using analytical formulae for scattering of plane P waves by a spherical elastic inclusion. A windowing technique is used to remove strong internal reverberations from the analytical solution. Although the Kirchhoff method tends to underestimate the total scattering intensity, the accuracy of the approximation improves with increasing value of the wavenumber-radius product, kR . The arrival times and pulse shapes of primary reflections from the sphere are well approximated using the Kirchhoff approach regardless of curvature of the scattering surface, but the amplitudes are significantly underestimated for kR ≤ 5. The results of this work provide some new guidelines to assess the accuracy of Kirchhoff-synthetic seismograms for curved interfaces.     

Facies architecture and Late Pliocene – Pleistocene evolution of a felsic volcanic island, Milos, Greece

The volcanic island of Milos, Greece, comprises an Upper Pliocene –Pleistocene, thick (up to 700 m), compositionally and texturally diverse succession of calc-alkaline, volcanic, and sedimentary rocks that record a transition from a relatively shallow but dominantly below-wave-base submarine setting to a subaerial one. The volcanic activity began at 2.66±0.07 Ma and has been more or less continuous since then. Subaerial emergence probably occurred at 1.44±0.08 Ma, in response to a combination of volcanic constructional processes and fault-controlled volcano-tectonic uplift. The architecture of the dominantly felsic-intermediate volcanic succession reflects contrasts in eruption style, proximity to source, depositional environment and emplacement processes. The juxtaposition of submarine and subaerial facies indicates that for part of the volcanic history, below-wave base to above-wave base, and shoaling to subaerial depositional environments coexisted in most areas. The volcanic facies architecture comprises interfingering proximal (near vent), medial and distal facies associations related to five main volcano types: (1) submarine felsic cryptodome-pumice cone volcanoes; (2) submarine dacitic and andesitic lava domes; (3) submarine-to-subaerial scoria cones; (4) submarine-to-subaerial dacitic and andesitic lava domes and (5) subaerial lava-pumice cone volcanoes. The volcanic facies are interbedded with a sedimentary facies association comprising sandstone and/or fossiliferous mudstone mainly derived from erosion of pre-existing volcanic deposits. The main facies associations are interpreted to have conformable, disconformable, and interfingering contacts, and there are no mappable angular unconformities or disconformities within the volcanic succession.Electronic Supplementary Material Supplementary material is available for this article at     

Gaseous transport and deposition of gold in magmatic fluid: evidence from the active Kudryavy volcano, Kurile Islands

The distribution of gold in high-temperature fumarole gases of the Kudryavy volcano (Kurile Islands) was measured for gas, gas condensate, natural fumarolic sublimates, and precipitates in silica tubes from vents with outlet temperatures ranging from 380 to 870°C. Gold abundance in condensates ranges from 0.3 to 2.4 ppb, which is significantly lower than the abundances of transition metals. Gold contents in zoned precipitates from silica tubes increase gradually with a decrease in temperature to a maximum of 8 ppm in the oxychloride zone at a temperature of approximately 300°C. Total Au content in moderate-temperature sulfide and oxychloride zones is mainly a result of Au inclusions in the abundant Fe–Cu and Zn sulfide minerals as determined by instrumental neutron activation analysis. Most Au occurs as a Cu–Au–Ag triple alloy. Single grains of native gold and binary Au–Ag alloys were also identified among sublimates, but aggregates and crystals of Cu–Au–Ag alloy were found in all fumarolic fields, both in silica tube precipitates and in natural fumarolic crusts. Although the Au triple alloy is homogeneous on the scale of microns and has a composition close to (Cu,Ni,Zn)₃(Au,Ag)₂, transmission electron microscopy (TEM) shows that these alloy solid solutions consist of monocrystal domains of Au–Ag, Au–Cu, and possibly Cu₂O. Gold occurs in oxide assemblages due to the decomposition of its halogenide complexes under high-temperature conditions (650–870°C). In lower temperature zones (<650°C), Au behavior is related to sulfur compounds whose evolution is strongly controlled by redox state. Other minerals that formed from gas transport and precipitation at Kudryavy volcano include garnet, aegirine, diopside, magnetite, anhydrite, molybdenite, multivalent molybdenum oxides (molybdite, tugarinovite, and ilsemannite), powellite, scheelite, wolframite, Na–K chlorides, pyrrhotite, wurtzite, greenockite, pyrite, galena, cubanite, rare native metals (including Fe, Cr, Mo, Sn, Ag, and Al), Cu–Zn–Fe–In sulfides, In-bearing Pb–Bi sulfosalts, cannizzarite, rheniite, cadmoindite, and kudriavite. Although most of these minerals are fine-grained, they are strongly idiomorphic with textures such as gas channels and lamellar, banded, skeletal, and dendrite-like crystals, characteristic of precipitation from a gas phase. The identified textures and mineral assemblages at Kudryavy volcano can be used to interpret geochemical origins of both ancient and modern ore deposits, particularly gold-rich porphyry and related epithermal systems.     

Sustainable lifestyles: Framing environmental action in and around the home

This paper examines the nature of environmental action in and around the home. Given the rise of local sustainable development and the emphasis placed on individual actions for sustainability, the paper examines the role of citizens in adopting sustainable lifestyles, incorporating a range of behavioural responses from energy saving and water conservation, to waste recycling and green consumption. Focussing on the debate in geography concerning the engagement of the public in environmental action, the paper argues that despite the assertions of those who advocate a deliberative approach to engagement (see [Owens, S., 2000. Engaging the public: information and deliberation in environmental policy. Environment and Planning A 32, 1141–1148]), an approach based on a social–psychological understanding of behaviour can have significant benefits. Such an approach is being developed by geographers in a range of settings and in this paper these developments are situated within the context of existing research that has identified environmental ‘activists’ in terms of their values, attitudes and demographic composition. The paper aims to examine environmental behaviour in relation to two key issues: (1) the way in which environmental action is framed in everyday practices (such as consumption behaviour) and (2) how these practices are reflected amongst different segments of the population to form lifestyle groups. The paper provides new insights for examining sustainable lifestyles that further our appreciation of how actions to help the environment are lived in everyday practices and framed by different lifestyle groups. Accordingly, the paper offers both academics and policy makers new insights into the potential use of focussing on lifestyle groups as a means for changing behaviour.