Comment on “the troodos ophiolitic complex was probably formed in an island arc”, by A. Miyashiro

The use of bulk chemical analyses from the Troodos complex to determine the chemical affinity of the ophiolites is unjustified since these rocks exhibit conspicuous alteration in thin section. Very similar rocks on mainland Greece can be shown, on mineralogical grounds, to have been mainly tholeiitic originally, with a subordinate alkaline trend. This is compatible with their origin at an oceanic ridge. Regional geological evidence provides strong support for this origin. However, bulk chemical analyses from them could be used, like those from Troodos, to argue against a mid-ocean ridge origin. This suggests that the use of bulk chemical analyses from these rocks is very unreliable. In the presence of other, more reliable data, inferences from bulk chemistry can be rejected. The Troodos ophiolites are very similar, in both petrology and geological position, to those in Greece and probably originated in the same way.     

Radiolaria as paleoclimatic indicators: Pleistocene climatic fluctuations in the equatorial Pacific Ocean

Late Pleistocene radiolarian assemblages were examined in two cores (V24-58 and RC11-209) from the eastern equatorial Pacific Ocean, using Nigrini's 1970 method of recurrent group analysis. The radiolarian “climatic index” curves obtained by this analysis were in close agreement with fluctuations in carbonate levels established previously for the same cores. This correspondence suggests that equatorial radiolarian assemblages changed significantly in response to Pleistocene climatic oscillations. The radiolarian “climatic indices” of the two cores showed close agreement with each other. Our data indicate that equatorial radiolarian assemblages may prove useful for regional correlations between cores, and for paleoclimatic interpretations.     

Determination of hydrocarbon distributions in oils and sediment extracts by gas chromatography—high resolution mass spectrometry

The distributions of steroid and triterpenoid hydrocarbons in crude oils and sedimentary rock extracts can be routinely determined by the direct injection of the sample into a gas chromatograph coupled to a mass spectrometer (GC-MS). The mass spectrometer is operated at a resolution of about 2500 (10% valley), and only the ion intensities at selected accurate mass values, diagnostic of the structural types of interest, are monitored throughout the analysis. The distributions, so obtained, find application in the assessment of the source and thermal maturity of crude oil accumulations in the subsurface. This technique eliminates chromatographic separation steps and combines two analyses in one. Thus, more geological samples and reference mixtures may be analyzed in a given time.     

MODFLOW 2000 head uncertainty,a first-order second moment method

A computationally efficient method to estimate the variance and covariance in piezometric head results computed through MODFLOW 2000 using a first-order second moment (FOSM) approach is presented. This methodology employs a first-order Taylor series expansion to combine model sensitivity with uncertainty in geologic data. MODFLOW 2000 is used to calculate both the ground water head and the sensitivity of head to changes in input data. From a limited number of samples, geologic data are extrapolated and their associated uncertainties are computed through a conditional probability calculation. Combining the spatially related sensitivity and input uncertainty produces the variance-covariance matrix, the diagonal of which is used to yield the standard deviation in MODFLOW 2000 head. The variance in piezometric head can be used for calibrating the model, estimating confidence intervals, directing exploration, and evaluating the reliability of a design. A case study illustrates the approach, where aquifer transmissivity is the spatially related uncertain geologic input data. The FOSM methodology is shown to be applicable for calculating output uncertainty for (1) spatially related input and output data, and (2) multiple input parameters (transmissivity and recharge).     

Patterns in benthic populations in the Milford Haven waterway following the 'Sea Empress' oil spill with special reference to amphipods

The macrobenthic fauna of the Milford Haven Waterway was studied in detail following the 'Sea Empress' oil spill in 1996. Contamination patterns indicated heaviest contamination of sediments by oil to have occurred in the lower reaches of the waterway, although water borne hydrocarbons are likely to have penetrated throughout the Haven. Generally, the communities showed little impact of contamination by oil, although some changes were evident at the population level. A decline in the amphipod fauna was observed throughout the Haven, with the genera Ampelisca and Harpinia and the family Isaeidae particularly affected. This was accompanied by increases in both the diversity and abundance of polychaete populations as opportunist species took advantage of the decline of the amphipod fauna. However, within five years of the spill the amphipod fauna has shown clear signs of recovery. The use of the polychaete/amphipod ratio as an indicator of oil pollution is discussed.     

Potential Implications of PCM Climate Change Scenarios for Sacramento–San Joaquin River Basin Hydrology and Water Resources

The potential effects of climate change on the hydrology and water resources of the Sacramento–San Joaquin River Basin were evaluated using ensemble climate simulations generated by the U.S. Department of Energy and National Center for Atmospheric Research Parallel Climate Model (DOE/NCAR PCM). Five PCM scenarios were employed. The first three were ensemble runs from 1995–2099 with a `business as usual' global emissions scenario, eachwith different atmospheric initializations. The fourth was a `control climate'scenario with greenhouse gas emissions set at 1995 levels and run through 2099. The fifth was a historical climate simulation forced with evolving greenhouse gas concentrations from 1870–2000, from which a 50-yearportion is taken for use in bias-correction of the other runs. From these global simulations, transient monthly temperature and precipitation sequences were statistically downscaled to produce continuous daily hydrologic model forcings, which drove a macro-scale hydrology model of theSacramento–San Joaquin River Basins at a 1/8-degree spatial resolution, and produceddaily streamflow sequences for each climate scenario. Each streamflow scenario was used in a water resources system model that simulated current and predicted future performance of the system. The progressive warming of the PCM scenarios (approximately 1.2 °C at midcentury, and 2.2 °C by the 2090s), coupled with reductions in winter and spring precipitation (from 10 to 25%), markedly reduced late spring snowpack (by as much as half on average by the end of the century). Progressive reductions in winter, spring, and summer streamflow were less severe in the northern part of the study domain than in the south, where a seasonality shift was apparent. Results from the water resources system model indicate that achieving and maintaining status quo (control scenario climate) system performance in the future would be nearly impossible, given the altered climate scenario hydrologies. The most comprehensive of the mitigation alternatives examined satisfied only 87–96% of environmental targets in the Sacramento system, and less than 80% in the San Joaquin system. It is evident that demand modification and system infrastructure improvements will be required to account for the volumetric and temporal shifts in flows predicted to occur with future climates in the Sacramento–San JoaquinRiver basins.     

Tertiary geodynamics of Sakhalin (NW Pacific) from anisotropy of magnetic susceptibility fabrics and paleomagnetic data

Sakhalin has been affected by several phases of Cretaceous and Tertiary deformation due to the complex interaction of plates in the northwest Pacific region. A detailed understanding of the strain is important because it will provide constraints on plate-scale processes that control the formation and deformation of marginal sedimentary basins. Anisotropy of magnetic susceptibility (AMS) data were obtained from fine-grained mudstones and siltstones from 22 localities in Sakhalin in order to provide information concerning tectonic strain. AMS data reliably record ancient strain tensor orientations before significant deformation of the sediments occurred. Paleomagnetically determined vertical-axis rotations of crustal rocks allow rotation of the fabrics back to their original orientation. Results from southwest Sakhalin indicate a N035°E-directed net tectonic transport from the mid-Paleocene to the early Miocene, which is consistent with the present-day relative motion between the Okhotsk Sea and Eurasian plates. Reconstruction of early–late Miocene AMS fabrics in east Sakhalin indicates a tectonic transport direction of N040°E. In west Sakhalin, the transport direction appears to have remained relatively consistent from the Oligocene to the late Miocene, but it has a different attitude of N080°E. This suggests local deflection of the stress and strain fields, which was probably associated with opening of the northern Tatar Strait. A northward-directed tectonic transport is observed in Miocene sediments in southeast Sakhalin, mid-Eocene sediments in east Sakhalin, and in Late Cretaceous rocks of west and northern Sakhalin, which may be associated with northwestward motion and subduction of the Pacific Plate in the Tertiary period. The boundaries of the separate regions defined by the AMS data are consistent with present-day plate models and, therefore, provide meaningful constraints on the tectonic evolution of Sakhalin.     

Structural fabric of the Central Metasedimentary Belt of southern Ontario, Canada, from deep seismic profiling

The Central Metasedimentary Belt boundary tectonic zone (CMBbtz) is a 10–20-km-wide zone of intense structural deformation within the 1.3–1.0 Ga Grenville orogen of southeastern Canada. The crustal structure of the exposed CMBbtz has been well studied, but its sub-Phanerozoic location and geometry beneath the urban development and nuclear stations of the Toronto region are not well known. A new 75-km Lithoprobe reflection profile acquired close to Toronto provides a clear image of the CMBbtz as a panel of southeast-dipping reflections that extends with moderate dip (<25°) to mid-crustal depth (25 km). These dipping reflections truncate and (or) overprint a subhorizontal band of reflectivity at 21 km depth. The seismic line is oblique to the major structural trends; cross-dip analysis shows that the southeast-dipping reflections have a strike and dip of N13°E and 25°, whereas the “subhorizontal” reflections strike and dip at N65°E and 20°, respectively. Both of these bands of reflectivity can be correlated to magnetic anomalies in the CMBbtz or its immediate footwall. Magnetic anomalies with similar strike directions are well expressed within a distinct rhomboid-shaped region (106×109 km) in the subsurface of western Lake Ontario, herein named Mississauga domain. Taken together, the seismic and magnetic data are inconsistent with existing models, in which the CMBbtz is extrapolated beneath Lake Ontario along a linear magnetic anomaly. We propose a revised subsurface trace of the CMBbtz along the western edge of the Mississauga domain. Small earthquakes in western Lake Ontario appear to cluster along trends co-linear with ENE magnetic anomalies, suggesting a possible degree of basement tectonic control on local intraplate seismicity.