Distribution of gold and rhenium between nickel-iron and silicate melts: implications for the abundance of siderophile elements on the Earth and Moon

The distribution equilibrium of Au and Re between nickel-iron and basaltic melts was studied at 1400–1600°C, using radioactive tracers. Metal/silicate distribution coefficients were 1–3 orders of magnitude higher than earlier estimates, as follows. Mauna Loa basalt—Fe₁₀Ni₉₀: D_Au = 3.3 × 10⁴, D_Re = (2.4?89) × 10⁴. Gorda Ridge basalt—Fe₁₀Ni₉₀: D_Au = (18?75) × 10⁴. Synthetic lunar basalt—Fe₇₀ Ni₃₀: D_Au≥ 2 × 10⁴, D_Re ≥ 2 × 10³. The experimental ΔG₁₈₀₀^° for the distribution of Au between nickel-iron and Mauna Loa basalt is ?40 kcal/mole, compared to a calculated value of about ?110 kcal/mole for a reaction involving simple Au³⁺ ions. Presumably the difference represents stabilization of Au(III) by complex formation with ligands such as Cl^?, H₂O, etc.Gold abundances in lunar basalts are roughly consistent with the measured D_Au, but those in terrestrial basalts are two orders of magnitude too high. This discrepancy may reflect complexing by volatiles in the Earth's upper lithosphere, as well as oxidative destruction of metal in the final stages of accretion. In the absence of a metal phase, siderophile trace elements would remain trapped in the upper mantle and crust.     

Investigation of the change in soil fabric during cone penetration in silt using 2D measurements

Interpretation of CPTU testing in silt is non-trivial because of the partially drained conditions that are likely to occur during penetration. A better understanding of the pore pressure generation/dissipation is needed in order to obtain reliable design parameters. Following a previous study using X-ray computed tomography (micro-CT) with volumetric digital image correlation (3D-DIC) that clearly showed the formation of distinct dilation and compression areas around the cone; the present work takes a closer look at those areas in order to link volumetric behavior to changes in soil fabric. High-resolution 2D backscattered electron images of polished thin sections prepared from frozen samples at the end of penetration are used. The images have a spatial resolution of 0.4 µm/pixel that allow a clear identification of grains and pore spaces. Image processing techniques are developed to quantify local porosity and obtain the statistical distribution of the particle orientation for the zones around the cone tip and shaft. It is shown that the formation of compaction regions is related to the ability of the grains to rearrange and align along a well-defined preferred orientation forming a more closed-fabric characterized by high anisotropy values, while zones of dilation are associated with a more open packing with grains randomly oriented and with large voids within. These observations suggested that for a saturated soil, water will move from a compressive zone to a neighboring dilative zone, creating a short drainage path. By shedding light on the link between soil fabric and drainage patterns, this study contributes toward a better understanding of the measured macro-response during CPTU tests on silt.     

The use of spectral analysis-based exact solutions to characterize topography-controlled groundwater flow

Spectral analysis enhances the ability to analyze groundwater flow at a steady state by separating the top boundary condition into its periodic forms. Specifically, spectral analysis enables comparisons of the impact of individual spatial scales on the total flow field. New exact spectral solutions are presented for analyzing 3D groundwater flow with an arbitrarily shaped top boundary. These solutions account for depth-decaying, anisotropic and layered permeability while utilizing groundwater flux or the phreatic surface as a top boundary condition. Under certain conditions, groundwater flow is controlled by topography. In areas where the groundwater flow is controlled by the topography, the unknown water table is often approximated by the topography. This approximation induces a systematic error. Here, the optimal resolution of digital elevation models (DEMs) is assessed for use as a top boundary in groundwater flow models. According to the analysis, the water-table undulation is smoother than the topography; therefore, there is an upper limit to the resolution of DEMs that should be used to represent the groundwater surface. The ability to represent DEMs of various spectral solutions was compared and the results indicate that the fit is strongly dependent on the number of harmonics in the spectral solution.     

Applying spatial regression to evaluate risk factors for microbiological contamination of urban groundwater sources in Juba,South Sudan

This study developed methodology for statistically assessing groundwater contamination mechanisms. It focused on microbial water pollution in low-income regions. Risk factors for faecal contamination of groundwater-fed drinking-water sources were evaluated in a case study in Juba, South Sudan. The study was based on counts of thermotolerant coliforms in water samples from 129 sources, collected by the humanitarian aid organisation Médecins Sans Frontières in 2010. The factors included hydrogeological settings, land use and socio-economic characteristics. The results showed that the residuals of a conventional probit regression model had a significant positive spatial autocorrelation (Moran’s I?=?3.05, I-stat?=?9.28); therefore, a spatial model was developed that had better goodness-of-fit to the observations. The most significant factor in this model (p-value 0.005) was the distance from a water source to the nearest Tukul area, an area with informal settlements that lack sanitation services. It is thus recommended that future remediation and monitoring efforts in the city be concentrated in such low-income regions. The spatial model differed from the conventional approach: in contrast with the latter case, lowland topography was not significant at the 5% level, as the p-value was 0.074 in the spatial model and 0.040 in the traditional model. This study showed that statistical risk-factor assessments of groundwater contamination need to consider spatial interactions when the water sources are located close to each other. Future studies might further investigate the cut-off distance that reflects spatial autocorrelation. Particularly, these results advise research on urban groundwater quality.     

Mixing and chemical interdiffusion of trachytic and latitic magma in a subvolcanic complex of the Tertiary Westerwald (Germany)

A special kind of magma mixing is extraordinarily well exposed in the Bittersberg subvolcanic complex in the Tertiary volcanic field of the German Westerwald: A trachytic melt has been penetrated by a latitic dyke which has been dispersed within the host magma as small spherical enclaves (globules). Whole rock analyses of the globules show a change in composition that cannot be explained by a simple mechanical mixing between the endmembers. The most evolved globules have a phonolitic composition. Microprobe measurements in the microlithic matrix of the host rock and the guest indicate a diffusive motion of the alkalis from the host into the globules. On the other hand, an opposite trend can be observed for Ca, Mg, Fe and Ti, which are impoverished in the globules. The trace elements and the middle rare earth elements (MREE) has also been involved in the diffusive exchange. The REE-pattern of the most evolved (phonolitic) globules shows a characteristic trough in the area of the MREE which is almost identical to the REE-pattern of many phonolites. The phonolites and the alkali-rich trachytes of the Westerwald show similar globular textures as the Bittersberg volcanics. Therefore, generation of these rocks involving diffusive element exchange during mixing processes in a magma reservoir situated on a deeper crustal level may be possible.     

Cenozoic erosion and the preglacial uplift of the Svalbard–Barents Sea region

The creation of the huge fans observed in the western Barents Sea margin can only be explained by assuming extremely high glacial erosion rates in the Barents Sea area. Glacial processes capable of producing such high erosion rates have been proposed, but require the largest part of the preglacial Barents Sea to be subaerial. To investigate the validity of these proposals we have attempted to reconstruct the western preglacial Barents Sea. Our approach was to combine erosion maps based on prepublished data into a single mean valued erosion map covering the whole western Barents Sea and consequently use it together with a simple Airy isostatic model to obtain a first rough estimate of the preglacial topography and bathymetry of the western Barents Sea margin. The mean valued erosion map presented herein is in good volumetric agreement with the sediments deposited in the western Barents Sea margin areas, and as a direct consequence of the averaging procedures employed in its construction we can safely assume that it is the most reliable erosion map based on the available information. By comparing the preglacial sequences with the glacial sequences in the fans we have concluded that 1/2 to 2/3 of the total Cenozoic erosion was glacial in origin and therefore a rough reconstruction of the preglacial relief of the western Barents Sea could be obtained. The results show a subaerial preglacial Barents Sea. Thus, during interglacials and interstadials the area may have been partly glaciated and intensively eroded up to 1 mm/y, while during relatively brief periods of peak glaciation with grounded ice extending to the shelf edge, sediments have been evacuated and deposited at the margins at high rates. The interplay between erosion and uplift represents a typical chicken and egg problem; initial uplift is followed by intensive glacial erosion, compensated by isostatic uplift, which in turn leads to the maintenance of an elevated, and glaciated, terrain. The information we have on the initial tectonic uplift suggests that the most likely mechanism to cause an uplift of the dimensions and magnitude of the one observed in the Barents Sea is a thermal mechanism.     

Noble gases in the Allende and Abee meteorites and a gas-rich mineral fraction: investigation by stepwise heating

Noble gases in three meteoritic samples were examined by stepwise heating, in an attempt to relate peaks in the outgassing curves to specific minerals: NeKrXe in Allende (C3V) and an Allende residue insoluble in HF-HCl, and Xe in Abee (E4). In Allende, chromite and carbon contain most of the trapped Ne (²⁰Ne/²²Ne ≈ 8.7) and anomalous Xe enriched in light and heavy isotopes, and release it at ~850°C (bulk meteorite) or 1000°C (residue). Mineral Q, containing most of the trapped Ar, Kr, Xe as well as some Ne (²⁰Ne/²²Ne ≈ 10.4), releases its gases mainly between 1200 and 1600°C, well above the release temperatures of organic polymers (300–500°) or amorphous carbon (800–1000°). The high noble-gas release temperature, ready solubility in oxidizing acids, and correlation with acid-soluble Fe and Cr all point to an inorganic rather than carbonaceous nature of Q.All the radiogenic ¹²⁹Xe is contained in HCl, HF-soluble minerals, and is distributed as follows over the peaks in the release curve: Attend 1000° (75%), 1300° (25%); Abee (data of Hohenberg and Reynolds, 1969) ~850° (15%), 1100° (60%), 1300° (25%). No conclusive identifications of host phases can yet be given; possible candidates are troilite and silicates for Allende, and djerfisherite, troilite and silicates for Abee.Mineral Q strongly absorbs air xenon, and releases some of it only at 800–1000°C. Dilution by air Xe from Q and other minerals may explain why temperature fractions from bulk meteorites often contain less ^124–130Xe for a given enrichment in heavy isotopes than does xenon from etched chromitecarbon samples, although chromite-carbon is the source of the anomalous xenon in either case. Air xenon contamination thus is an important source of error in the derivation of fission xenon spectra.     

Chemical fractionations in meteorites—X. Ureilites

Four ureilites (Dyalpur, Goalpara, Haverö, and Novo Urei) were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Ni, Rb, Re, Sb, Se, Te, Tl, and U. An attempt has been made to resolve the data into contributions from the parent ultramafic rock and the injected, carbon- and gas-rich vein material. Interelement correlations, supported by analyses of separated vein material (WANKE et al, 1972), suggest that the vein material is enriched about 10-fold in refractory Ir and Re over moderately volatile Ni and Au, and is low in volatiles except Ge, C, and noble gases. It appears to be a refractory-rich nebular condensate that precipitated carbon by surface catalytic reactions at ˜500K and trapped noble gases but few other volatiles. The closest known analogue is a Cr- and C-rich fraction from the Allende meteorite, highly enriched in heavy noble gases and noble metals. By analogy with Allende, the gas-bearing phase in ureilites may have been an Fe, Cr-sulfide.

The ultramafic rock contains siderophiles and chalcophiles (Ni, Au, Ge, S, Se) at ˜0.05 of Cl chondrite level, and highly volatile elements (Rb, Cs, Bi, Tl, Br, Te, In, Cd) at ˜0.01 Cl level. It probably represents the residue from partial melting of a C3V-like chondrite body, under conditions where phase separation was incomplete so that some liquid was retained. The vein material was injected into this rock at some later time.     

Impact of Hydropower Regulation on River Water Composition in Northern Sweden

Using hydrogeochemical analysis of two large boreal rivers (pristine Kalix and hydropower regulated Lule) discharging into the Gulf of Bothnia, the major impacts of regulation on water discharge, element transport and their seasonal redistribution have been assessed. The pre-regulation hydrogeochemical features were assumed to be similar for the two rivers. For the Lule River, the average maximum runoff was almost halved, while the average minimum was tripled as a result of the regulation. The fraction of winter transport of total organic carbon (TOC), Fe, Si, suspended Mn and P in the Lule River was, according to a conservative estimate, two to three times higher than in the pristine river. Longer residence time in the Lule River delayed arrival of the suspended Mn peak and dissolved Si decline to the river mouth. During summer, the suspended C/N ratio in the regulated river was 10–20 compared to <10 for the pristine, suggesting presence of predominantly old organic material. This was supported by a virtually constant suspended P/Fe ratio throughout the year in the Lule River, indicating low abundance of phytoplankton. TOC varied irregularly in the Lule River suggesting temporal disconnection between the river and the upper riparian zone. The disappearance of the spring flow maximum, a shift of element transport from spring to winter and supply of mainly old organic material during the vegetation growth season may have a pronounced impact on the ecosystem of the Gulf of Bothnia and the river itself.     

H-chondrites: Trace element clues to their origin

We have analyzed 10 H-chondrites for 20 trace elements, using RNAA. The meteorites included 4 of petrologic type 4 and 2 each of types 3, 5 and 6.The data show that H-chondrites are not isochemical. H3's are depleted by some 10% not only in Fe (Dodd, 1976), but also in the siderophiles Os, Re, Ir, Ni, Pd, Au, and Ge. Moreover, the abundance pattern of siderophiles varies systematically with petrologic type. As similar fractionations of REE have been observed by Nakamura (1974), it appears that both the proportions and compositions of the main nebular condensates varied slightly during accretion of the H-chondrites. Thus the higher petrologic types are independent nebular products, not metamorphosed descendants of lower petrologic types.Abundances of highly volatile elements (Cs, Br, Bi, Tl, In, Cd, Ar³⁶) correlate with petrologic type, declining by ≤ 10^?3 from Type 3 to Type 6. The trends differ from those for artificially heated Type 3's (Ikramuddinet al., 1977b; Herzoget al., 1979), but agree passably with theoretical curves for nebular condensation. Apparently the low volatile contents of higher petrologic types are a primary feature, not the result of metamorphic loss.The mineralogy of chondrites suggests that they accreted between 405 K (absence of Fe₃O₄) and 560 K (presence of FeS), and the abundances of Tl, Bi, and In further restrict this interval to 420–500 K. Accretion at 1070 ± 100 K, as proposed by Hutchisonet al. (1979, 1980), leads to some extraordinary problems. Volatiles must be injected into the parent body after cooling, which requires permeation of the body by 10¹¹ times its volume of nebular gas. This process must also achieve a uniform distribution of the less volatile elements (Rb, Cu, Ag, Zn, Ga, Ge, Sn, Sb, Se, F), without freezeout in the colder outer layers.Factor analysis of our data shows 3 groupings: siderophiles (Os, Re, Ir, Ni, Pd, Au, and Ge), volatiles (Ag, Br, In, Cd, Bi, and Tl) and alkalis (Rb and Cs). The remaining 5 elements (U, Zn, Te, Se, and Sb) remain unassociated.