Hybrid Model for Urban Air Pollution Forecasting: A Stochastic Spatio-Temporal Approach

Air pollution is usually driven by a complex combination of factors in which meteorology, physical obstacles, and interactions between pollutants play significant roles. Considering the characteristics of urban atmospheric pollution and its consequent impacts on human health and quality of life, forecasting models have emerged as an effective tool to identify and forecast air pollution episodes. The overall objective of the present work is to produce forecasts of pollutant concentrations with high spatio-temporal resolution and to quantify the uncertainty in those forecasts. Therefore, a new approach was developed based on a two-step methodology. Firstly, neural network models were used to generate short-term temporal forecasts based on air pollution and meteorology data. The accuracy of those forecasts was then evaluated against an independent set of historical data. Secondly, local conditional distributions of the observed values with respect to the predicted values were used to perform spatial stochastic simulations for the entire geographic area of interest. With this approach the spatio-temporal dispersion of a pollutant can be predicted, while accounting for both the temporal uncertainty in the forecast (reflecting the neural networks efficiency at each monitoring station) and the spatial uncertainty as revealed by the spatial variograms. Based on an analysis of the results, our proposed method offers a highly promising alternative for the characterization of urban air quality.     

The state of the environment in Mexico

The present work evaluates the state of the environment in Mexico based on indicators of the present status of the country’s natural resource management, social and economical conditions and anthropogenic modifications. The Mexican environment is interpreted as a spatially open system having a historical character that is essentially determined by the continual interaction between nature, society and economy. The landscape approach is followed, considering as units of territorial analysis each one of the 145 biophysical environmental units included in the national physiographic regionalization. The assessment of 16 indicators for each biophysical environmental unit was made considering their regional environmental integrity problems, the degree of disarticulation of their structure and function, and the alteration of their territorial structure, all of which determine whether or not they accomplish their environmental functions and achieve environmental stability. The classification of the state of the environment included 5 categories in 8 combinations represented in the map of the state of the environment in Mexico for the year 2008. The map shows that nearly 47.10% of the country’s surface has an environmental status ranging between unstable and critical, the problematic areas being mostly concentrated in the southeast and center of the national territory.     

Streamflow response to regional climate model output in the mountainous watershed: a case study from the Swiss Alps

Regional climate model (RCM) outputs are often used in hydrological modeling, in particular for streamflow forecasting. The heterogeneity of the meteorological variables such as precipitation, temperature, wind speed and solar radiation often limits the ability of the hydrological model performance. This paper assessed the sensitivity of RCM outputs from the PRUDENCE project and their performance in reproducing the streamflow. The soil and water assessment tool was used to simulate the streamflow of the Rhone River watershed located in the southwestern part of Switzerland, with the climate variables obtained from four RCMs. We analyzed the difference in magnitude of precipitation, maximum and minimum air temperature, and wind speed with respect to the observed values from the meteorological stations. In addition, we also focused on the impact of the grid resolution on model performance, by analyzing grids with resolutions of 50 × 50 and 25 × 25 km². The variability of the meteorological inputs from various RCMs is quite severe in the studied watershed. Among the four different RCMs, the Danish Meteorological Institute provided the best performance when simulating runoff. We found that temperature lapse rate is significantly important in the mountainous snow and glacier dominated watershed as compared to other variables like precipitation, and wind speed for hydrological performance. Therefore, emphasis should be given to minimum and maximum temperature in the bias correction studies for downscaling climatic data for impact modeling in the mountainous snow and glacier dominated complex watersheds.     

A Middle Miocene carbonate embankment on an active volcanic slope: Ilhéu de Baixo,Madeira Archipelago,Eastern Atlantic

Carbonate factories on insular oceanic islands in active volcanic settings are poorly explored. This case study illuminates marginal limestone deposits on a steep volcanic flank and their recurring interruption by deposits linked to volcaniclastic processes. Historically known as Ilhéu da Cal (Lime Island), Ilhéu de Baixo was separated from Porto Santo, in the Madeira Archipelago, during the course of the Quaternary. Here, extensive mines were tunnelled in the Miocene carbonate strata for the production of slaked lime. Approximately 10 000 m³ of calcarenite (−1 to 1ø) was removed by hand labour from the Blandy Brothers mine at the south end of the islet. Investigations of two stratigraphic sections at opposite ends of the mine reveal that the quarried material represents an incipient carbonate ramp developed from east to west and embanked against the flank of a volcanic island. A petrographic analysis of limestones from the mine shows that coralline red algae from crushed rhodoliths account for 51% of all identifiable bioclasts. This material was transported shoreward and deposited on the ramp between normal wave base and storm wave base at moderate depths. The mine's roof rocks are formed by Surtseyan deposits from a subsequent volcanic eruption. Volcaniclastic density flows also are a prevalent factor interrupting renewed carbonate deposition. These flows arrived downslope from the north and gradually steepened the debris apron westwards. Slope instability is further shown by a coral rudstone density flow that followed from growth of a coral reef dominated by Pocillopora madreporacea (Lamarck), partial reef collapse, and transport from a more easterly direction into a fore‐reef setting. The uppermost facies represents a soft bottom at moderate depths in a quiet, but shore‐proximal setting. Application of this study to a broader understanding of the relationship between carbonate and volcaniclastic deposition on oceanic islands emphasizes the susceptibility of carbonates to dilution and complete removal by density flows of various kinds, in contrast to the potential for preservation beneath less‐disruptive Surtseyan deposits. Copyright © 2013 John Wiley & Sons, Ltd.     

Water reservoirs and the risk of accidental flood occurrence. Case study: Stanca–Costesti reservoir and the historical floods of the Prut river in the period July–August 2008, Romania

In the summer of 2008 the Prut river recorded a historical flow of 7140 m³/s at its entrance into Romania. This flow was the highest ever recorded of any Romanian river. The high value was generated by high amounts of rainfall recorded first on the territory of Ukraine and then in Romania. Unfortunately, there were some discrepancies between the data transmitted and intercepted from the Meteorology National Agency and Hydrology and Water Management National Agency. This is why the amount of precipitation which fell over the territory of Ukraine could not be monitored in time and punctually. Nor could the high flood wave moving rapidly from the upper basin to the lower basin. The high flow of the upper Prut caused the accumulation of an immense quantity of water in the Stanca–Costesti reservoir. Under the conditions of precipitation occurring in the lower river basin as well, the levels reached the flood quota and the reservoir reached the maximum accepted capacity, with 0·1% insurance. The release of supplementary water quantities from the reservoir would have produced catastrophic floods downstream. Keeping the water in the reservoir could have broken it and the flooding, through backwater eddies, or the riverbank settlements. In such a case, it would have produced the greatest tragedy in the hydrological history of Europe. The most significant damage was produced upstream of the barrage, next to the localities of Radauti Prut and Baranca–Hudesti, as well as in the area of the reservoir, as a result of the phenomenon known as ‘remuu’, or backwater eddies. The floods of the Prut river occurred between the end of July and the end of August. Copyright © 2011 John Wiley & Sons, Ltd.     

Generative Adversarial Network Applied to Ore Type Modeling in Complex Geological Environments

Mathematical Geosciences - In complex geological environments, the spatial domain characterization of different ore types has been one of the most important challenges in the assessment of mineral...     

On the variability of seasonal temperature in southern South America

The aim of this paper is to investigate different aspects of the seasonal-to-interannual temperature variability in Eastern Patagonia, the southernmost area of South America, east of the Andes Cordillera. Homogenous regions of seasonal variability and the atmospheric circulation patterns associated with warm and cold conditions in each of them are described in this study. Relationships between temperature in Eastern Patagonia and that registered in other areas of southern South America are also addressed. Results show that the northern and southern areas of Eastern Patagonia have different temperature variability in summer and autumn whereas the temperature variability tends to be more homogeneous within the region during winter and spring. Warm (cold) conditions in the northern areas are associated with reinforced (weakened) westerlies in summer, winter and spring whereas northerly (southerly) advections of warm (cold) air toward the region produce such conditions in autumn. Temperature in the southern portion of Eastern Patagonia is affected by anticyclonic (cyclonic) anomalies that enhance (reduce) the incoming solar radiation and induce reinforced (weakened) westerlies promoting warm (cold) conditions in the region. Furthermore, cyclonic (anticyclonic) anomalies at subpolar latitudes hinder (favor) outbreaks of cold air increasing (decreasing) the temperature over areas of Eastern Patagonia. The circulation anomalies associated with warm (cold) conditions in Eastern Patagonia also promote cold (warm) conditions over areas of northern Argentina, Paraguay and southern Brazil. Consequently, a dipole of temperature is detected in southern South America with centers of opposite sign over these regions.     

A global model study of natural bromine sources and the effects on tropospheric chemistry using MOZART4

Halogens in the atmosphere chemically destroy ozone. In the troposphere, bromine has higher ozone destruction efficiency than chlorine and is the halogen species with the widest geographical spread of natural sources. We investigate the relative strength of various sources of reactive tropospheric bromine and the influence of bromine on tropospheric chemistry using a 6-year simulation with the global chemistry transport model MOZART4. We consider the following sources: short-lived bromocarbons (CHBr₃, CH₂BrCl, CHBr₂Cl, CHBrCl₂, and CH₂Br₂) and CH₃Br, bromine from airborne sea salt particles, and frost flowers and sea salt on or in the snowpack in polar regions. The total bromine emissions in our simulations add up to 31.7 Gmol(Br)/yr: 63 % from polar sources, 24.6 % from short-lived bromocarbons and 12.4 % from airborne sea salt particles. We conclude from our analysis that our global bromine emission is likely to be on the lower end of the range, because of too low emissions from airborne sea salt. Bromine chemistry has an effect on the oxidation capacity of the troposphere, not only due to its direct influence on ozone concentrations, but also by reactions with other key chemical species like HO _x and NO _x . Globally, the impact of bromine chemistry on tropospheric O₃ is comparable to the impact of gas-phase sulfur chemistry, since the inclusion of bromine chemistry in MOZART4 leads to a decrease of the O₃ burden in the troposphere by 6 Tg, while we get an increase by 5 Tg if gas-phase sulfur chemistry is switched off in the standard model. With decreased ozone burden, the simulated oxidizing capacity of the atmosphere decreases thus affecting species associated with the oxidation capacity of the atmosphere (CH₃OOH, H₂O₂).