Sediment disturbance off the Tagus Estuary, Western Portugal: chronic contamination, sewage outfall operation and runoff events

Sediment disturbance patterns in the coastal area off the Tagus Estuary (Portugal) have been assessed using a set of combined techniques. The potential sources of disturbance in the area include chronic contamination of the fine sediments originating from the estuary, a local input from a long-sea sewage outfall and occasional high runoff episodes following torrential rain. The Sediment Quality Triad approach, combining environmental chemistry (namely organic contaminants), macrofaunal benthic communities and laboratory sediment toxicity assays, was performed on sediment samples from 20 sites. The samples were collected before the outfall commenced operation and four years after commissioning, in order to evaluate the relative magnitudes of the three potential sources of disturbance. The sediment contamination created by the estuary was identified as the most important cause of reduced sediment quality, as disturbance in all three components of the Sediment Quality Triad were only found in a site located near the estuary.     

The use of the marine biotic index AMBI in the assessment of the ecological status of the Obidos lagoon (Portugal)

This study reports the longitudinal distribution of sediment properties, including inorganic and organic contaminants, and the structure of the benthic community in Obidos lagoon, a coastal system permanently connected to the sea and with negligible freshwater sources. Sediments from the upper to central lagoon consist of fine particles (91%) and from the lower lagoon of sands (94%). Chemical composition is strongly correlated to the percentage of fine particles. Contamination is relatively low in those sediments suggesting the effect of diffuse sources. The increase in organic matter content from down- to upstream areas was associated with the dominance of opportunistic species, while sensitive and indifferent species to organic enrichment were mainly associated to the clean sandy downstream area. The marine biotic index (AMBI) was suitable for the discrimination of the biological and environmental gradients in the Obidos lagoon and was highly related with the gradient of organic matter content in this system.     

Agricultural land use dynamics in the Brazilian Amazon based on remote sensing and census data

The potential impact of deforestation in the Brazilian Amazon on greenhouse gas emissions to the atmosphere calls for policies that take account of changes in forest cover. Although much research has focused on the location and effects of deforestation, little is known about the distribution and reasons for the agricultural uses that replace forest cover. We used Landsat TM-based deforestation and agricultural census data to generate maps of the distribution and proportion of four major agricultural land uses throughout the Brazilian Amazon in 1997 and 2007. We built linear and spatial regression models to assess the determinant factors of deforestation and those major agricultural land uses - pasture, temporary agriculture and permanent agriculture - for the states of Pará, Rondônia, and Mato Grosso. The data include 30 determinant factors that were grouped into two years (1996 and 2006) and in four categories: accessibility to markets, public policies, agrarian structure, and environment. We found an overall expansion of the total agricultural area between 1997 and 2007, and notable differences between the states of Pará, Rondônia, and Mato Grosso in land use changes during this period. Regression models for deforestation and pasture indicated that determinant factors such as distance to roads were more influential in 1997 than in 2007. The number of settled families played an important role in the deforestation and pasture, the effect was stronger in 2007 than 1997. Indigenous lands were significant in preventing deforestation in high-pressure areas in 2007. For temporary and permanent agricultures, our results show that in 1997 the effect of small farms was stronger than in 2007. The mapped land use time series and the models explain empirically the effects of land use changes across the region over one decade.     

A new design of the LAPS land surface scheme for use over and through heterogeneous and non-heterogeneous surfaces: Numerical simulations and tests

Numerical simulations and tests with the recently redesigned land–air parameterization scheme (LAPS) are presented. In all experiments, supported either by one-point micrometeorological, 1D or 3D simulations, the attention has been directed to: (1) comparison of simulation outputs, expressing the energy transfer over and through heterogeneous and non-heterogeneous surfaces, versus observations and (2) analysis of uncertainties occurring in the solution of the energy balance equation at the land–air interface. To check the proposed method for aggregation of albedo, “propagating hole” sensitivity tests with LAPS over a sandstone rock grid cell have been performed with the forcing meteorological data for July 17, 1999 in Baxter site, Philadelphia (USA). Micrometeorological and biophysical measurements from the surface experiments conducted over crops and apple orchard in Serbia, Poland, Austria and France were used to test the operation of LAPS in calculating surface fluxes and canopy environment temperatures within and above plant covers of different densities. In addition, sensitivity tests with single canopy covers over the Central Europe region and comparison against the observations taken from SYNOP data using 3D simulations were made. Validation of LAPS performances over a solid surface has been done by comparison of 2 m air temperature observations against 5-day simulations over the Sahara Desert rocky ground using 3D model. To examine how realistically the LAPS simulates surface processes over a heterogeneous surface, we compared the air temperature measured at 2 m and that predicted by the 1D model with the LAPS as the surface scheme. Finally, the scheme behaviour over urban surface was tested by runs over different parts of a hypothetical urban area. The corresponding 1D simulations were carried out with an imposed meteorological dataset collected during HAPEX-MOBILHY experiment at Caumont (France). The quantities predicted by the LAPS compare well with the observations and the various subcomponents of the scheme appear to operate realistically.     

Future change of climate in South America in the late twenty-first century: intercomparison of scenarios from three regional climate models

Regional climate change projections for the last half of the twenty-first century have been produced for South America, as part of the CREAS (Cenarios REgionalizados de Clima Futuro da America do Sul) regional project. Three regional climate models RCMs (Eta CCS, RegCM3 and HadRM3P) were nested within the HadAM3P global model. The simulations cover a 30-year period representing present climate (1961–1990) and projections for the IPCC A2 high emission scenario for 2071–2100. The focus was on the changes in the mean circulation and surface variables, in particular, surface air temperature and precipitation. There is a consistent pattern of changes in circulation, rainfall and temperatures as depicted by the three models. The HadRM3P shows intensification and a more southward position of the subtropical Pacific high, while a pattern of intensification/weakening during summer/winter is projected by the Eta CCS/RegCM3. There is a tendency for a weakening of the subtropical westerly jet from the Eta CCS and HadRM3P, consistent with other studies. There are indications that regions such of Northeast Brazil and central-eastern and southern Amazonia may experience rainfall deficiency in the future, while the Northwest coast of Peru-Ecuador and northern Argentina may experience rainfall excesses in a warmer future, and these changes may vary with the seasons. The three models show warming in the A2 scenario stronger in the tropical region, especially in the 5°N–15°S band, both in summer and especially in winter, reaching up to 6–8°C warmer than in the present. In southern South America, the warming in summer varies between 2 and 4°C and in winter between 3 and 5°C in the same region from the 3 models. These changes are consistent with changes in low level circulation from the models, and they are comparable with changes in rainfall and temperature extremes reported elsewhere. In summary, some aspects of projected future climate change are quite robust across this set of model runs for some regions, as the Northwest coast of Peru-Ecuador, northern Argentina, Eastern Amazonia and Northeast Brazil, whereas for other regions they are less robust as in Pantanal region of West Central and southeastern Brazil.     

Kinetics of the reactions of Cl atoms with 2-buten-1-ol, 2-methyl-2-propen-1-ol, and 3-methyl-2-buten-1-ol as a function of temperature

The reactions of three structurally similar unsaturated alcohols, 2-buten-1-ol (crotyl alcohol), 2-methyl-2-propen-1-ol (MPO221) and 3-methyl-2-buten-1-ol (MBO321) with Cl atoms, have been investigated for the first time, using a 400 l Teflon reaction chamber coupled with gas chromatograph-coupled with flame-ionization detection (GC-FID). The experiments were performed at atmospheric pressure and at temperatures between 255 and 298 K, in air or nitrogen as the bath gas. The obtained kinetic data were used to derive the Arrhenius expressions , , (in units of cm³ molecule⁻¹ s⁻¹). Finally, atmospheric lifetimes of those unsaturated alcohols with respect to OH, NO₃, O₃ and Cl have been calculated.     

Effect of growth on active biomonitoring with terrestrial mosses

The effects of growth of autoirrigated, shaded transplants of Pseudoscleropodium purum on the quantification of tissue concentrations of Cd, Cu, Hg, V and Zn, were investigated in 4 exposure periods, each of 56 days, at 7 sampling sites (contaminated and uncontaminated). Concentrations of the elements in the basal portions of the moss shoots were compared with the concentrations in the portions of the shoots that grew during the exposure period. Mercury and V were present at lower concentrations in the new portions of the shoots than in the basal portions, whereas the opposite was true for Cd, Cu and Zn. The magnitude of error introduced by growth was not negligible, and in some cases was higher than 40%, relative to the results obtained by analysis of the whole shoot. Devitalization of moss prior to its use as transplant material is recommended to avoid growth of the plant during the exposure period.     

Optical spectroscopy of the quiescent counterpart to EXO 0748−676

We present phase resolved optical spectroscopy and X-ray timing of the neutron star X-ray binary EXO 0748−676 after the source returned to quiescence in the autumn of 2008. The X-ray light curve displays eclipses consistent in orbital period, orbital phase and duration with the predictions and measurements before the return to quiescence. Hα and He  i emission lines are present in the optical spectra and show the signature of the orbit of the binary companion, placing a lower limit on the radial velocity semi-amplitude of   K ₂ > 405 km s⁻¹  . Both the flux in the continuum and the emission lines show orbital modulations, indicating that we observe the hemisphere of the binary companion that is being irradiated by the neutron star. Effects due to this irradiation preclude a direct measurement of the radial velocity semi-amplitude of the binary companion; in fact, no stellar absorption lines are seen in the spectrum. Nevertheless, our observations place a stringent lower limit on the neutron star mass of   M ₁ > 1.27 M_⊙  . For the canonical neutron star mass of   M ₁= 1.4 M_⊙  , the mass ratio is constrained to  0.075 < q < 0.105  .     

Doppler and modulation tomography of XTE J1118+480 in quiescence

We present Doppler and modulation tomography of the X-ray nova XTE J1118+480 with data obtained during quiescence using the 10-m Keck II telescope. The hotspot where the gas stream hits the accretion disc is seen in Hα, Hβ, He  i λ5876 and Ca  ii λ8662, thus verifying the presence of continued mass transfer within the system. The disc is clearly seen in Hα and Ca  ii λ8662. We image the mass-donor star in narrow absorption lines of Na  i  λλ5890, 5896, 8183, 8195  and Ca  ii λ8662, implying an origin from the secondary itself rather than the interstellar medium. We also detect deviations in the centroid of the double peak of Hα akin to those found by Zurita et al. suggesting disc eccentricity.     

A numerical study of the orbits of second species of the planar circular RTBP

We present a numerical study of the set of orbits of the planar circular restricted three body problem which undergo consecutive close encounters with the small primary, or orbits of second species. The value of the Jacobi constant is fixed, and we restrict the study to consecutive close encounters which occur within a maximal time interval. With these restrictions, the full set of orbits of second species is found numerically from the intersections of the stable and unstable manifolds of the collision singularity on the surface of section that corresponds to passage through the pericentre. A ‘skeleton’ of this set of curves can be computed from the solutions of the two-body problem. The set of intersection points found in this limit corresponds to the S-arcs and T-arcs of Hénon’s classification which verify the energy and time constraints, and can be used to construct an alphabet to describe the orbits of second species. We give numerical evidence for the existence of a shift on this alphabet that describes all the orbits with infinitely many close encounters with the small primary, and sketch a proof of the symbolic dynamics. In particular, we find periodic orbits that combine S-type and T-type quasi-homoclinic arcs.