Green and Eco‐Friendly Removal of Mycotoxins with Organo‐Bentonites; Isothermal,Kinetic, and Thermodynamic Studies

In the current study the application of organo‐modified bentonite for the adsorption of mycotoxins (aflatoxin B1, citrinin, patulin, and zearalenone) is presented. The modification of clays is carried out using benzyl‐tri‐n‐butyl ammonium bromide (BTB), benzethonium chloride (BTC), and dioctyl sodium sulfosuccinate (DSS). Various experimental parameters such as pH, time, adsorbent dose, and mycotoxins concentration are thoroughly studied. The modified clays (B‐BTB, B‐BTC and B‐DSS) are characterized by X‐ray fluorescence, X‐ray diffraction, and Fourier transform infrared spectroscopy. The results depicted the high detoxification efficiency (≈99%) of modified clays for the removal of mycotoxins under optimized conditions (pH 5, time: 30 min, adsorbent amount: 50 mg). The adsorption capacities of modified clays are found in the order of: B‐BTC (AFB1: 18.02, CIT: 18.35, PAT: 18.21, ZEA: 18.09 mg g^?1) > B‐BTB (AFB1: 17.7, CIT: 18.11, PAT: 17.95, ZEA: 17.90 mg g^?1) > B‐DSS (AFB1: 17.5, CIT: 18.02, PAT: 17.86, ZEA: 17.80 mg g^?1). The obtained results fitted well with thermodynamic, isothermal (Langmuir) and pseudo‐second order kinetics. Low cost organo‐modified bentonite shows the promise in mitigating mycotoxin contamination, which could improve food safety and reduce environmental contamination.     

Analytical‐numerical solution for stress distribution around tunnel reinforced by radial fully grouted rockbolts

This paper presents an analytical‐numerical approach to obtain the distribution of stresses and deformations around a reinforced tunnel. The increase in the radial stress of the reinforced tunnel, based on the performance of a bolt, is modeled by a function, which its maximum value is in the vicinity of the bolt periphery and it exponentially decreases in the far distance from the bolt. On the basis of this approach, the shear stiffness between the bolt and the rock mass and the shear stress distribution around the bolt within the rock mass are also analytically obtained. The results are compared with those obtained by the assumption of ‘uniform increase of radial stress’ method, which is made by the previous studies. The analyses show when the bolts' spacing is large, the safety factor must be increased if the ‘uniform increase of radial stress’ method is used for the design. Finally, a procedure is introduced to calculate the non‐equal deformation of the rock mass between the bolts at any radius that can be useful to compute the bending moment in shotcrete layer in New Austrian Tunnelling Method (NATM) approach. Copyright © 2016 John Wiley & Sons, Ltd.     

Meso- and Neoproterozoic complexes of the cover in the southeastern Siberian Platform: Formation conditions and main tectonic features

The large (more than 200000 km²) Uchur-Maya Meso- and Neoproterozoic intracontinental basin is delineated for the first time in the southeastern Siberian Platform, including the territory overlapped by the Ediacaran to Cambrian plate complex. The tectonic elements of higher orders—uplifts, domes, and deeps formed during the Neoproterozoic and Late Mesozoic tectonomagmatic activity—are outlined. The tectonic nappes of Paleoproterozoic rocks from 200 to 400 m thick were established between the Calymmian and Ectasian to Stenian rocks in the southeastern portion of the basin. The thickness of sedimentary rocks increases toward the Yudoma-Maya Aulacogen. The considerable thickness of Meso- and Neoproterozoic rocks and bitumen contents in sedimentary rocks are favorable factors testifying to the petroleum resource potential of the basin. The southern part of the basin is promising for ore deposits (primarily, uranium and gold) in zones of structural and stratigraphic unconformities and within the sedimentary cover itself. This study may serve as a background for further, more detailed tectonic investigations and substantiation of strategic lines of geological exploration.     

A Simple Limit Equilibrium Approach for Calculation of Ultimate Bearing Capacity of Shallow Foundations on Two-Layered Granular Soils

The bearing capacity of shallow foundations in a non-homogeneous soil profile has been a challenging task in geotechnical engineering. In this paper, a limit equilibrium method is used for calculating bearing capacity factors of shallow foundations constructed on a two-layered granular soil profile. The main objective has been to determine the ultimate bearing capacity computed from equivalent bearing capacity factors N_q and N_γ and comparing that with numerical analysis using finite element methods. It will be shown that the data obtained form the developed method are well comparable with those obtained from FE approach, specially when the difference between shear strength parameters of layers is low which is a practical case for sedimentary soil profiles and also for artificially compacted soils. A computer program has been developed to investigate the influence of various parameters on bearing capacity factors.     

Gorgan Bay:a microcosm for study on macrobenthos species-environment relationships in the southeastern Caspian Sea

The relationship between spatial patterns of macrobenthos community characteristics and environmental conditions(salinity, temperature, dissolved oxygen, organic matter content, sand, silt and clay) was investigated throughout the Gorgan Bay in June 2010. Principal components analysis(PCA) based on environmental data separated eastern and western stations. The maximum(4500 ind./m²) and minimum(411 ind./m²) densities were observed at Stas 1 and 6, respectively. Polychaeta was the major group and Streblospio gynobranchiata was dominant species in the bay. According to Distance Based Linear Models results, macrofaunal total density was correlated with silt percentage and salinity and these two factors explaining 64% of the variability while macrofaunal community structure just correlated with salinity(22% total variation). In general, western part of the bay showed the highest number of species and biodiversity while, the highest density was found at Sta. 1 and in the middle part of the bay. Furthermore, relationship between diversity indices and macrobenthic species with measured factors is also discussed. Our results confirm the effect of salinity as an important factor on distribution of macrobenthic fauna in south Caspian brackish waters.