Tracing nitrogen in volcanic and geothermal volatiles from the Nicaraguan volcanic front

We report new chemical and isotopic data from 26 volcanic and geothermal gases, vapor condensates, and thermal water samples, collected along the Nicaraguan volcanic front. The samples were analyzed for chemical abundances and stable isotope compositions, with a focus on nitrogen abundances and isotope ratios. These data are used to evaluate samples for volatile contributions from magma, air, air-saturated water, and the crust. Samples devoid of crustal contamination (based upon He isotope composition) but slightly contaminated by air or air-saturated water are corrected using N₂/Ar ratios in order to obtain primary magmatic values, composed of contributions from upper mantle and subducted hemipelagic sediment on the down-going plate. Using a mantle endmember with δ¹⁵N = −5‰ and N₂/He = 100 and a subducted sediment component with δ¹⁵N = +7‰ and N₂/He = 10,500, the average sediment contribution to Nicaraguan volcanic and geothermal gases was determined to be 71%. Most of the gases were dominated by sediment-derived nitrogen, but gas from Volcán Mombacho, the southernmost sampling location, had a mantle signature (46% from subducted sediment, or 54% from the mantle) and an affinity with mantle-dominated gases discharging from Costa Rica localities to the south. High CO₂/N_{2 exc.} ratios (N_{2 exc.} is the N₂ abundance corrected for contributions from air) in the south are similar to those in Costa Rica, and reflect the predominant mantle wedge input, whereas low ratios in the north indicate contribution by altered oceanic crust and/or preferential release of nitrogen over carbon from the subducting slab. Sediment-derived nitrogen fluxes at the Nicaraguan volcanic front, estimated by three methods, are 7.8 × 10⁸ mol N/a from ³He flux, 6.9 × 10⁸ mol/a from SO₂ flux, and 2.1 × 10⁸ and 1.3 × 10⁹ mol/a from CO₂ fluxes calculated from ³He and SO₂, respectively. These flux results are higher than previous estimates for Central America, reflecting the high sediment-derived volatile contribution and the high nitrogen content of geothermal and volcanic gases in Nicaragua. The fluxes are also similar to but higher than estimated hemipelagic nitrogen inputs at the trench, suggesting addition of N from altered oceanic basement is needed to satisfy these flux estimates. The similarity of the calculated input of N via the trench to our calculated outputs suggests that little or none of the subducted nitrogen is being recycled into the deeper mantle, and that it is, instead, returned to the surface via arc volcanism.     

Effects of enhanced zinc and copper in drinking water on spatial memory and fear conditioning

Ingestion of enhanced zinc can cause memory impairments and copper deficiencies. This study examined the effect of zinc supplementation, with and without copper, on two types of memory. Rats raised pre- and post-natally on 10 mg/kg ZnCO₃ or ZnSO₄ in the drinking water were tested in a fear-conditioning experiment at 11 months of age. Both zinc groups showed a maladaptive retention of fearful memories compared to controls raised on tap water. Rats raised on 10 mg/kg ZnCO₃, 10 mg/kg ZnCO₃ + 0.25 mg/kg CuCl₂, or tap water, were tested for spatial memory ability at 3 months of age. Significant improvements in performance were found in the ZnCO₃ + CuCl₂ group compared to the ZnCO₃ group, suggesting that some of the cognitive deficits associated with zinc supplementation may be remediated by addition of copper.     

Geochemical evolution of the Capim River kaolin, Northern Brazil

The Capim River kaolin, located in the eastern Brazilian Amazon, constitutes one of the most important kaolin deposits in the world. Known for its high whiteness, its noble application is in the paper industry. Studies were carried out on samples from the six facies of the deposit (sand kaolin, soft kaolin, lower transition facies, ferruginous crust, upper transition facies and flint kaolin) in order to trace its geochemical evolution. The kaolin developed at the expense of Cretaceous sandy–clayey sediments of the Ipixuna Formation. Intense lateritic processes characterized by ferruginization and deferruginization mechanisms led to the distinction of the different facies.     

Developments in the characterisation of waste materials for environmental impact assessment purposes

The characterisation of waste is entering a new phase with the latest developments of characterisation leaching tests and associated modelling capabilities. The currently applied too simple testing approaches lead to poor choices in waste management. With the increased insight in release controlling processes chemical speciation aspects can be addressed even in the most complex and heterogeneous waste materials. From a composition perspective materials may be highly variable, but often materials are far more consistent in their leaching behaviour. This aspect should be exploited more extensively as it holds the key to treat waste materials in such a way that long term solutions are achieved rather than reaching temporary gains.     

Cosmogenic nuclide methods for measuring long-term rates of physical erosion and chemical weathering

Understanding the evolution of geochemical and geomorphic systems requires measurements of long-term rates of physical erosion and chemical weathering. Erosion and weathering rates have traditionally been estimated from measurements of sediment and solute fluxes in streams. However, modern sediment and solute fluxes are often decoupled from long-term rates of erosion and weathering, due to storage or re-mobilization of sediment and solutes upstream from the sampling point. Recently, cosmogenic nuclides such as ¹⁰Be and ²⁶Al have become important new tools for measuring long-term rates of physical erosion and chemical weathering. Cosmogenic nuclides can be used to infer the total denudation flux (the sum of the rates of physical erosion and chemical weathering) in actively eroding terrain. Here we review recent work showing how this total denudation flux can be partitioned into its physical and chemical components, using the enrichment of insoluble tracers (such as Zr) in regolith relative to parent rock. By combining cosmogenic nuclide measurements with the bulk elemental composition of rock and soil, geochemists can measure rates of physical erosion and chemical weathering over 1000- to 10,000-year time scales.     

Effects of irrigation on geochemical processes in a paddy soil and in ground waters in Camargue (France)

In waterlogged soils, dynamics of water influence the redox conditions and thus the mobility of elements. Irrigation of rice in Camargue (South eastern France) induces yearly dynamics of water. In order to determine the impact of irrigation on the geochemical properties of ground waters, a continuously in situ record of physico-chemical parameters (pH, Eh, temperature and electric conductivity) is performed during 1 year in an irrigated rice field. Seasonal dynamics show large Eh and pH variations. An annual irrigation cycle generates fast precipitations of Ca–Mg carbonates and Fe oxides between 50 and 110 cm depth when the soil is waterlogged. The dissolution of these minerals is initiated during a year without irrigation.     

Neoproterozoic alkaline magmatism at Sivamalai, southern India

The Sivamalai alkaline complex lies at the southern margin of the Cauvery Shear System that separates the Archaean and Proterozoic domains of the Southern Granulite Terrain in India. U–Pb TIMS dating of zircon from a pegmatitic syenite sample in the complex yields a concordant age of 590.2 ± 1.3 (2σ) Ma which is interpreted to date the intrusion of the alkaline rocks. A lower concordia intercept at 168 ± 210 Ma defined by two grains with high common lead may indicate post-magmatic disturbances due to recrystallisation which is also evident in the CL images of the zircons. EPMA dating of monazite from a post-kinematic pegmatite which intrudes the crystalline basement hosting the alkaline rocks yields an age of 478 ± 29 (2σ) Ma and provides a lower bracket for the main phase of tectonism in this part of the Southern Granulite Terrain. The Pan-African high-grade metamorphism and ductile deformation has thus most likely affected the alkaline rocks. This is supported by the presence of a metamorphic foliation and extensive recrystallisation textures seen in the rocks. The major and trace element concentrations measured on selected samples reveals the presence of both enriched and depleted rock types. The enriched group includes ferrosyenite and nepheline syenite while the depleted group has only nepheline syenites. The trace element depletion of some nepheline syenites is interpreted to be a result of fractional crystallization involving the removal of accessory phases like zircon, titanite, apatite and allanite.